triethylsilyl hydroperoxide | 18173-68-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: triethylsilyl hydroperoxide
• 英文别名: triethylsilyloxy alcohol；Triaethylsilyl-hydroperoxyd；Triethyl(hydroperoxy)silane
• CAS: 18173-68-7
• 化学式: C₆H₁₆O₂Si
• 分子量: 148.277
• InChiKey: FQNJJVYOIDFBMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.48
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三乙基氯硅烷 在 咪唑 、 双氧水 作用下， 以 乙醚 为溶剂， 反应 0.33h， 以31%的产率得到triethylsilyl hydroperoxide
  参考文献：
  名称：

  Co(III)−Alkyl Complex- and Co(III)−Alkylperoxo Complex-Catalyzed Triethylsilylperoxidation of Alkenes with Molecular Oxygen and Triethylsilane

  摘要：

  [GRAPHICS]Both a Co(III)-alkyl complex and a Co(III)-alkylperoxo complex were found to catalyze triethylsilylperoxidation of alkenes with O-2 and Et3SiH. On this basis, together with the nonstereoselectivity in the Co(II)-catalyzed peroxidation of 3-phenylindene and the formation of the corresponding 1,2-dioxolane from 2-phenyl-1-vinylcyclopropane (a radical clock), we propose a reasonable mechanism for the Co(II)-catalyzed novel autoxidation of alkenes with Et3SiH discovered by Isayama and Mukaiyama.

  DOI：

  10.1021/ol0201299

文献信息

• Co(III)−Alkyl Complex- and Co(III)−Alkylperoxo Complex-Catalyzed Triethylsilylperoxidation of Alkenes with Molecular Oxygen and Triethylsilane
  作者：Takahiro Tokuyasu、Shigeki Kunikawa、Araki Masuyama、Masatomo Nojima

  DOI：10.1021/ol0201299

  日期：2002.10.1

  [GRAPHICS]Both a Co(III)-alkyl complex and a Co(III)-alkylperoxo complex were found to catalyze triethylsilylperoxidation of alkenes with O-2 and Et3SiH. On this basis, together with the nonstereoselectivity in the Co(II)-catalyzed peroxidation of 3-phenylindene and the formation of the corresponding 1,2-dioxolane from 2-phenyl-1-vinylcyclopropane (a radical clock), we propose a reasonable mechanism for the Co(II)-catalyzed novel autoxidation of alkenes with Et3SiH discovered by Isayama and Mukaiyama.