Zinc Gold | 12006-63-2

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Zinc Gold
• 英文别名: gold-zinc；zinc-gold；Gold;ZINC
• CAS: 12006-63-2
• 化学式: AuZn
• 分子量: 262.356
• InChiKey: SAOPTAQUONRHEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  金 、 锌 在 Ti 作用下， 以 neat (no solvent) 为溶剂， 生成 Zinc Gold
  参考文献：
  名称：

  Synthesis of Pt–Zn and Au–Zn compounds by isopiestic method

  摘要：

  This study examined the synthesis of Pt-Zn and Au-Zn compounds by applying Zn vapor. Phases of formed compounds were controlled by an isopiestic method, in which Pt or Au was heated at higher temperature than the Zn vapor source in a reaction container. The result was that gamma(1)-Pt(3)Zn(10), r-PtZn(1.7) and nu-PtZn were synthesized and the activities of Zn in these compounds were obtained. gamma(2)-AuZn(3) and beta'-AuZn were synthesized using thermodynamic information previously reported. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2010.05.146

文献信息

• Possibility of and conditions for the room temperature formation of compounds at the bulk metal/thin metal film interface
  作者：V. Simić、Ž. Marinković

  DOI：10.1016/0022-5088(83)90519-2

  日期：1983.12
• Solution chemistry synthesis, morphology studies, and optical properties of five distinct nanocrystalline Au–Zn intermetallic compounds
  作者：Zachary L. Schaefer、Dimitri D. Vaughn、Raymond E. Schaak

  DOI：10.1016/j.jallcom.2009.10.137

  日期：2010.2

  Au-Zn was used as a prototype binary system for exploring intermetallic phase accessibility in nanoparticle systems using low-temperature solution chemistry methods. By reacting Au nanoparticles with diethylzinc (Et2Zn) in oleylamine at temperatures of 250-300 degrees C, nanoparticles of five distinct binary intermetallic compounds were accessible: Au3Zn, Au5Zn3, AuZn, Cu5Zn8-type gamma-(Au,Zn), and Mg-type epsilon-(AuZn). A variety of nanoparticle shapes, including spheres, triangles, hexagons, and rods, are accessible in the Au-Zn system via a pseudomorphic reaction of Au nanocrystal shapes with Et2Zn. The Au-Zn nanoparticles have optical properties that vary with Zn content, ranging from a surface plasmon resonance peak at similar to 495 nm for Au3Zn to absorption in the ultraviolet region for the Zn-rich phases. (C) 2009 Elsevier B.V. All rights reserved.
• Rhombohedrally Distorted γ-Au_5–<i>x</i>Zn_8+<i>y</i> Phases in the Au–Zn System
  作者：Srinivasa Thimmaiah、Gordon J. Miller

  DOI：10.1021/ic301933a

  日期：2013.2.4

  The region of the Au-Zn phase diagram encompassing gamma-brass-type phases has been studied experimentally from 45 to 85 atom % Zn. The gamma phases were obtained directly from the pure elements by heating to 680 degrees C in evacuated silica tubes, followed by annealing at 300 degrees C. Powder X-ray and single-crystal diffraction studies show that gamma-AuSZn8" phases adopt a rhombohedrally distorted Cr5Al8 structure type rather than the cubic Cu5Zn8 type. The refined compositions from two single crystals extracted from the Znand Au-rich loadings are Au4.27(3)Zn8.26(3)square(0.47) (I) and Au4.58(3)Zn8.12(3)square(0.3). (II), respectively (square = vacancy). These (I and II) refinements indicated both nonstatistical mixing of Au and Zn atoms as well as partially ordered vacancy distributions. The structures of these gamma phases were solved in the acentric space group R3m (No. 160, Z = 6), and the observed lattice parameters from powder patterns were found to be a = 13.1029(6) and 13.1345(8) angstrom and c = 8.0410(4) and 8.1103(6) angstrom for crystals I and II, respectively. According to single-crystal refinements, the vacancies were found on the outer tetrahedron (OT) and octahedron (OH) of the 26-atom cluster. Single-crystal structural refinement clearly showed that the vacancy content per unit cell increases with increasing Zn, or valence-electron concentration. Electronic structure calculations, using the tight-binding linear muffin-tin orbital method with the atomic-sphere approximation (TB-LMTO-ASA) method, indicated the presence of a well-pronounced pseudogap at the Fermi level for "Au5Zn8" as the representative composition, an outcome that is consistent with the Hume-Rothery interpretation of gamma brass.
• Synthesis of Pt–Zn and Au–Zn compounds by isopiestic method
  作者：Hideaki Sasaki、Takashi Nagai、Masafumi Maeda

  DOI：10.1016/j.jallcom.2010.05.146

  日期：2010.8

  This study examined the synthesis of Pt-Zn and Au-Zn compounds by applying Zn vapor. Phases of formed compounds were controlled by an isopiestic method, in which Pt or Au was heated at higher temperature than the Zn vapor source in a reaction container. The result was that gamma(1)-Pt(3)Zn(10), r-PtZn(1.7) and nu-PtZn were synthesized and the activities of Zn in these compounds were obtained. gamma(2)-AuZn(3) and beta'-AuZn were synthesized using thermodynamic information previously reported. (C) 2010 Elsevier B.V. All rights reserved.