| 71320-99-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 71320-99-5
• 化学式: C₁₀H₂₀Si
• 分子量: 168.354
• InChiKey: IFBMBQKKTADSQS-UHFFFAOYSA-N

物化性质

• 沸点：
  69-70 °C(Press: 35 Torr)
• 密度：
  0.755±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.62
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  生成 9-((E)-4,4-Dimethyl-3-trimethylsilanyl-pent-2-enyl)-9-bora-bicyclo[3.3.1]nonane
  参考文献：
  名称：

  WANG, KUNG K.;LIU, CHIN;GU, YU GUI;BURNETT, FRIEDRICH;N. , SATTSANGI PREM+, J. ORG. CHEM., 56,(1991) N, C. 1914-1922

  摘要：

  DOI：
• 作为产物：
  描述：

  三甲硅基丙炔醇 、 magnesium,2-methylpropane,bromide 生成
  参考文献：
  名称：

  A New and General Route to 1-Trimethylsilyl-1,2-alkadienes

  摘要：

  DOI：

  10.1055/s-1979-28697

文献信息

• Lewis acid-catalyzed three-component condensation reactions of aldehydes, alkoxysilanes, and allenylsilanes: synthesis of α-propargyl ethers
  作者：Lui Niimi、Shuichi Hiraoka、Tsutomu Yokozawa

  DOI：10.1016/s0040-4020(01)01145-0

  日期：2002.1

  Lewis acid-catalyzed reaction of acetals with allenylsilanes and the three-component reactions of aldehydes, alkoxysilanes, and allenylsilanes are described. Both reactions are strongly dependent on the substituent at the α-position of allenylsilanes. Allenylsilanes having bulky substituents such as the tert-butyl and isopropyl groups result in the corresponding α-propargyl ethers in high yields, whereas

  描述了路易斯酸催化的缩醛与烯丙基硅烷的反应以及醛，烷氧基硅烷和烯丙基硅烷的三组分反应。两个反应都强烈依赖于烯丙基硅烷的α-位上的取代基。具有大的取代基（例如叔丁基和异丙基）的烯丙基硅烷可产生高产率的相应α-炔丙基醚，而具有甲基和乙基的烯丙基硅烷不仅可提供低产率的相应α-炔丙基醚，而且还可提供环丙基酮和α，β-不饱和酮为副产物。
• Stereoselective synthesis of terminal 1,3-butadienes by the condensation reaction of aldehydes and ketones with .gamma.-trimethylsilyl-substituted allylboranes
  作者：Kung K. Wang、Chin Liu、Yu Gui Gu、Friedrich N. Burnett、Prem D. Sattsangi

  DOI：10.1021/jo00005a045

  日期：1991.3

  Allylboranes 7-12, readily prepared from allenylsilanes 1-6 by hydroboration with 9-borabicyclo[3.3.1]nonane, smoothly condense with aldehydes and ketones to afford, after basic or acidic workup to promote the Peterson olefination reaction, a variety of terminal 1,3-butadienes. The dienes derived from aldehydes have high isomeric purity except in the cases with allylborane 12. Apparently, high diastereoselectivity was obtained during the condensation step with 7-11 to form 14. In each case, by simply changing the workup conditions to induce syn or anti elimination of hydroxytrimethylsilane, either the Z or the E isomer of the diene was obtained.
• WESTMIJZE H.; VERMEER P., SYNTHESIS, 1979, NO 5, 390-392
  作者：WESTMIJZE H.、 VERMEER P.

  DOI：——

  日期：——
• A New and General Route to 1-Trimethylsilyl-1,2-alkadienes
  作者：H. Westmijze、P. Vermeer

  DOI：10.1055/s-1979-28697

  日期：——
• WANG, KUNG K.;LIU, CHIN;GU, YU GUI;BURNETT, FRIEDRICH;N. , SATTSANGI PREM+, J. ORG. CHEM., 56,(1991) N, C. 1914-1922
  作者：WANG, KUNG K.、LIU, CHIN、GU, YU GUI、BURNETT, FRIEDRICH、N. , SATTSANGI PREM+

  DOI：——

  日期：——