diethoxyethylphenylsilane | 16522-50-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: diethoxyethylphenylsilane
• 英文别名: ethylphenyldiethoxysilane；EPDEOS；Diethoxy-ethyl-phenylsilane
• CAS: 16522-50-2
• 化学式: C₁₂H₂₀O₂Si
• 分子量: 224.375
• InChiKey: UYJVWFZJQXTYLG-UHFFFAOYSA-N

物化性质

• 沸点：
  253.6±9.0 °C(Predicted)
• 密度：
  0.94±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.43
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  diethoxyethylphenylsilane 在 sodium methylate 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 250.0 ℃ 、133.32 Pa 条件下， 反应 1.0h， 生成 1-ethylsilatrane
  参考文献：
  名称：

  D'yakov, V. M.; Makarov, A. F.; Kir'yanova, A. N., Journal of general chemistry of the USSR, 1988, vol. 58, # 3, p. 480 - 485

  摘要：

  DOI：
• 作为产物：
  描述：

  乙基三乙氧基硅烷 、 氯苯 在 sodium 作用下， 生成 diethoxyethylphenylsilane 、 ethoxy(ethyl)(diphenyl)silane
  参考文献：
  名称：

  Measurement and Correlation of Saturated Vapor Pressure of Ethylphenyldimethoxysilane and Ethylphenyldiethoxysilane

  摘要：

  The saturated temperatures of ethylphenyldimethoxysilane (EPDMOS) and ethylphenyldiethoxysilane (EPDEOS) were determined using an inclined ebulliometer from 2.035 to 64.0 kPa. The experimental data were fitted with the Antoine and Clarke-Glew equations by a weighted least-squares regression method, which yielded Antoine parameters (A = 9.1280, B = 1590.18, C = -100.39 K and A = 9.1049, B = 1678.64, C = -102.84 K) and standard vaporization enthalpies (Delta H-g(l)m(0)(298.15 K) = 62.52 kJ center dot mol(-1) and Delta H-g(l)m(0)(298.15 K) = 65.19 kJ center dot mol(-1)) for EPDMOS and EPDEOS, respectively. The critical properties of EPDMOS and EPDEOS, such as critical temperature, pressure, and volume, were estimated by the group contribution method introduced by Nannoolal et al. The acentric factors of EPDMOS and EPDEOS were estimated from these critical parameters and the reduced saturated vapor pressures calculated from either the Clarke-Glew equation or the Antoine equation.

  DOI：

  10.1021/acs.jced.5b00255

文献信息

• D'yakov, V. M.; Kir'yanova, A. N.; Kireeva, L. N., Journal of general chemistry of the USSR, 1988, vol. 58, # 3, p. 473 - 480
  作者：D'yakov, V. M.、Kir'yanova, A. N.、Kireeva, L. N.、Chernyshev, A. E.、Bochkarev, V. N.、Androsenko, S. I.

  DOI：——

  日期：——
• D'yakov, V. M.; Makarov, A. F.; Kir'yanova, A. N., Journal of general chemistry of the USSR, 1992, vol. 62, # 2.2, p. 285 - 290
  作者：D'yakov, V. M.、Makarov, A. F.、Kir'yanova, A. N.、Androsenko, S. I.

  DOI：——

  日期：——
• DYAKOV, V. M.;KIRYANOVA, A. N.;KIREEVA, L. N.;CHERNYSHEV, A. E.;BOCHKAREV+, ZH. OBSHCH. XIMII, 58,(1988) N 3, 539-547
  作者：DYAKOV, V. M.、KIRYANOVA, A. N.、KIREEVA, L. N.、CHERNYSHEV, A. E.、BOCHKAREV+

  DOI：——

  日期：——
• DYAKOV, V. M.;MAKAROV, A. F.;KIRYANOVA, A. N.;CHERNYSHEV, A. E.;BOCHKAREV+, ZH. OBSHCH. XIMII, 58,(1988) N 3, 548-552
  作者：DYAKOV, V. M.、MAKAROV, A. F.、KIRYANOVA, A. N.、CHERNYSHEV, A. E.、BOCHKAREV+

  DOI：——

  日期：——
• D'yakov, V. M.; Makarov, A. F.; Kir'yanova, A. N., Journal of general chemistry of the USSR, 1988, vol. 58, # 3, p. 480 - 485
  作者：D'yakov, V. M.、Makarov, A. F.、Kir'yanova, A. N.、Chernyshev, A. E.、Bochkarev, V. N.

  DOI：——

  日期：——