N,N'-bis(3-triethoxysilylpropyl)malonic amide | 223476-24-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N,N'-bis(3-triethoxysilylpropyl)malonic amide
• 英文别名: N,N'-bis-[3-(triethoxysilyl)propyl]malonamide；N,N'-bis(3-triethoxysilylpropyl)propanediamide
• CAS: 223476-24-2
• 化学式: C₂₁H₄₆N₂O₈Si₂
• 分子量: 510.776
• InChiKey: DTRFVBYMIUKDEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.49
• 重原子数：
  33
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  114
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  三乙醇胺 、 N,N'-bis(3-triethoxysilylpropyl)malonic amide 反应 7.0h， 以97%的产率得到N,N'-bis(3-silatranylpropyl)malonic diamide
  参考文献：
  名称：

  摘要：

  Condensation of 3-triethoxysilylpropylamine with malonic amide was studied. The condensation products, dicarboxylic acid diamides (malonic and phthalic), were used for peretherification with triethanolamine and thus new representatives of silatran series compounds were prepared: N,N'-bis(3-triethoxysilyl)malonic diamide and -phthalic diamide. By hydrolytic polycondensation of N,N'-bis(3-triethoxysilyl)malonic diamide we synthesized an organosilicon polymer with silsesquioxane structure, which we studied as a sorbent of platinum group metals rhodium, palladium and platinum. Peculiar features of sorption activity of the polymer and speculative mechanism of metal sorption are discussed.

  DOI：

  10.1023/a:1014219722025
• 作为产物：
  描述：

  丙二酰胺 、 3-氨基丙基三乙氧基硅烷 在 ammonium sulfate 作用下， 反应 21.0h， 以86%的产率得到N,N'-bis(3-triethoxysilylpropyl)malonic amide
  参考文献：
  名称：

  摘要：

  Condensation of 3-triethoxysilylpropylamine with malonic amide was studied. The condensation products, dicarboxylic acid diamides (malonic and phthalic), were used for peretherification with triethanolamine and thus new representatives of silatran series compounds were prepared: N,N'-bis(3-triethoxysilyl)malonic diamide and -phthalic diamide. By hydrolytic polycondensation of N,N'-bis(3-triethoxysilyl)malonic diamide we synthesized an organosilicon polymer with silsesquioxane structure, which we studied as a sorbent of platinum group metals rhodium, palladium and platinum. Peculiar features of sorption activity of the polymer and speculative mechanism of metal sorption are discussed.

  DOI：

  10.1023/a:1014219722025

文献信息

• Dumbbell‐Shaped T ₈ ‐POSS with Functional Organic Linkers
  作者：Nadège Rey、Sophie Carenco、Carole Carcel、Armelle Ouali、David Portehault、Michel Wong Chi Man、Clément Sanchez

  DOI：10.1002/ejic.201900284

  日期：2019.7.23

  New dumbbell‐shaped octasilsesquioxanes (T8‐POSS) are obtained by the condensation of organobridged silane precursors with partially condensed T7‐triol. The synthesis based on corner‐capping proceeds under mild reaction conditions (60 °C in toluene) upon a nucleophilic fluoride‐catalyzed condensation of the T7‐triol with the alkoxysilyl organics. Two dumbbell‐type T8‐POSS, one with a non‐symmetrical

  通过有机桥连硅烷前体与部分缩合的 T7-三醇缩合获得新的哑铃形八聚倍半硅氧烷 (T8-POSS)。基于封角的合成是在温和的反应条件下（甲苯中 60°C）在亲核氟化物催化的 T7-三醇与烷氧基甲硅烷基有机物的缩合反应中进行的。描述了两种哑铃型 T8-POSS，一种具有非对称尿素硫脲接头，另一种具有对称丙二酰胺接头。通过 FTIR 监测它们的形成，通过 NMR 光谱（1H、13C 和 29Si）研究它们的结构并通过质谱法确认。
• Sol–gel immobilized and reusable copper-catalyst for arylation of phenols from aryl bromides
  作者：Sofia Benyahya、Florian Monnier、Michel Wong Chi Man、Catherine Bied、Fouad Ouazzani、Marc Taillefer

  DOI：10.1039/b905205d

  日期：——

  A simple β-diamide ligand was immobilized by the sol–gel process on hybrid silica for Cu-mediated O-arylation reactions. Combined with 5% of CuI, the latter can easily be recovered and reused to generate diarylethers under smooth conditions from cheap aryl bromides in an eco-friendly solvent (MIBK). Besides, negligible metal leaching occurred after reaction in solution from the supported catalyst.

  一种简单的β-二酰胺配体通过溶胶-凝胶过程固定在杂化硅酸盐上，用于铜介导的O-芳基化反应。与5%的CuI结合后，后者能够在便捷条件下从便宜的芳基溴化物中生成二芳醚，并且使用环保溶剂（MIBK）进行反应。此外，反应后支持催化剂中的金属浸出微乎其微。
• 一种含酰胺基的烷氧基硅烷的合成工艺
  申请人：蓝星（成都）新材料有限公司

  公开号：CN102786546B

  公开（公告）日：2016-02-24

  本发明提供一种合成酰胺烷基烷氧基硅烷的工艺方法。采用羧酸酯和氨烷基烷氧基硅烷为原料进行加热回流反应，必要时可以添加醇钠作为催化剂，使酯与氨基发生酰胺化反应，生成酰胺烷基烷氧基硅烷目的产物和副产物醇。反应完成后用少量氯硅烷中和醇钠催化剂，然后常压蒸馏除去醇类等低沸物，再减压蒸馏除去未反应的高沸点原料。目的产物转化率可达90%以上，过程中副产物醇不会使原料及产物中的烷氧基硅基水解。目的产物还可以进一步精馏提纯，可以用作偶联剂、交联剂或合成硅树脂单体等。
• New hybrid silica based materials for the solid–liquid extraction of actinides
  作者：Jean­Charles Broudic、Olivier Conocar、Joël J. E. Moreau、Daniel Meyer、Michel Wong Chi Man

  DOI：10.1039/a904454j

  日期：——

  New hybrid silica based materials containing malonamide ligands have been prepared by sol–gel hydrolysis condensation of functionalised precursors. These hybrids proved to be highly efficient extracting solids which compare favorably to related silica materials.

  通过对功能化前体进行溶胶水解缩合，制备出了含有丙二酰胺配体的新型混合硅基材料。事实证明，这些混合物是高效的萃取固体，与相关的二氧化硅材料相比毫不逊色。
• ——
  作者：M. G. Voronkov、L. I. Belousova、Yu. N. Pozhidaev、N. N. Vlasova

  DOI：10.1023/a:1014219722025

  日期：——

  Condensation of 3-triethoxysilylpropylamine with malonic amide was studied. The condensation products, dicarboxylic acid diamides (malonic and phthalic), were used for peretherification with triethanolamine and thus new representatives of silatran series compounds were prepared: N,N'-bis(3-triethoxysilyl)malonic diamide and -phthalic diamide. By hydrolytic polycondensation of N,N'-bis(3-triethoxysilyl)malonic diamide we synthesized an organosilicon polymer with silsesquioxane structure, which we studied as a sorbent of platinum group metals rhodium, palladium and platinum. Peculiar features of sorption activity of the polymer and speculative mechanism of metal sorption are discussed.