1-trimethylsilyl-2-methoxymethyl-2-trimethylstannyl-ethene | 97607-47-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: 1-trimethylsilyl-2-methoxymethyl-2-trimethylstannyl-ethene
• 英文别名: (3-methoxy-2-trimethylstannylprop-1-enyl)-trimethylsilane
• CAS: 97607-47-1
• 化学式: C₁₀H₂₄OSiSn
• 分子量: 307.095
• InChiKey: USSVYANIYLDMBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.31
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-trimethylsilyl-2-methoxymethyl-2-trimethylstannyl-ethene 、 mercury dichloride 在 potassium fluoride 作用下， 以 四氢呋喃 为溶剂， 以79%的产率得到1-trimethylsilyl-2-chloromercuri-2-methoxymethyl-ethene
  参考文献：
  名称：

  Tin/mercury exchange in 1,2-distannyl-1-alkenes and 1-silyl-2-stannyl-1-alkenes

  摘要：

  1,2-Bis(chloromercuri)alkenes, 1-trimethylsilyl-2-chloromercuri-alkenes and 1-trimethylsilyl-2-organomercurialkenes can be readily made by transmetallation of the corresponding trimethyltin compounds with HgCl2 and RHgCl; their structures have been confirmed by multinuclear NMR data. The new compounds are expected to have a large synthetic potential involving lithium/mercury exchange, and subsequent reaction with electrophilic reagents.

  DOI：

  10.1016/0022-328x(94)88103-0
• 作为产物：
  描述：

  trimethyl(trimethylstannyl)silane 、 甲基炔丙基醚 、 四(三苯基膦)钯 生成 1-trimethylsilyl-2-methoxymethyl-2-trimethylstannyl-ethene
  参考文献：
  名称：

  MITCHELL, T. N.;KILLING, H.;DICKE, R.;WICKENKAMP, R., J. CHEM. SOC. CHEM. COMMUN., 1985, N 6, 354-355

  摘要：

  DOI：

文献信息

• Tin/mercury exchange in 1,2-distannyl-1-alkenes and 1-silyl-2-stannyl-1-alkenes
  作者：T.N. Mitchell、B. Kowall

  DOI：10.1016/0022-328x(94)88103-0

  日期：1994.5

  1,2-Bis(chloromercuri)alkenes, 1-trimethylsilyl-2-chloromercuri-alkenes and 1-trimethylsilyl-2-organomercurialkenes can be readily made by transmetallation of the corresponding trimethyltin compounds with HgCl2 and RHgCl; their structures have been confirmed by multinuclear NMR data. The new compounds are expected to have a large synthetic potential involving lithium/mercury exchange, and subsequent reaction with electrophilic reagents.
• MITCHELL, T. N.;KILLING, H.;DICKE, R.;WICKENKAMP, R., J. CHEM. SOC. CHEM. COMMUN., 1985, N 6, 354-355
  作者：MITCHELL, T. N.、KILLING, H.、DICKE, R.、WICKENKAMP, R.

  DOI：——

  日期：——