(2-(triethylstannylthio)ethyl)trimethoxysilane | 60171-40-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (2-(triethylstannylthio)ethyl)trimethoxysilane
• 英文别名: (2-triethylstannylthioethyl)trimethoxysilane；Trimethoxy-(2-triethylstannylmercaptoethyl)-silan；7,7-Diethyl-3,3-dimethoxy-2-oxa-6-thia-3-sila-7-stannanonane；trimethoxy(2-triethylstannylsulfanylethyl)silane
• CAS: 60171-40-6
• 化学式: C₁₁H₂₈O₃SSiSn
• 分子量: 387.203
• InChiKey: KRERGLBTTOLHLD-UHFFFAOYSA-M

物化性质

• 沸点：
  310.4±44.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  53
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (2-(triethylstannylthio)ethyl)trimethoxysilane 、 碘甲烷 以 氯仿 为溶剂， 生成 三乙基碘锡 (IV)
  参考文献：
  名称：

  Reactions of (triethylstannylthioalkyl)trialkoxysilanes and (triethylstannylthioalkyl)trialkoxysilatranes with methyl iodide

  摘要：

  Reactions of (triethylstannylthioalkyl)trimethoxysilanes Et3SnS(CH2)(n)Si(OMe)(3) (n = 1, 2) and (triethylstannylthioalkyl)trialkoxysilatranes Et3Sn(CH2) (n) Sa [hereinafter Sa = Si(OCH2CH2)(3)N is silatranyl group] with methyl iodide are studied for the first time. The results of the investigation of the reaction of 1-(2-alkylthioethyl)silatranes RSCH(2)CH(2)Sa (R = Me, Et) with methyl iodide are also discussed.

  DOI：

  10.1134/s107036320811011x

文献信息

• Sorokin; Stankevich; Kuznetsova, Russian Journal of General Chemistry, 1999, vol. 69, # 4, p. 560 - 563
  作者：Sorokin、Stankevich、Kuznetsova、Lopyrev、Voronkov

  DOI：——

  日期：——
• Reactions of (triethylstannylthioalkyl)trialkoxysilanes and (triethylstannylthioalkyl)trialkoxysilatranes with methyl iodide
  作者：M. S. Sorokin、M. G. Voronkov

  DOI：10.1134/s107036320811011x

  日期：2008.11

  Reactions of (triethylstannylthioalkyl)trimethoxysilanes Et3SnS(CH2)(n)Si(OMe)(3) (n = 1, 2) and (triethylstannylthioalkyl)trialkoxysilatranes Et3Sn(CH2) (n) Sa [hereinafter Sa = Si(OCH2CH2)(3)N is silatranyl group] with methyl iodide are studied for the first time. The results of the investigation of the reaction of 1-(2-alkylthioethyl)silatranes RSCH(2)CH(2)Sa (R = Me, Et) with methyl iodide are also discussed.