dithiophosphoric acid O,O'-diethyl ester-S-(methylcarbamoyl-methyl ester) | 2605-70-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: dithiophosphoric acid O,O'-diethyl ester-S-(methylcarbamoyl-methyl ester)
• 英文别名: Dithiophosphorsaeure-O,O'-diaethylester-S-(methylcarbamoyl-methylester)；Diaethoxythiophosphorylmercapto-essigsaeure-methylamid；Dithiophosphorsaeure-O,O'-diaethylester-S-methylaminocarbonylmethylester；Di-O-aethyl-S-dithiophosphat；Phosphorodithioic acid, O,O-diethyl S-(2-(methylamino)-2-oxoethyl) ester；2-diethoxyphosphinothioylsulfanyl-N-methylacetamide
• CAS: 2605-70-1
• 化学式: C₇H₁₆NO₃PS₂
• 分子量: 257.315
• InChiKey: AITRBAWLXICRTL-UHFFFAOYSA-N

物化性质

• 密度：
  1.232±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  105
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-氯-N-甲基乙酰胺 、 二硫代磷酸二乙酯钾盐 生成 dithiophosphoric acid O,O'-diethyl ester-S-(methylcarbamoyl-methyl ester)
  参考文献：
  名称：

  The Reaction of O,O-Dialkyl Thiophosphoric Acid Salts with Some α-Haloacyl Derivatives

  摘要：

  DOI：

  10.1021/ja01146a015

文献信息

• Aromatic compounds, their production processes and their compositions for the control of insect pests
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0488236A1

  公开（公告）日：1992-06-03

  An aromatic compound of the formula: wherein R¹ is, the same or different, a halogen atom, a C₁-C₄ alkyl group, a C₁-C₄ haloalkyl group, a C₁-C₃ alkoxy group or a C₁-C₃ haloalkoxy group; R² is a hydrogen atom or a methyl group; R³ is, the same or different, a halogen atom, a C₁-C₄ alkyl group, a C₁-C₄ haloalkyl group, a C₁-C₂ alkoxy group or a C₁-C₂ haloalkoxy group, or two adjacent R³s may be combined together to represent a C₁-C₂ alkylenedioxy group optionally bearing one or two substituents selected from halogen and methyl; p is an integer of 2 to 5; q is an integer of 0 to 5, which is useful for control of insect pests.

  式中的芳香族化合物： 其中 R¹ 是相同或不同的卤素原子、C₁-C₄ 烷基、C₁-C₄ 卤代烷基、C₁-C₃ 烷氧基或 C₁-C₃ 卤代烷氧基；R² 是氢原子或甲基；R³是相同或不同的卤原子、C₁-C₄烷基、C₁-C₄卤代烷基、C₁-C₂烷氧基或 C₁-C₂卤代烷氧基、或两个相邻的 R³ 结合在一起代表 C₁-C₂烷二氧基基团，该基团可任选带有一个或两个选自卤素和甲基的取代基；p 是 2 至 5 的整数； q 是 0 至 5 的整数，可用于防治害虫。
• Aromatic compounds, their production process and their compositions for the control of insect pests
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0484688A1

  公开（公告）日：1992-05-13

  An aromatic compound of the formula: wherein R¹ is, the same or different, a hydrogen atom, a halogen atom, an alkyl group, a haloalkyl group, an alkoxy group, a haloalkoxy group, a cyano group or a nitro group, or two adjacent R¹s may be combined together to represent a methylenedioxy group optionally bearing one or two substituents selected from halogen and methyl; R² is, the same or different, a hydrogen atom, a halogen atom or a methyl group; R³ is a halogen atom or an alkyl group; R⁴ is a hydrogen atom or an alkyl group; R⁵ is, the same or different, a halogen atom, an alkyl group, a haloalkyl group, an alkoxy group or a haloalkoxy group, or two adjacent R⁵s may be combined together to represent a methylenedioxy group optionally bearing one or two substituents selected from halogen and methyl; X is an oxygen atom (-O-), a sulfur atom (-S-), a carbonyl group (-CO-), a sulfinyl group (-SO-), a sulfonyl group (-SO₂-), an imino group (-NH-) or a methylene group (-CH₂-); Y is an oxygen atom (-O-) or a sulfur atom (-S-); p is an integer of 1 to 5; q is an integer of 1 to 3; and r is an integer of 1 to 5, which is useful as an insect pest controlling agent.

  式中的芳香族化合物： 其中 R¹是相同或不同的氢原子、卤素原子、烷基、卤代烷基、烷氧基、卤代烷氧基、氰基或硝基，或两个相邻的 R¹组合在一起代表亚甲基二氧基，可任选带有一个或两个选自卤素和甲基的取代基；R² 是相同或不同的氢原子、卤素原子或甲基；R³ 是卤素原子或烷基；R⁴ 是氢原子或烷基；R⁵是相同或不同的卤素原子、烷基、卤代烷基、烷氧基或卤代烷氧基，或两个相邻的 R⁵ 可以组合在一起代表亚甲基二氧基，可选择带有一个或两个选自卤素和甲基的取代基；X 是氧原子 (-O-)、硫原子 (-S-)、羰基 (-CO-)、亚磺酰基 (-SO-)、磺酰基 (-SO₂-)、亚氨基 (-NH-) 或亚甲基 (-CH₂-)；Y 是氧原子 (-O-) 或硫原子 (-S-)；p 是 1 至 5 的整数；q 是 1 至 3 的整数；r 是 1 至 5 的整数。
• A method for controlling insect pests which belong to homoptera
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0512557A1

  公开（公告）日：1992-11-11

  A method for controlling insect pests which belong to Homoptera which comprises applying an insect pesticidally effective amount of the compound having the formula: wherein A is a phenyl group, a 3-fluorophenyl group, a 3-chlorophenyl group and 3,5-difluorophenyl group; X is an oxygen atom or a methylene group, optionally together with an additive(s) and/or an inert carrier(s) to the said insect pests and/or the locus where the said insect pests propagate and/or cultivated plants to which the said insect pests do damage.

  一种控制同翅目害虫的方法，包括施用杀虫有效量的式化合物： 其中 A 是苯基、3-氟苯基、3-氯苯基和 3,5-二氟苯基；X 是氧原子或亚甲基，可选择与添加剂和/或惰性载体一起施用到上述害虫和/或上述害虫繁殖的地点和/或上述害虫造成危害的栽培植物上。
• 3-(4-Substituted-2-chlorophenoxy)propionaldoxime ethyl ether compounds, their production processes and their compositions for the control of insect pests
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0514831A2

  公开（公告）日：1992-11-25

  A 3-(4-substituted-2-chlorophenoxy)propionaldoxime ethyl ether compound of the formula: wherein X and Y are, the same or different, a hydrogen atom or a fluorine atom; Z is an oxygen atom or a methylene group with the proviso that X and Y are not a hydrogen atom at the same time when Z is an oxygen atom, which is useful for control of insect pests.

  一种式中的 3-(4-取代-2-氯苯氧基)丙二肟乙醚化合物： 其中 X 和 Y 相同或不同，均为氢原子或氟原子；Z 为氧原子或亚甲基，但当 Z 为氧原子时，X 和 Y 不能同时为氢原子，该化合物可用于防治害虫。
• O,O-Dialkyl S-(carbamoylalkyl) phosphorodithioates
  作者：GERALD BERKELHAMMER、SHIRLEY DuBREUIL、RICHARD W. YOUNG

  DOI：10.1021/jo01351a033

  日期：1961.7