Indium, [tris(trimethylsilyl)methyl]- | 562069-97-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Indium, [tris(trimethylsilyl)methyl]-
• CAS: 562069-97-0
• 化学式: C₁₀H₂₇InSi₃
• 分子量: 346.401
• InChiKey: CEQZDIPPOUHPPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.95
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 Indium, [tris(trimethylsilyl)methyl]- 以 正己烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  [M(GaCp*)₄] (M = Pd, Pt) as Building Blocks for Dimeric Homoleptic Cluster Compounds of the Type [MPt(GaCp*)₅]

  摘要：

  The monomeric homoleptic Pt(O) complex [Pt(GaCp*)(4)] (1) has been synthesized by reaction of [Pt(COD)(2)] with GaCp* in hexane. The monomeric homoleptic NO complexes [Pd(GaCp*)(4)] (2) and [Pd{InC(SiMe3)(3)}(4)] (3) are accessible by reaction of [Pd(tmeda)(CH3)(2)] with GaCp* and [InC(SiMe3)(3)], respectively. These reactions were shown to proceed via methyl group transfer from palladium to indium. or gallium, respectively. Complexes 1 and 2 can be used as building blocks for the synthesis of dinuclear cluster compounds. Thus, reaction of [Pt(COD)(2)] with 1 or 2 and subsequent addition of GaCp* yields [Pt-2(GaCp*)(2)(mu(2)-GaCp*)(3)] (4a) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)] (5a). Intermediates of this dimerization reactions, i.e., [Pt-2(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)] (4b) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)](5b), were isolated and characterized by means of variable-temperature NMR spectroscopy.

  DOI：

  10.1021/om021003i

文献信息

• Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal–group 13 metal bond formation
  作者：Tobias Steinke、Christian Gemel、Mirza Cokoja、Manuela Winter、Roland A. Fischer

  DOI：10.1039/b301928d

  日期：2003.4.16

  Insertion of the carbenoid group 13 metal species InCp* (Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh-Cl bonds of [[RhCp*Cl2]2] yields the new complexes [Cp*Rh(InCp*)3(Cl)2] 1 and [Cp*Rh(mu2-Cl)2(InC(SiMe3)3)3] 2, respectively, exhibiting novel cage-like intermetallic complexes with In-Cl-In bridges.

  将类胡萝卜素的13类金属InCp *（Cp * =五甲基环戊二烯基）和InC（SiMe3）3插入[[RhCp * Cl2] 2]的Rh-Cl键中，得到新的络合物[Cp * Rh（InCp *）3 （Cl）2] 1和[Cp * Rh（mu2-Cl）2（InC（SiMe3）3）3] 2分别显示具有In-Cl-In桥的新型笼状金属间配合物。
• [M(GaCp*)₄] (M = Pd, Pt) as Building Blocks for Dimeric Homoleptic Cluster Compounds of the Type [MPt(GaCp*)₅]
  作者：Christian Gemel、Tobias Steinke、Dana Weiss、Mirza Cokoja、Manuela Winter、Roland A. Fischer

  DOI：10.1021/om021003i

  日期：2003.6.1

  The monomeric homoleptic Pt(O) complex [Pt(GaCp*)(4)] (1) has been synthesized by reaction of [Pt(COD)(2)] with GaCp* in hexane. The monomeric homoleptic NO complexes [Pd(GaCp*)(4)] (2) and [PdInC(SiMe3)(3)}(4)] (3) are accessible by reaction of [Pd(tmeda)(CH3)(2)] with GaCp* and [InC(SiMe3)(3)], respectively. These reactions were shown to proceed via methyl group transfer from palladium to indium. or gallium, respectively. Complexes 1 and 2 can be used as building blocks for the synthesis of dinuclear cluster compounds. Thus, reaction of [Pt(COD)(2)] with 1 or 2 and subsequent addition of GaCp* yields [Pt-2(GaCp*)(2)(mu(2)-GaCp*)(3)] (4a) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)] (5a). Intermediates of this dimerization reactions, i.e., [Pt-2(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)] (4b) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)](5b), were isolated and characterized by means of variable-temperature NMR spectroscopy.