2,4,6-tris(ethylthio)-1,3,5-triazine | 30863-36-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,4,6-tris(ethylthio)-1,3,5-triazine
• 英文别名: tris-ethylmercapto-[1,3,5]triazine；Tris-aethylmercapto-[1,3,5]triazin；2,4,6-Tris(ethylsulfanyl)-1,3,5-triazine
• CAS: 30863-36-6
• 化学式: C₉H₁₅N₃S₃
• 分子量: 261.436
• InChiKey: UPXVUCGBEAYKTE-UHFFFAOYSA-N

物化性质

• 沸点：
  455.4±28.0 °C(Predicted)
• 密度：
  1.25±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  115
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  盐酸 、 2,4,6-tris(ethylthio)-1,3,5-triazine 生成 氰尿酸 、 乙硫醇
  参考文献：
  名称：

  Klason, Journal fur praktische Chemie (Leipzig 1954), 1886, vol. <2>33, p. 130

  摘要：

  DOI：
• 作为产物：
  描述：

  硫氰酸乙酯 在 盐酸 作用下， 生成 2,4,6-tris(ethylthio)-1,3,5-triazine
  参考文献：
  名称：

  Hofmann,A.W., Chemische Berichte, 1885, vol. 18, p. 2201

  摘要：

  DOI：

文献信息

• Sulfides and Disulfides of s-Triazine: Potential Thermal Thiyl Radical Generators
  作者：Carl-Christoph Höhne、Christian Posern、Uwe Böhme、Edwin Kroke

  DOI：10.1002/chem.201802427

  日期：2018.9.12

  A series of aliphatic and aromatic thioethers and dithioethers of s‐triazine were synthesised to study their thermal properties, in particular the thermally induced thiyl radical generation ability. Four symmetric s‐triazine sulfides of the type (RS)3C3N3, namely 2,4,6‐tris(phenylthio)‐ (1), 2,4,6‐tris(para‐tolylthio)‐ (3), 2,4,6‐tris(ethylthio)‐ (5) and 2,4,6‐tris(tert‐butylthio)‐1,3,5‐triazine (7)

  合成了一系列的s-三嗪脂族和芳族硫醚和二硫醚，以研究它们的热性能，特别是热诱导的噻吩基自由基的生成能力。（RS）3 C 3 N 3类型的四个对称的S-三嗪硫化物，即2,4,6-三（苯硫基）-（1），2,4,6-三（对甲苯甲硫基）-（3） ，2,4,6-三（乙硫基）-（5）和2,4,6-三（叔丁硫基）-1,3,5-三嗪（7）以及四个对称的S-三嗪二硫化物（RSS）3 C 3 N 3的类型，即2,4,6-tris（phenyldithio）-（2），2,4,6-三（对-甲苯基二硫代）-（4），2,4,6-三-（乙基二硫代）-（6）和2,4,6-三-（叔丁基二硫代）-1,3合成了5-5-三嗪（8）。所有化合物均通过1 H和13 C NMR，红外和拉曼光谱以及元素分析进行了全面表征。的单晶X射线衍射分析1，2和5讨论。通过热重分析，质谱分析（TGA-MS）和量子化学计算研究了热行为。极限氧指数（L
• PLANOGRAPHIC PRINTING PLATE PRECURSOR USING A POLYMERIZABLE COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3182204A1

  公开（公告）日：2017-06-21

  A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.

  一种聚合物，其侧链上具有可聚合基团和烷氧基，以及一种含有该聚合物的可聚合组合物。可聚合组合物最好含有可聚合化合物和聚合引发剂。此外，还提供了一种平版印刷板前体，它在亲水性支撑物上具有可聚合层，可聚合层含有侧链上具有可聚合基团的聚合物。这种平版印刷板前体无需经过碱显影即可形成图像。在支承层和可光聚合层之间可设置一个含有特定共聚物的底涂层。
• Hofmann, Chemische Berichte, 1885, vol. 18, p. 2206
  作者：Hofmann

  DOI：——

  日期：——
• Polymer having polymerizable group, polymerizable composition, planographic printing plate precursor, and planographic printing method using the same
  申请人：Kunita Kazuto

  公开号：US20080182205A1

  公开（公告）日：2008-07-31

  A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.
• POLYMER HAVING POLYMERIZABLE GROUP, POLYMERIZABLE COMPOSITION, PLANOGRAPHIC PRINTING PLATE PRECURSOR, AND PLANOGRAPHIC PRINTING METHOD USING THE SAME
  申请人：KUNITA Kazuto

  公开号：US20100003618A1

  公开（公告）日：2010-01-07

  A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.