pentacarbonyl(μ-η(5:3)-4H-indenyl)diiron(Fe-Fe) | 59714-91-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: pentacarbonyl(μ-η(5:3)-4H-indenyl)diiron(Fe-Fe)
• 英文别名: (η3,η5-C9H8)Fe2(CO)5；pentacarbonyl-7H-indenediiron；[Fe2(CO)5(η3,η5-C9H8)]
• CAS: 59714-91-9
• 化学式: C₁₄H₈Fe₂O₅
• 分子量: 367.909
• InChiKey: AWRIJFNYWYBVRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  pentacarbonyl(μ-η(5:3)-4H-indenyl)diiron(Fe-Fe) 、 (2-methylphenyl)lithium 以0%的产率得到[Fe2(μ-C(OC2H5)C6H4CH3-o)(CO)4(η4,η4-7H-indene)]*0.5(hexane)
  参考文献：
  名称：

  衍生自末端羰基双金属化合物的新型双金属桥联卡宾络合物。7H-茚配位二铁桥联卡宾配合物的合成，结构和反应活性。

  摘要：

  五羰基-7H-茚二铁[Fe2（CO）5（eta3，eta5-C9H8）]（1）与芳基锂ArLi（Ar = C6H5，p-C6H5C6H4）反应，然后与Et3OBF4烷基化，得到新型7H-茚-配位二铁桥联烷氧基卡宾配合物[Fe 2 {mu-C（OC2H5）Ar}（CO）4（eta4，eta4-C9H8）]（2，Ar = C6H5; 3，Ar = p-C6H5C6H4）。配合物2和3在低温下与HBF4.Et2O反应生成阳离子桥联卡宾配合物[Fe2（mu-CAr）（CO）4（eta4，eta4-C9H8）] BF4（4，Ar = C6H5; 5，Ar = p -C6H5C6H4）。阳离子4和5在低温下与NaBH4在THF中反应得到二铁桥联芳基碳烯络合物[Fe2 {mu-C（H）Ar}（CO）4（eta4，eta4-C9H8）]（6，Ar = C6H5; 7， Ar ＝ p-C6H5C6H4）。4

  DOI：

  10.1039/b607283f
• 作为产物：
  描述：

  五羰基铁 、 茚 以 正庚烷 为溶剂， 以60-75的产率得到[(η(5)-C9H7)(CO)2Fe]2
  参考文献：
  名称：

  Davies, Stephen G.; Holland, K. Sarah; Sutton, Kevin H., Israel Journal of Chemistry, 1991, vol. 31, p. 25 - 32

  摘要：

  DOI：

文献信息

• Photochemical reactions of transition metal organyl complexes with olefins
  作者：Cornelius G. Kreiter、Mike Packheiser、Walter Frank、Vera Reiland、Franz-Georg Wittmer

  DOI：10.1016/s0020-1693(99)00320-5

  日期：1999.12

  Pentacarbonyl(mu-eta(5:3)-4H-indenyl)diiron(Fe-Fe) (1) reacts upon UV irradiation with dimethyl 2-butynedioate (A) or methyl propynoate (B) by H-transfer to substituted pentacarbonyl(eta(5)-indenyl)[mu-eta(2:1)-vinyl]diiron(Fe-Fe) complexes (2A, 2B). With ethynylethylether (C) complex 1 yields pentacarbonyl- (3), and tetracarbonyl[mu-1-3a(7a),2'-eta:6,7,1',2'-eta-4,5-dihydro-5-(3'-oxo-1'- penten-1'-yl)indenyl]diiron(Fe-Fe) (4) by a C-C bond formation. The photoreaction of complex 1 with cis-cyclooctene (D) in toluene leads, without CO elimination by hapticity change to pentacarbonyl(eta(2)-cis-cyclooctene)(mu-eta(5:1)-4H-indenyl)diiron(Fe-Fe) (5) which stays during irradiation in equilibrium with 1 and D. In the dark 1 is re-formed quantitatively. Complex 5 reacts in situ with A to form dicarbonyl[1,2-bis(methoxycarbonyl)vinyl-kappa C-1](eta(5)-indenyl)iron (7) With C, complexes 3 and 4 are obtained. In solution 4 loses a Fe(CO)(2) unit and yields crude dicarbonyl[1-3a(7a),2'-eta-4,5-dihydro-5-(3'-oxa-1'-penten-1'-yl)indenyl]iron (8) During chromatography on alumina 8 is hydrolysed and rearranged to dicarbonyl(1-3a(7a),2'-eta-4,5-dihydro-5-methylenecarbonyl-indenyl)iron (9). Crystal and molecular structures were determined for 3 and 4. The constitutions of the other products are developed on the basis of IR, MS, and H-1 NMR spectroscopic data. (C) 1999 Elsevier Science S.A. All rights reserved.
• Novel dimetal bridging carbene complexes derived from a terminal carbonyl dimetal compound. Syntheses, structures and reactivities of 7H-indene-coordinated diiron bridging carbene complexes
  作者：Lei Zhang、Jie Sun、Huping Zhu、Qiang Xu、Nobuko Tsumori、Jiabi Chen

  DOI：10.1039/b607283f

  日期：——

  7H-indene-coordinated diiron bridging alkoxycarbene complexes [Fe2mu-C(OC2H5)Ar}(CO)4(eta4,eta4-C9H8)] (2, Ar = C6H5; 3, Ar = p-C6H5C6H4). Complexes 2 and 3 react with HBF4.Et2O at low temperature to yield cationic bridging carbyne complexes [Fe2(mu-CAr)(CO)4(eta4,eta4-C9H8)]BF4 (4, Ar = C6H5; 5, Ar = p-C6H5C6H4). Cationic 4 and 5 react with NaBH4 in THF at low temperature to afford diiron bridging arylcarbene complexes

  五羰基-7H-茚二铁[Fe2（CO）5（eta3，eta5-C9H8）]（1）与芳基锂ArLi（Ar = C6H5，p-C6H5C6H4）反应，然后与Et3OBF4烷基化，得到新型7H-茚-配位二铁桥联烷氧基卡宾配合物[Fe 2 mu-C（OC2H5）Ar}（CO）4（eta4，eta4-C9H8）]（2，Ar = C6H5; 3，Ar = p-C6H5C6H4）。配合物2和3在低温下与HBF4.Et2O反应生成阳离子桥联卡宾配合物[Fe2（mu-CAr）（CO）4（eta4，eta4-C9H8）] BF4（4，Ar = C6H5; 5，Ar = p -C6H5C6H4）。阳离子4和5在低温下与NaBH4在THF中反应得到二铁桥联芳基碳烯络合物[Fe2 mu-C（H）Ar}（CO）4（eta4，eta4-C9H8）]（6，Ar = C6H5; 7， Ar ＝ p-C6H5C6H4）。4
• Davies, Stephen G.; Holland, K. Sarah; Sutton, Kevin H., Israel Journal of Chemistry, 1991, vol. 31, p. 25 - 32
  作者：Davies, Stephen G.、Holland, K. Sarah、Sutton, Kevin H.、McNally, John P.

  DOI：——

  日期：——