MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
申请人:TABATA Masayoshi
公开号:US20110224343A1
公开(公告)日:2011-09-15
The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W
1
x
—Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III):
and monovalent residues represented by Formula (IV): —O—C(O)—R
7
—.
There is provided an aromatic polyester suitable for optical applications, which has not only high heat resistance and transparency, but also enhanced fluidity at a relatively low molding temperature of less than 300° C. despite its high molecular weight to be substantially colorless after the molding process. The aromatic polyester of the present invention comprises polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof; wherein the polyhydric phenol residues comprise polyhydric phenol residues represented by Formula (I): —O—Ar—W
1
x
—Ar—O— and/or Formula (II): —O—Ar—O—, and bulky polyhydric phenol residues represented by Formula (III): —O—Ar—W
2
—Ar—O—; wherein the molar ratio of the polyhydric phenol residues represented by Formula (I) and/or Formula (II) to the polyhydric phenol residues represented by Formula (III) is in the range of 100:0 to 30:70 (exclusive of 100:0).
US8129493B2
申请人:——
公开号:US8129493B2
公开(公告)日:2012-03-06
Tomita, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1938, vol. 58, p. 510,514; dtsch. Ref. S. 136, 138