申请人:QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
公开号:US20190315786A1
公开(公告)日:2019-10-17
Provided are a phosphazene compound, a method for preparing a phosphazene compound and a method for producing a polymer with a phosphazene compound as a catalyst. The compound of formula (I) or a solvate thereof, where A is a six- or eight-membered ring consisting of repeated P═N, and B is at least one of unsubstituted or substituted C
1-6
alkylamino, unsubstituted or substituted C
1-6
cycloalkylamino, unsubstituted or substituted arylamino,
or halogen, and B is attached to A at phosphorus in P═N, where R is unsubstituted or substituted C
1-6
alkyl, unsubstituted or substituted C
1-6
cycloalkyl, unsubstituted or substituted aryl, or unsubstituted or substituted benzyl, or R forms C
1-6
heterocycloalkyl together with N attached thereto.
提供了一种磷氮化合物,一种制备磷氮化合物的方法以及一种以磷氮化合物为催化剂生产聚合物的方法。该化合物的结构式(I)或其溶剂化合物,其中A是由重复的P═N组成的六元或八元环,B至少是未取代或取代的C1-6烷基氨基、未取代或取代的C1-6环烷基氨基、未取代或取代的芳基氨基或卤素中的至少一种,并且B连接到A上的磷处于P═N中,其中R是未取代或取代的C1-6烷基、未取代或取代的C1-6环烷基、未取代或取代的芳基或未取代或取代的苄基,或者R与N结合形成C1-6杂环烷基。