N-phenyl(4-{[phenyl(oxido)iminio]methyl}phenyl)methylideneamine N-oxide | 1586-93-2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 醌二甲烷类
• 英文名称: N-phenyl(4-{[phenyl(oxido)iminio]methyl}phenyl)methylideneamine N-oxide
• 英文别名: [4-[(N-oxidoanilino)methylidene]cyclohexa-2,5-dien-1-ylidene]methyl-oxo-phenylazanium
• CAS: 1586-93-2
• 化学式: C₂₀H₁₆N₂O₂
• 分子量: 316.359
• InChiKey: WVLPWNBZMLAWFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-phenyl(4-{[phenyl(oxido)iminio]methyl}phenyl)methylideneamine N-oxide 以 乙腈 为溶剂， 反应 0.2h， 生成 3,3'-(1,4-phenylene)bis(2-(2-methoxy-2-oxoacetyl)-1-phenylylaziridine-2-carboxylate)
  参考文献：
  名称：

  新型双（异恶唑啉）和双（氮丙啶）衍生物的合成

  摘要：

  已经描述了通过微波辐射通过1,3-偶极环加成反应由对苯甲醛衍生的双（硝酮）合成一些新的双（异恶唑啉）衍生物。双（异恶唑啉）衍生物通过鲍德温重排依次成功地转化为新的双（氮丙啶）衍生物。简单的反应方法，不涉及催化剂以及良好至极好的收率是该合成过程中注意到的重要特征。

  DOI：

  10.1002/jhet.2657
• 作为产物：
  描述：

  硝基苯 在 氯化铵 、 锌 作用下， 以 乙醇 、 水 为溶剂， 反应 12.33h， 生成 N-phenyl(4-{[phenyl(oxido)iminio]methyl}phenyl)methylideneamine N-oxide
  参考文献：
  名称：

  10.1039/b0071641

  摘要：

  DOI：

  10.1039/b0071641

文献信息

• Chakraborty, Bhaskar; Luitel, Govinda Prasad; Chhetri, Manjit Singh, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2016, vol. 55B, # 10, p. 1259 - 1266
  作者：Chakraborty, Bhaskar、Luitel, Govinda Prasad、Chhetri, Manjit Singh

  DOI：——

  日期：——
• RUBBER COMPOSITION FOR TIRE TREADS AND PNEUMATIC TIRE
  申请人：THE YOKOHAMA RUBBER CO., LTD.

  公开号：US20180051163A1

  公开（公告）日：2018-02-22

  A rubber composition for tire treads contains an inorganic filler containing silica and a diene rubber containing a carboxy-modified polymer. The content of the inorganic filler is from 70 to 170 parts by mass per 100 parts by mass of the diene rubber. The content of the silica is from 70 to 160 parts by mass per 100 parts by mass of the diene rubber. The carboxy-modified polymer is obtained by modifying a styrene-butadiene rubber (A) with a nitrone compound (B) having a carboxy group, and the content of the carboxy-modified polymer in the diene rubber is from 10 to 100 mass %. The content of styrene units in the styrene-butadiene rubber (A) is not less than 36 mass %. The degree of modification of the carboxy-modified polymer is from 0.02 to 4.0 mol %.
• RUBBER COMPOSITION FOR TIRE TREADS, AND PNEUMATIC TIRE
  申请人：THE YOKOHAMA RUBBER CO., LTD.

  公开号：US20180079834A1

  公开（公告）日：2018-03-22

  The present invention provides a rubber composition for tire treads, the rubber composition achieving high rubber hardness and 300% modulus at high temperatures, and excellent dry grip properties when formed into a tire, along with a pneumatic tire obtainable by using the same. The rubber composition for tire treads of the present invention contains carbon black and a diene rubber including a carboxy-modified polymer. The carbon black content is from 80 to 150 parts by mass per 100 parts by mass of the diene rubber. The carboxy-modified polymer is obtained by modifying styrene-butadiene rubber (A) with a nitrone compound having carboxy group (B), and the content of the carboxy-modified polymer in the diene rubber is from 10 to 100 mass %. The content of styrene units in styrene-butadiene rubber (A) is at least 36 mass %. The degree of modification of the carboxy-modified polymer is from 0.02 to 4.0 mol %.