chloro-tetracyanoquinodimethane | 56403-65-7

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 醌二甲烷类
• 英文名称: chloro-tetracyanoquinodimethane
• 英文别名: 2-Chlor-7,7,8,8-tetracyanochinodimethan；2-[3-Chloro-4-(dicyanomethylidene)cyclohexa-2,5-dien-1-ylidene]propanedinitrile
• CAS: 56403-65-7
• 化学式: C₁₂H₃ClN₄
• 分子量: 238.636
• InChiKey: RQYRALOMRBYRQH-UHFFFAOYSA-N

物化性质

• 熔点：
  210-212 °C
• 沸点：
  154.8±40.0 °C(Predicted)
• 密度：
  1.42±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  95.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1',1'''-dineopentyl-1,1''-biferrocene 、 chloro-tetracyanoquinodimethane 以 二氯甲烷 为溶剂， 以23%的产率得到
  参考文献：
  名称：

  A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor–acceptor interactions

  摘要：

  [Dineopentyl-biferrocene]2[Cl1TCNQ]7，其给受体比为2：7，包含一个线性顺磁性六聚体Cl1TCNQ。

  DOI：

  10.1039/c4cc06888b
• 作为产物：
  描述：

  Dimethyl α,α,α',α'-tetracyano-2-chlor-p-phenylendiacetat 生成 chloro-tetracyanoquinodimethane
  参考文献：
  名称：

  Synthesis of substituted 7,7,8,8-tetracyanoquinodimethanes

  摘要：

  DOI：

  10.1021/jo00909a019

文献信息

• PROCESS FOR PREPARING HIGHLY CONDUCTIVE ACETYLENE HIGH POLYMER
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0026234A1

  公开（公告）日：1981-04-08

  A process for preparing organic semiconductor, which comprises doping an acetylene high polymer having a fibril structure with a specific electron-accepting compound. Conventional electron-accepting compounds are highly toxic and provide conductive acetylene high polymers which do not always exhibit a sufficiently high electric conductivity, which have a mechanical strength seriously reduced by the doping, and which have an insufficient heat resistance. The use of a specific, the low-toxic electron-accepting compound of the present invention provides a conductive acetylene high polymer having an enhanced electric conductivity and good flexibility and heat resistance. This conductive acetylene high polymer is a p-type semiconductor enabling to freely control the electric conductivity within the range of 10-9 to 103Ω-1.cm-1 and is useful as a material for conductive materials, p-n heterojunction elements, and photo-electric transducers such as solar batteries, photosensors, etc.

  一种制备有机半导体的工艺，包括在具有纤维结构的乙炔高聚物中掺入特定的电子接受化合物。传统的电子接受化合物毒性很高，所提供的导电乙炔高聚物并不总是具有足够高的导电性，掺杂后机械强度严重下降，耐热性也不足。使用本发明的一种特定的低毒电子接受化合物，可以得到一种导电性乙炔高聚物，它具有更高的导电性、良好的柔韧性和耐热性。这种导电乙炔高聚物是一种 p 型半导体，可在 10-9 至 103Ω-1.cm-1 的范围内自由控制电导率，可用作导电材料、p-n 异质结元件和太阳能电池、光传感器等光电转换器的材料。
• THIA- AND/OR SELENAFULVALENYL COMPOUND
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0454874A1

  公开（公告）日：1991-11-06

  A thia- and/or selenafulvalenyl compound having an excellent thermal stability and represented by general formula (I), wherein X1 to X4 and X1' to X4' are each independently S or Se; Y is a substituent not inhibiting overlapping of the molecule; m is an integer of 0 to 4; Z1, Z2, Z1' and Z2' are each independently a hydrogen atom, CnH2n+1 wherein n is an integer of 1 to 5 or XCnH2n+1 wherein X is S or Se, n is an integer of 1 to 5, or Z1 and Z2 are combined to Z1' and Z2' to form CnH2n wherein n is an integer of 1 to 5, or X(CnH2n)n'X wherein X is S or Se and n' is an integer of 1 to 3; and R1 to R3 and R1' to R3' are each independently a hydrogen atom or CnH2n+1 wherein n is an integer of 1 to 5, and a conductive complex comprising a compound represented by general formula (I) as an electron donor.

  一种具有优异热稳定性的噻吩和/或硒富戊烯基化合物，由通式(I)表示，其中 X1 至 X4 和 X1' 至 X4'各自独立地为 S 或 Se；Y 为不抑制分子重叠的取代基；m 为 0 至 4 的整数；Z1、Z2、Z1'和 Z2'各自独立地为氢原子、CnH2n+1（其中 n 为 1 至 5 的整数）或 XCnH2n+1（其中 X 为 S 或 Se，n 为 1 至 5 的整数），或 Z1 和 Z2 与 Z1'和 Z2'结合形成 CnH2n（其中 n 为 1 至 5 的整数），或 X(CnH2n)n'X（其中 X 为 S 或 Se，n'为 1 至 3 的整数）；R1至R3和R1'至R3'各自独立地为氢原子或CnH2n+1（其中n为1至5的整数），以及包含通式(I)代表的化合物作为电子供体的导电复合物。
• ANILINE DERIVATIVE AND USE THEREOF
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3118190A1

  公开（公告）日：2017-01-18

  An aniline derivative represented by the formula, for instance, has good solubility in organic solvents, and when a thin film comprising such derivative as a charge-transporting substance is used in a hole injection layer, an organic EL element having excellent luminance characteristics can be obtained.

  例如，由式表示的苯胺衍生物在有机溶剂中具有良好的溶解性，当在孔注入层中使用由这种衍生物作为电荷传输物质的薄膜时，可以获得具有优异发光特性的有机 EL 元件。
• CHARGE-TRANSPORTING VARNISH
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3147960A1

  公开（公告）日：2017-03-29

  A thin film that has high flatness and high charge transport properties and enables an organic EL element to achieve excellent luminance characteristics if applied thereto can be obtained by using a charge-transporting varnish which contains a charge-transporting substance, an organosilane compound that is composed of a polymer prepared in advance by subjecting an alkoxysilane compound to hydrolysis-condensation and having a weight average molecular weight of 500-10,000, and an organic solvent, said alkoxysilane compound containing at least one compound selected from among alkoxysilane compounds represented by formulae (1-1) and (1-2). SiR1(OR2)3 (1-1) SiR12(OR2)2 (1-2) (In the formulae, each R1 independently represents an alkyl group having 1-20 carbon atoms, which is substituted by Z1, or the like; each R2 independently represents an alkyl group having 1-20 carbon atoms, which may be substituted by Z3; and each of Z1 and Z3 represents a halogen atom or the like.)

  通过使用含有电荷传输物质的电荷传输清漆，可以获得一种具有高平整度和高电荷传输特性的薄膜，如果将其应用于有机电致发光元件，可使其获得优异的亮度特性、有机硅烷化合物，该有机硅烷化合物由通过对烷氧基硅烷化合物进行水解-缩合预先制备的聚合物和有机溶剂组成，所述聚合物的平均分子量为 500-10000，所述烷氧基硅烷化合物含有至少一种从式（1-1）和（1-2）所代表的烷氧基硅烷化合物中选出的化合物。SiR1(OR2)3 (1-1) SiR12(OR2)2 (1-2) (在式中，每个 R1 独立地代表具有 1-20 个碳原子的烷基，该烷基被 Z1 或类似物取代；每个 R2 独立地代表具有 1-20 个碳原子的烷基，该烷基可被 Z3 取代；Z1 和 Z3 各自代表卤素原子或类似物)。
• THIN-FILM PLANARIZATION METHOD, PLANARIZED THIN-FILM FORMATION METHOD, AND THIN-FILM FORMATION VARNISH
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3151298A1

  公开（公告）日：2017-04-05

  Provided are a thin-film planarization method, a planarized thin-film formation method, and a thin-film formation varnish to be used in these methods, in which when forming a thin film using a thin-film formation varnish which includes an organic compound and an organic solvent, the varnish flow activation energy is set to no more than 28 kJ/mol.

  本发明提供了一种薄膜平面化方法、一种平面化薄膜形成方法和一种用于这些方法的薄膜形成光油，其中在使用包括有机化合物和有机溶剂的薄膜形成光油形成薄膜时，光油流动活化能被设定为不超过 28 kJ/mol。