4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine | 92238-45-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine
• 英文别名: 2-cyclopropyl-4,6-bis(trichloromethyl)-s-triazine；4-cyclopropyl-2,6-bis-trichloromethyl-1,3,5-triazine；2-Cyclopropyl-4,6-bis-trichloromethyl-1,3,5-triazine；2-cyclopropyl-4,6-bis(trichloromethyl)-1,3,5-triazine
• CAS: 92238-45-4
• 化学式: C₈H₅Cl₆N₃
• 分子量: 355.866
• InChiKey: YCTPGQYFEFXYER-UHFFFAOYSA-N

物化性质

• 沸点：
  383.2±52.0 °C(Predicted)
• 密度：
  1.781±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine 、 氨 在 乙醚 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 0.5h， 生成 2-amino-4-cyclopropyl-6-trichloromethyl-1,3,5-triazine
  参考文献：
  名称：

  2-amino-4-cyclopropyl-1,3,5-triazines as intermediates for the

  摘要：

  本文揭示了2-氨基-4-环丙基-1,3,5-三嗪及其制备方法。2-氨基-4-环丙基-1,3,5-三嗪是除草活性N-(环丙基三嗪基)-N'-芳基磺酰脲的生产中间体，对应于以下式子：##STR1## 其中R.sub.1是氢，C.sub.1-C.sub.4-烷基或C.sub.1-C.sub.4-烷氧基，R.sub.2是C.sub.1-C.sub.3-烷基，C.sub.1-C.sub.3-卤代烷基或C.sub.2-C.sub.6-烷氧基烷基。

  公开号：

  US04670559A1
• 作为产物：
  描述：

  三氯乙腈 、 环丙基腈 在 盐酸 作用下， 以 正己烷 为溶剂， 生成 4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine 、 敌菌灵
  参考文献：
  名称：

  Use of triazine derivatives for protecting maize and sorghum plants

  摘要：

  描述了式I的三嗪衍生物，其中R.sub.1、R.sub.2和R.sub.3彼此独立地为每个未被C.sub.3-C.sub.6环烷基单取代的C.sub.1-C.sub.5烷基，或者被卤素单取代，或者被C.sub.3-C.sub.6环烷基单取代或多取代，或者是未被卤素单取代或多取代的C.sub.3-C.sub.6环烷基，或者取代基R.sub.1、R.sub.2和R.sub.3中的一个也是卤素或-NR.sub.4 R.sub.5，其中R.sub.4是氢或C.sub.1-C.sub.5烷基，R.sub.5是氢，C.sub.1-C.sub.5烷基，单氯乙酰基或二氯乙酰基。这些三嗪衍生物用于保护玉米和高粱植物免受除草剂氯乙酰苯胺和氯乙酰胺的有害影响。

  公开号：

  US04523947A1

文献信息

• N-(Cyclopropyl-triazinyl-n'-(arylsulfonyl) ureas having herbicidal
  申请人：Ciba Geigy Corporation

  公开号：US04515626A1

  公开（公告）日：1985-05-07

  N-(Cyclopropyl-triazinyl- and -pyrimidinyl)-N'-arylsulfonyl ureas of the formula ##STR1## wherein Ar is a phenyl group ##STR2## or a naphthyl group ##STR3## and Q is a group X-A or R.sub.3, A is a C.sub.3 -C.sub.6 -alkynyl group, a C.sub.1 -C.sub.6 -alkyl group which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.1 -C.sub.4 -haloalkylsulfinyl or C.sub.1 -C.sub.4 -haloalkylsulfonyl, or a C.sub.2 -C.sub.6 -alkenyl group which is unsubstituted or substituted by the groups given in the foregoing for C.sub.1 -C.sub.6 -alkyl, or A is a phenyl or benzyl group, E is the methine group or nitrogen, X is oxygen, sulfur, or a sulfinyl or sulfonyl bridge, Z is oxygen or sulfur, R.sub.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sub.2 is halogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -haloalkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -haloalkoxy, amino, C.sub.1 -C.sub.3 -alkylamino, di-(C.sub.1 -C.sub.3 -alkyl)amino, C.sub.3 -C.sub.6 -cycloalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a group --X-R.sub.6, --COZR.sub.11, --NO.sub.2 or --CO-NR.sub.8 R.sub.9, --CN, --COR.sub.10, --NR.sub.1 R.sub.7 or --NR.sub.1 -COR.sub.12, R.sub.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen, or alkoxyalkyl having at most 4 carbon atoms, R.sub.5 is the same as R.sub.3 but independent thereof, R.sub.6 and R.sub.7 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, R.sub.8 and R.sub.9 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, R.sub.10 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.3 -haloalkyl, R.sub.11 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -haloalkyl, C.sub.3 -C.sub.5 -alkenyl, C.sub.3 -C.sub.5 -alkynyl, phenyl or benzyl, and R.sub.12 is the same as R.sub.1 but independent thereof, and the salts of these compounds with amines, alkali metal bases or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence-selective herbicidal and plant-growth-regulating properties.

  这是一种化合物的公式，其为N-(环丙基-三嗪基和嘧啶基)-N'-芳基磺酰脲，其公式为##STR1##其中Ar为苯基##STR2##或萘基##STR3##，Q为X-A或R.sub.3，A为C.sub.3-C.sub.6-炔基、未取代或取代卤素的C.sub.1-C.sub.6-烷基、C.sub.1-C.sub.4-烷氧基、C.sub.1-C.sub.4-烷硫基、C.sub.1-C.sub.4-烷基亚磺酰基、C.sub.1-C.sub.4-烷基磺酰基、C.sub.1-C.sub.4-卤代烷氧基、C.sub.1-C.sub.4-卤代烷硫基、C.sub.1-C.sub.4-卤代烷基亚磺酰基或C.sub.1-C.sub.4-卤代烷基磺酰基，或未取代或取代为C.sub.1-C.sub.6-烷基的C.sub.2-C.sub.6-烯基，A为苯基或苄基，E为亚甲基或氮，X为氧、硫或亚磺酰基或磺酰基桥，Z为氧或硫，R.sub.1为氢、C.sub.1-C.sub.4-烷基或C.sub.1-C.sub.4-烷氧基，R.sub.2为卤素、C.sub.1-C.sub.3-烷基、C.sub.1-C.sub.3-卤代烷基、C.sub.1-C.sub.3-烷氧基、C.sub.1-C.sub.3-卤代烷氧基、氨基、C.sub.1-C.sub.3-烷基氨基、双-(C.sub.1-C.sub.3-烷基)氨基、C.sub.3-C.sub.6-环烷基或C.sub.2-C.sub.6-烷氧基烷基，R.sub.3为氢、卤素、C.sub.1-C.sub.5-烷基、C.sub.2-C.sub.5-烯基、C.sub.1-C.sub.4-卤代烷基或--X-R.sub.6、--COZR.sub.11、--NO.sub.2或--CO-NR.sub.8R.sub.9、--CN、--COR.sub.10、--NR.sub.1R.sub.7或--NR.sub.1-COR.sub.12的基团，R.sub.4为氢、C.sub.1-C.sub.4-烷基、C.sub.1-C.sub.4-烷氧基、C.sub.1-C.sub.4-烷硫基、C.sub.1-C.sub.4-卤代烷基、C.sub.1-C.sub.4-卤代烷氧基、卤素或最多具有4个碳原子的烷氧基烷基，R.sub.5与R.sub.3相同但独立，R.sub.6和R.sub.7均为C.sub.1-C.sub.5-烷基、C.sub.2-C.sub.5-烯基或C.sub.2-C.sub.6-炔基，R.sub.8和R.sub.9独立地为氢、C.sub.1-C.sub.5-烷基、C.sub.2-C.sub.5-烯基或C.sub.2-C.sub.6-炔基，R.sub.10为氢、C.sub.1-C.sub.4-烷基或C.sub.1-C.sub.3-卤代烷基，R.sub.11为氢、C.sub.1-C.sub.4-烷基、C.sub.1-C.sub.3-卤代烷基、C.sub.3-C.sub.5-烯基、C.sub.3-C.sub.5-炔基、苯基或苄基，R.sub.12与R.sub.1相同但独立，这些化合物与胺、碱金属基或碱土金属基或季铵基的盐具有良好的前和后除草和植物生长调节性能。
• N-(cyclopropyl-pyrimidinyl-N'-(aryl-sulfonyl) ureas having herbicidal
  申请人：Ciba-Geigy Corporation

  公开号：US04600428A1

  公开（公告）日：1986-07-15

  N-(Cyclopropyl-pyrimidinyl)-N'-aryl-sulfonyl ureas of the formula ##STR1## wherein Ar is a phenyl group ##STR2## or a naphthyl group and Q is a group X-A or R.sub.3, A is alkynyl, alkyl which is unsubstituted or substituted by halogen, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkoxy, haloalkylthio, haloalkylsulfinyl or haloalkylsulfonyl, or alkenyl which is unsubstituted or substituted by the substituents given above for alkyl, or A is a phenyl or benzyl group, E is methine, X is oxygen, sulfur, or a sulfinyl or sulfonyl bridge, Z is oxygen or sulfur, R.sub.1 is hydrogen, alkyl or alkoxy, R.sub.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, amino, alkylamino, di-alkylamino, cycloalkyl or alkoxyalkyl, R.sub.3 is hydrogen, halogen, alkyl, alkenyl, haloalkyl, --CO--NR.sub.8 R.sub.9, --CN, --COR.sub.10, --NR.sub.1 R.sub.7 or --NR.sub.1 --COR.sub.12, R.sub.4 is hydrogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy, halogen, or alkoxyalkyl, R.sub.5 is independently selected from the same groups as R.sub.3 or --X--R.sub.6, R.sub.6 and R.sub.7 are each alkyl, alkenyl or alkynyl, R.sub.8 and R.sub.9 independently of one another are each hydrogen, alkyl, alkenyl or alkynyl, R.sub.10 is hydrogen, alkyl or haloalkyl, R.sub.11 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, phenyl or benzyl, and R.sub.12 is the same as R.sub.1 but independent thereof, and the salts of these compounds with amines, metal bases, or quaternary ammonium bases, have good herbicidal and plant-growth-regulating properties.

  该化合物为N-(环丙基嘧啶基)-N'-芳基磺酰脲，其分子式为##STR1##其中Ar为苯基##STR2##或萘基，Q为X-A或R.sub.3基团，A为炔基、未取代或取代的烷基，其取代基为卤素、烷氧基、烷硫基、烷基亚砜基、烷基磺酰基、卤代烷氧基、卤代烷硫基、卤代烷基亚砜基或卤代烷基磺酰基，或为未取代或取代的烯基，其取代基与烷基相同，或A为苯基或苄基，E为亚甲基，X为氧、硫或亚砜基或磺酰基桥，Z为氧或硫，R.sub.1为氢、烷基或烷氧基，R.sub.2为卤素、烷基、卤代烷基、烷氧基、卤代烷氧基、氨基、烷基氨基、二烷基氨基、环烷基或烷氧基烷基，R.sub.3为氢、卤素、烷基、烯基、卤代烷基、--CO--NR.sub.8 R.sub.9、--CN、--COR.sub.10、--NR.sub.1 R.sub.7或--NR.sub.1 --COR.sub.12，R.sub.4为氢、烷基、烷氧基、烷硫基、卤代烷基、卤代烷氧基、卤素或烷氧基烷基，R.sub.5独立于R.sub.3，可为与R.sub.3相同的基团或--X--R.sub.6，R.sub.6和R.sub.7均为烷基、烯基或炔基，R.sub.8和R.sub.9相互独立地为氢、烷基、烯基或炔基，R.sub.10为氢、烷基或卤代烷基，R.sub.11为氢、烷基、卤代烷基、烯基、炔基、苯基或苄基，R.sub.12与R.sub.1相同但不受其影响，这些化合物与胺、金属碱或季铵盐的盐具有良好的除草和植物生长调节作用。
• Verwendung von Triazin-Derivaten zum Schützen von Mais- und Sorghumpflanzen
  申请人：CIBA-GEIGY AG

  公开号：EP0130939A1

  公开（公告）日：1985-01-09

  Es werden Triazin-Derivate der Formel I worm R1, und R2 und R, unabhängig voneinander C1-C5-Alkyl, welches unsubstituiert oder durch C3-C6-Cycloalkyl monosubstituiert oder durch Halogen ein- oder mehrfach substituiert ist, C3-C6-Cycloalkyl, welches unsubstituiert oder ein- oder mehrfach durch Halogen substituiert ist, bedeuten, oder einer der Substituenten R1, R2 und R3 auch für Halogen oder - NR4R5 steht, worin R4 Wasserstoff oder C, - C5- Alkyl und R5 Wasserstoff, C1-C5-Alkyl, Monochloracetyl oder Dichloracetyl bedeuten, beschrieben. Die Triazin-Derivate werden zum Schützen von Mais- und Sorghumpflanzen gegen schädigende Wirkungen von herbiziden Chloracetaniliden und -amiden eingesetzt.

  式 I 的三嗪衍生物 其中 R1、R2 和 R 相互独立地为未被 C3-C6 环烷基取代或被 C3-C6 环烷基单取代或被卤素单取代或多取代的 C1-C5 烷基，未被卤素取代或被卤素单取代或多取代的 C3-C6 环烷基、或取代基 R1、R2 和 R3 中的一个也是卤素或-NR4R5，其中 R4 是氢或 C、-C5-烷基，R5 是氢、C1-C5-烷基、一氯乙酰基或二氯乙酰基。三嗪衍生物用于保护玉米和高粱植物免受除草剂氯乙酰苯胺和酰胺的损害。
• N-(Cyclopropyl-triazinyl- und -pyrimidinyl)-N'-(arylsulfonyl)harnstoffe mit herbizider Wirkung
  申请人：CIBA-GEIGY AG

  公开号：EP0108708B1

  公开（公告）日：1989-06-14
• US4523947A
  申请人：——

  公开号：US4523947A

  公开（公告）日：1985-06-18