Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs<sub>8</sub>Zn<sub>18</sub>Sb<sub>28</sub> and Cs<sub>8</sub>Cd<sub>18</sub>Sb<sub>28</sub>
作者:Bryan Owens-Baird、Philip Yox、Shannon Lee、Xian B. Carroll、Suyin Grass Wang、Yu-Sheng Chen、Oleg I. Lebedev、Kirill Kovnir
DOI:10.1039/d0sc03846f
日期:——
Giant clathrate supercell driven by ordering of Zn/Sb bonding in the framework and Cs-guest vacancies is found in unconventional clathrate Cs8Zn18Sb28.