bis(4-chlorodimethylsilabutyl)dichlorosilane | 59718-65-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(4-chlorodimethylsilabutyl)dichlorosilane
• 英文别名: dichloro-bis-[3-(chloro-dimethyl-silanyl)-propyl]-silane；[(Dichlorosilanediyl)di(propane-3,1-diyl)]bis[chloro(dimethyl)silane]；dichloro-bis[3-[chloro(dimethyl)silyl]propyl]silane
• CAS: 59718-65-9
• 化学式: C₁₀H₂₄Cl₄Si₃
• 分子量: 370.369
• InChiKey: DYOABQNHZQKZID-UHFFFAOYSA-N

物化性质

• 沸点：
  348.4±27.0 °C(Predicted)
• 密度：
  1.069±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.57
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(4-chlorodimethylsilabutyl)dichlorosilane 在 叔丁基锂 作用下， 以 正戊烷 为溶剂， 生成 3,9-ditert-butyl-12,12,19,19-tetramethyl-6,12,19-trisilatrispiro[4.0.0.47.46.45]nonadeca-1,3,8,10-tetraene
  参考文献：
  名称：

  ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: syntheses, crystal structures and properties as olefin polymerization catalysts

  摘要：

  Chiral ansa-zirconocene complexes with a trimethylene link between the Si bridge atom and an alpha-position of each C-5 ring ligand were prepared; two representatives, with i-propyl and t-butyl groups as beta-substituents, were structurally characterized, The properties of these complexes with respect to MAO-activated propene polymerization were studied in comparison with those of their Me(2)Si-bridged analogs. The t-butyl-substituted spirosilane complex gives a polymer with relatively high content of 3,1-insertions. These increased regioirregularities appear to be associated with decreased coordination gap aperture and increased lateral extension angles of the spirosilane-bridged zirconocene complexes; this notion is supported by a molecular-mechanics analysis of alternative olefin-insertion transition states.

  DOI：

  10.1016/0022-328x(95)06073-6
• 作为产物：
  描述：

  二甲基一氯硅烷 、 二烯丙基二氯硅烷 在 platinum on activated charcoal 作用下， 以 乙醚 为溶剂， 反应 48.0h， 以87%的产率得到bis(4-chlorodimethylsilabutyl)dichlorosilane
  参考文献：
  名称：

  ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: syntheses, crystal structures and properties as olefin polymerization catalysts

  摘要：

  Chiral ansa-zirconocene complexes with a trimethylene link between the Si bridge atom and an alpha-position of each C-5 ring ligand were prepared; two representatives, with i-propyl and t-butyl groups as beta-substituents, were structurally characterized, The properties of these complexes with respect to MAO-activated propene polymerization were studied in comparison with those of their Me(2)Si-bridged analogs. The t-butyl-substituted spirosilane complex gives a polymer with relatively high content of 3,1-insertions. These increased regioirregularities appear to be associated with decreased coordination gap aperture and increased lateral extension angles of the spirosilane-bridged zirconocene complexes; this notion is supported by a molecular-mechanics analysis of alternative olefin-insertion transition states.

  DOI：

  10.1016/0022-328x(95)06073-6

文献信息

• Gar,T.K. et al., Journal of general chemistry of the USSR, 1976, vol. 46, p. 835 - 839
  作者：Gar,T.K. et al.

  DOI：——

  日期：——
• ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: syntheses, crystal structures and properties as olefin polymerization catalysts
  作者：Stefan Mansel、Ursula Rief、Marc-Heinrich Prosenc、Robin Kirsten、Hans-Herbert Brintzinger

  DOI：10.1016/0022-328x(95)06073-6

  日期：1996.4

  Chiral ansa-zirconocene complexes with a trimethylene link between the Si bridge atom and an alpha-position of each C-5 ring ligand were prepared; two representatives, with i-propyl and t-butyl groups as beta-substituents, were structurally characterized, The properties of these complexes with respect to MAO-activated propene polymerization were studied in comparison with those of their Me(2)Si-bridged analogs. The t-butyl-substituted spirosilane complex gives a polymer with relatively high content of 3,1-insertions. These increased regioirregularities appear to be associated with decreased coordination gap aperture and increased lateral extension angles of the spirosilane-bridged zirconocene complexes; this notion is supported by a molecular-mechanics analysis of alternative olefin-insertion transition states.