1-(4-vinylbenzyl)piperidine | 4072-75-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-(4-vinylbenzyl)piperidine
• 英文别名: 4-(N-piperidinomethyl) styrene；1-[(4-ethenylphenyl)methyl]piperidine
• CAS: 4072-75-7
• 化学式: C₁₄H₁₉N
• 分子量: 201.312
• InChiKey: LHYKNHIVFLHRLF-UHFFFAOYSA-N

物化性质

• 沸点：
  130-131 °C(Press: 6.7 Torr)
• 密度：
  0.997±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319

反应信息

• 作为反应物：
  描述：

  1-(4-vinylbenzyl)piperidine 、 溴甲烷 以92%的产率得到
  参考文献：
  名称：

  TOROSYAN, G. O.;PARAVYAN, S. L.;MKRTCHYAN, A. T.;POGOSYAN, G. M.;BABAYAN,+, ARM. XIM. ZH., 1982, 35, N 10, 640-644

  摘要：

  DOI：
• 作为产物：
  描述：

  piperidin-1-yl(4-vinylphenyl)methanethione 在 五羰基溴化锰(I) 、 氢气 、 三乙胺 、 copper(I) bromide 作用下， 100.0 ℃ 、3.0 MPa 条件下， 以95 %的产率得到1-(4-vinylbenzyl)piperidine
  参考文献：
  名称：

  硫代酰胺的锰催化加氢脱硫

  摘要：

  开发了硫代酰胺的第一个锰催化氢化脱硫，以选择性地裂解 C=S 键。值得注意的是，在这种基于锰的方案中，醛、酮、砜甚至硝基等官能团可以得到前所未有的耐受性，尽管它们对还原条件很敏感。

  DOI：

  10.1002/anie.202215963

文献信息

• Aerobic Oxidation of Amines Catalyzed by Polymer-Incarcerated Au Nanoclusters: Effect of Cluster Size and Cooperative Functional Groups in the Polymer
  作者：Hiroyuki Miyamura、Masataka Morita、Takeshi Inasaki、Shū Kobayashi

  DOI：10.1246/bcsj.20100300

  日期：2011.6.15

  Aerobic oxidation reaction of amines to imines catalyzed by polymer-incarcerated Au nanoclusters (PI-Au) was developed. The effect of cluster size for this oxidation reaction was carefully examined...

  开发了由聚合物包埋的 Au 纳米团簇 (PI-Au) 催化的胺到亚胺的有氧氧化反应。仔细检查了簇大小对这种氧化反应的影响......
• Functionalized monomers for synthesis of rubbery polymers
  申请人：——

  公开号：US20040063884A1

  公开（公告）日：2004-04-01

  The present invention relates to a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one functionalized monomer of the structural formula: 1 wherein the R′ groups in repeat units and in different repeat units can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 4 carbon atoms, wherein x represents an integer from 1 to about 10, and wherein the R groups in repeat units and in different repeat units can be the same or different and represent alkyl groups containing from 1 to about 10 carbon atoms or alkoxy groups containing from 1 to about 10 carbon atoms.

  本发明涉及一种橡胶聚合物，其由以下重复单元组成：（1）至少一种共轭二烯单体，和（2）至少一种结构式为的官能化单体，其中重复单元中的R′基和不同重复单元中的R′基可以相同或不同，代表氢原子或含有1至约4个碳原子的烷基基团，其中x代表从1到约10的整数，重复单元中的R基和不同重复单元中的R基可以相同或不同，代表含有1至约10个碳原子的烷基基团或含有1至约10个碳原子的烷氧基团。
• CONJUGATED DIENE POLYMER PRODUCTION METHOD, AND CONJUGATED DIENE POLYMER COMPOSITION PRODUCTION METHOD
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20150005440A1

  公开（公告）日：2015-01-01

  A method for producing a conjugated diene-based polymer is provided, in which compounds of formulas (2) and (3) and a conjugated diene compound are polymerized using a compound of formula (1), and then a compound containing a nitrogen atom and/or a silicon atom is reacted with an active end of the polymer formed via the polymerization, R 11 represents a hydrocarbylene group, R 12 and R 13 each represent an optionally substituted hydrocarbyl group or a trihydrocarbylsilyl group, or R 12 is bonded to R 3 and the group in which R 12 is bonded to R 13 represents a hydrocarbylene group optionally having a nitrogen and/or oxygen atom, —Si(R 14 ) 2 —(CH 2 ) x —Si(R 14 ) 2 —, or —Si(R 15 ) 2 —(CH 2 ) y − , and M represents an alkali metal atom, E 2 -A 2 (2) E 3 -A 3 (3) E 2 and E 3 each represent a hydrocarbyl group having a polymerizable carbon-carbon double bond, A 2 represents a substituted amino group or a nitrogen-containing heterocyclic group, and A 3 represents a substituted silyl group.

  提供一种制备基于共轭二烯的聚合物的方法，其中使用式(1)的化合物聚合式(2)和(3)的化合物以及共轭二烯化合物，然后使用含有氮原子和/或硅原子的化合物与通过聚合形成的聚合物的活性末端反应。其中，R11代表烃基烷基，R12和R13分别代表可选取代的烃基或三烷基硅基，或者R12与R3结合，R12与R13结合的基团可选地具有氮和/或氧原子，-Si(R14)2-(CH2)x-Si(R14)2-，或-Si(R15)2-(CH2)y-，M代表碱金属原子，E2-A2(2)E3-A3(3)中，E2和E3分别代表具有可聚合碳-碳双键的烃基，A2代表取代的氨基或含氮杂环基团，A3代表取代的硅基。
• Styrenic block copolymer and process for producing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0570932A2

  公开（公告）日：1993-11-24

  There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135°C) which comprises highly syndiotactic styrenic-polymer segments and 10⁻⁴ to 10 mol% of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerizaiton reaction. The above-disclosed styrenic block copolymer and the resin composition exhibit excellent compatibiity and adhesivenesss, and the multi-layer material is expected to find a wide range of applications in automobile parts, electrical and electronic parts as well as film, sheet, etc.

  本发明公开了一种苯乙烯嵌段共聚物，其粘度降低至 0.01 至 20 dl/g （在 135°C 的 1，2，4-三氯苯中为 0.05 g/l in 1,2,4-trichlorobenzene at 135°C)的苯乙烯嵌段共聚物，它由高度齐聚的苯乙烯聚合物段和 10-⁴ 至 10 摩尔%的含杂原子的苯乙烯聚合物段组成；一种树脂组合物，它由上述苯乙烯嵌段共聚物和一种热塑性树脂、一种无机填料或一种有机填料组成；一种多层材料，其中至少一层由上述苯乙烯嵌段共聚物或上述树脂组合物构成；以及一种生产上述苯乙烯嵌段共聚物的工艺，该工艺包括在特定催化剂存在下聚合苯乙烯单体，并加入含杂原子的苯乙烯单体以连续进行共聚反应。上述苯乙烯嵌段共聚物和树脂组合物具有优异的相容性和粘合性，多层材料有望广泛应用于汽车部件、电子电气部件以及薄膜、板材等领域。
• PROCESS FOR PRODUCING FUNCTIONAL STYRENE COPOLYMER AND FUNCTIONAL STYRENE COPOLYMER
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1219649A1

  公开（公告）日：2002-07-03

  A process for producing a styrenic copolymer having a functional group and the syndiotactic configuration is provided. The process comprises bringing a metal compound into interaction with a vinyl compound having a functional group to mask the functional group and copolymerizing the vinyl compound having the masked functional group with a styrenic compound in the presence of a polymerization catalyst comprising (A) a transition metal compound, (B) at least one compound selected from compounds having oxygen and compounds which can form ionic complex compounds by reaction with the transition metal compound and (C) an organometallic compound. A styrenic copolymer which is a random, block or graft copolymer, preferably a random copolymer, of a vinyl compound having a functional group and a styrenic compound and has the repeating units derived from the styrenic compound having the syndiotactic configuration can be produced efficiently. The above styrenic random copolymer exhibits excellent physical properties such as excellent adhesion with various adhesives and excellent compatibility with various rubbers and is advantageously used for various applications as various types of molded articles.

  本发明提供了一种生产具有官能团和辛二构造的苯乙烯共聚物的工艺。该工艺包括使金属化合物与具有官能团的乙烯基化合物相互作用以掩蔽官能团，并在聚合催化剂存在下使具有被掩蔽官能团的乙烯基化合物与苯乙烯化合物共聚，聚合催化剂包括(A)过渡金属化合物，(B)至少一种选自具有氧的化合物和通过与过渡金属化合物反应可形成离子络合物的化合物的化合物，以及(C)有机金属化合物。一种苯乙烯共聚物是由具有官能团的乙烯基化合物和苯乙烯化合物组成的无规、嵌段或接枝共聚物，最好是无规共聚物，其重复单元来自具有联合构型的苯乙烯化合物。 上述苯乙烯类无规共聚物具有优异的物理性能，例如与各种粘合剂具有优异的粘合性，与各种橡胶具有优异的相容性，可用于各种成型制品。