Ethylenedithio(dimethyl)tetrathiafulvalene | 96521-23-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: Ethylenedithio(dimethyl)tetrathiafulvalene
• 英文别名: 2-(4,5-Dimethyl-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine
• CAS: 96521-23-2
• 化学式: C₁₀H₁₀S₆
• 分子量: 322.585
• InChiKey: GHTYQWZOPPAYOY-UHFFFAOYSA-N

物化性质

• 熔点：
  169-170 °C(Solv: benzene (71-43-2))
• 沸点：
  391.9±42.0 °C(Predicted)
• 密度：
  1.60±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  152
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  7,7,8,8-四氰基对苯二醌二甲烷 、 Ethylenedithio(dimethyl)tetrathiafulvalene 生成 2-[4-(dicyanomethylidene)cyclohexa-2,5-dien-1-ylidene]propanedinitrile;2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine
  参考文献：
  名称：

  TATEMITSU, HITOSHI;NISHIKAWA, ETSUSHI;SAKATA, YOSHITERU;MISUMI, SOICHI, J. CHEM. SOC. CHEM. COMMUN., 1985, N 3, 106-107

  摘要：

  DOI：
• 作为产物：
  描述：

  (4,5-dimethyl-1,3-dithiol-2-yl)-dimethoxyphosphane 以15%的产率得到
  参考文献：
  名称：

  Fourmigue Marc, Krebs Frederik C., Larsen Jan, Synthesis, (1993) N 5, S 509-513

  摘要：

  DOI：

文献信息

• Synthesis of unsymmetrical tetrathiafulvalenes and electrical conductivities of their tetracyanoquinodimethane complexes
  作者：Hitoshi Tatemitsu、Etsushi Nishikawa、Yoshiteru Sakata、Soichi Misumi

  DOI：10.1039/c39850000106

  日期：——

  The preparation of some unsymmetrical tetrathiafulvalenes and the electrical conductivities of their charge transfer complexes with tetracyanoquinodimethane (TCNQ) are described; the ethylenedithio(trimethylene)tetrathiafulvalene–TCNQ complex exhibited higher conductivity than complexes of tetrathiafulvalene, tetramethyltetrathia-fulvalene, and hexamethylenetetrathiafulvalene with TCNQ.

  描述了一些不对称四硫富瓦烯的制备及其与四氰基喹二甲烷（TCNQ）的电荷转移配合物的电导率；乙二硫（三亚甲基）四硫富瓦烯-TCNQ配合物比四硫富瓦烯，四甲基四硫富瓦烯和六亚甲基四硫富瓦烯与TCNQ的配合物具有更高的电导率。
• Electrochemical synthesis of unsymmetrical tetrathiafulvalene derivatives. Electrocrystallization of their radical-cation salts
  作者：J. P. Morand、L. Brzezinski、C. Manigand

  DOI：10.1039/c39860001050

  日期：——

  A new synthesis of some unsymmetrical tetrathiafulvalene molecules using electrochemical methods is described; ethylenedithio(dimethyl)tetrathiafulvalene and (ethylenedithio)benzotetrathiafulvalene have been obtained and their radical-cation salts prepared by electrocrystallization.

  描述了使用电化学方法合成一些不对称四硫富瓦烯分子的新方法。已经获得了乙二硫（二甲基）四硫富瓦烯和（乙二硫基）苯并四硫富瓦烯，并通过电结晶制备了它们的自由基阳离子盐。
• Synthesis of unsymmetrically substituted TTF derivatives via the “phosphonate way”. Some investigations on the scope of the method
  作者：H.J. Cristau、F. Darviche、M.-T. Babonneau、J.-M. Fabre、E. Torreilles

  DOI：10.1016/s0040-4020(99)00795-4

  日期：1999.11

  The scope and limitations of the synthesis of unsymmetrically substituted TTF derivatives via the “phosphonate way” was investigated using as precursors 1,3-dithiol-2-yl-phosphonates and 1,3-dithiol-2-yliden iminium salts with various substitutents on the dithiole cycles.

  研究了通过“膦酸酯方式”合成不对称取代的TTF衍生物的范围和局限性，并使用了具有不同取代基的1,3-二硫醇-2-基膦酸酯和1,3-二硫醇-2-嘧啶亚胺盐作为前体。二硫醇循环。
• A Selective Synthesis of Ethylenedithiotetrathiafulvalene (EDT-TTF) and Related Molecules
  作者：Marc Fourmigué、Frederik C. Krebs、Jan Larsen

  DOI：10.1055/s-1993-25894

  日期：——

  A selective synthesis of the ethylenedithiotetrathiafulvalene (EDT-TTF), involving a Wittig-Horner reaction is described and extended to related unsymmetrically substituted tetrathiafulvalenes, whose electrochemical properties are reported.

  描述了涉及 Wittig-Horner 反应的亚乙基二硫四硫富瓦烯 (EDT-TTF) 的选择性合成，并将其扩展到相关的不对称取代的四硫富瓦烯，并报道了其电化学性质。
• Laversanne, R.; Dupart, E.; Delhaes, P., Molecular Crystals and Liquid Crystals (1969-1991), 1986, vol. 137, p. 179 - 190
  作者：Laversanne, R.、Dupart, E.、Delhaes, P.

  DOI：——

  日期：——