Dimethyl-tetrathiafulvalen | 54397-96-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: Dimethyl-tetrathiafulvalen
• 英文别名: 4,4'-Dimethyltetrathiafulvalene；(2Z)-4-methyl-2-(4-methyl-1,3-dithiol-2-ylidene)-1,3-dithiole
• CAS: 54397-96-5
• 化学式: C₈H₈S₄
• 分子量: 232.416
• InChiKey: KTUWYNVNQFNGBX-FPLPWBNLSA-N

物化性质

• 沸点：
  258.1±40.0 °C(Predicted)
• 密度：
  1.445±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Dimethyl-tetrathiafulvalen 、 7,7,8,8-四氰基对苯二醌二甲烷 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Fabre, Jean-Marc; Torreilles, Eliane; Vigroux, Michel, Journal of Chemical Research, Miniprint, 1980, # 11, p. 4572 - 4592

  摘要：

  DOI：
• 作为产物：
  描述：

  在 三乙胺 作用下， 以 乙腈 为溶剂， 生成 Dimethyl-tetrathiafulvalen
  参考文献：
  名称：

  Fabre, Jean-Marc; Torreilles, Eliane; Vigroux, Michel, Journal of Chemical Research, Miniprint, 1980, # 11, p. 4572 - 4592

  摘要：

  DOI：

文献信息

• Bis- and tetrakis-(diphenylphosphino) tetrathiafulvalenes as precursors of redox-active organic—inorganic polymeric networks
  作者：M. Fourmigué、C.E. Uzelmeier、K. Boubekeur、S.L. Bartley、K.R. Dunbar

  DOI：10.1016/s0022-328x(96)06637-5

  日期：1997.2

  Lithiation of the (Z)-, (E)-dimethyltetrathiafulvalene mixture and subsequent reaction with ClPPh2 afford (Z)- and (E)-dimethyl-bis(diphenylphosphino)tetrathiafulvalene which are separated by fractional recrystallization. The identity of(Z)-P-2 has been ascertained by its X-ray crystal structure determination. By similar methods, tetrakis(diphenylphosphino)tetrathiafulvalene (P-4) is obtained from the tetrathiafulvalene tetralithium derivative. Cyclic voltammetry experiments reveal that the new compounds oxidize reversibly in two one-electron steps to the radical cation and dication. Reaction of o-P-2 with the dinuclear complex [Rh-2(NCCH3)(10)](BF4)(4) has been investigated and found to produce the square-planar Rh(I) compound [(o-P-2)(2)Rh][BF4]. The identity of the product has been confirmed by X-ray crystallography, FAB-MS, elemental analysis, and NMR spectroscopy. Several reactions of solvated cations were also performed, all of which appear to lead to products with o-P-2 and P-4 ligands.
• Noncoupling synthesis of tetrathiafulvalenes
  作者：R. R. Schumaker、V. Y. Lee、E. M. Engler

  DOI：10.1021/jo00177a041

  日期：1984.2
• POLYMER, SEMICONDUCTOR FILM, ELECTRODE, ELECTRODE ACTIVE MATERIAL, ELECTROCHEMICAL ELEMENT AND ELECTRICITY STORAGE DEVICE
  申请人：Panasonic Corporation

  公开号：EP2308912B1

  公开（公告）日：2016-01-06
• US8481674B2
  申请人：——

  公开号：US8481674B2

  公开（公告）日：2013-07-09