sambacolignoside | 114449-12-6

分子结构分类

有机化合物 - 木脂素、新木脂素和相关化合物 - 木脂素苷

中文名称

——

中文别名

——

英文名称

sambacolignoside

英文别名

methyl (4S,5E,6S)-4-[2-[[(2R,3S,4S,5R,6S)-6-[[(3R,3aS,6S,6aR)-3,6-bis(4-hydroxy-3-methoxyphenyl)-3,4,6,6a-tetrahydro-1H-furo[3,4-c]furan-3a-yl]oxy]-3,4,5-trihydroxyoxan-2-yl]methoxy]-2-oxoethyl]-5-ethylidene-6-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4H-pyran-3-carboxylate

CAS

114449-12-6

化学式

C₄₃H₅₄O₂₂

mdl

——

分子量

922.889

InChiKey

URBPIXMUXQEKHZ-AKZJQTFZSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

-2.2
重原子数：

65
可旋转键数：

16
环数：

7.0
sp3杂化的碳原子比例：

0.58
拓扑面积：

318
氢给体数：

9
氢受体数：

22

上下游信息

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(+)-1-hydroxy-pinoresinol-1-β-D-glucoside	81495-71-8	C₂₆H₃₂O₁₂	536.533
木樨榄苷-11-甲酯	4-carboxymethyl-5-ethylidene-6-(3,4,5-trihydroxy-6-hydroxymethyl-tetrahydropyran-2-yloxy)-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester	60539-23-3	C₁₇H₂₄O₁₁	404.371

反应信息

作为反应物：

描述：

sambacolignoside 生成木樨榄苷-11-甲酯、 (+)-1-hydroxy-pinoresinol-1-β-D-glucoside

参考文献：

名称：

Tanahashi, Takao; Nagakura, Naotaka; Inoue, Kenichiro, Chemical and pharmaceutical bulletin, 1987, vol. 35, # 12, p. 5032 - 5035

摘要：

DOI：

点击查看最新优质反应信息

文献信息

Tanahashi, Takao; Nagakura, Naotaka; Inoue, Kenichiro, Chemical and pharmaceutical bulletin, 1987, vol. 35, # 12, p. 5032 - 5035

作者：Tanahashi, Takao、Nagakura, Naotaka、Inoue, Kenichiro、Inouye, Hiroyuki、Shingu, Tetsuro

DOI：——

日期：——

同类化合物

鹅掌楸碱罗汉松树脂酚-4'-O-β-龙胆二糖苷络石苷元-4'-O-BETA-龙胆二糖苷络石苷牛蒡苷柑属苷B 松脂醇二葡萄糖苷松脂醇-4-O-beta-D-吡喃葡萄糖苷松脂醇 beta-D-吡喃葡萄糖苷木須皮苷异落叶松脂素-9'-O-beta-D-吡喃葡萄糖苷开环异落叶松脂素BETA-D-葡糖苷地菲林葡萄糖苷南烛木糖甙刺五加苷D 刺五加甙E 刺五加甙 E 刺五加提取物丁香树脂醇双葡萄糖苷 b-D-吡喃葡萄糖苷,4-[(1R,2R)-1,3-二羟基-2-[4-[(1E)-3-羟基-1-丙烯-1-基]-2-甲氧基苯氧基]丙基]-2-甲氧苯基 Ssioriside; (2S,3S)-4-羟基-2,3-双[(4-羟基-3,5-二甲氧基苯基)甲基]丁基 beta-D-吡喃木糖苷 8-羟基松脂醇二葡萄糖苷 8-O-(α-阿拉伯呋喃糖)-β-àpeltatin 4-(1,3-苯并二氧戊环-5-基)-9-[(2S,3R,4S,5R)-3,4-二甲氧基-5-[(2S,3R,4S,5S,6R)-3,4,5-三羟基-6-(羟基甲基)四氢吡喃-2-基]氧基四氢吡喃-2-基]氧基-6,7-二甲氧基-1H-苯并[f][2]苯并呋喃-3-酮 4-(1,3-苯并二氧戊环-5-基)-6,7-二甲氧基-9-[(2S,3R,4S,5S,6R)-3,4,5-三羟基-6-(羟基甲基)四氢吡喃-2-基]氧基-1H-苯并[f][2]苯并呋喃-3-酮 3-[2,3-二氢-6-羟基-2-(1-羟基-1-甲基乙基)苯并呋喃-5-基]-8-(beta-D-吡喃葡萄糖基)-2,3-二氢-5,7-二羟基-4H-1-苯并吡喃-4-酮 2,3-双(3-甲氧基-4-羟基苄基)丁烷-1,4-二醇 1,4-二葡萄糖甙 (3S,4R)-4-(苯并[1,3]二氧杂环戊烯-5-基甲基)-3-[(S)-[(2R,3R,4S,5R,6R)-3,4,5-三羟基-6-(羟基甲基)四氢吡喃-2-基]氧基-(3,4,5-三甲氧基苯基)甲基]四氢呋喃-2-酮 (3R,4S)-3-[[4-(beta-D-吡喃葡萄糖基氧基)-3-甲氧基苯基]甲基]-4,5-二氢-4-[(4-羟基-3-甲氧基苯基)甲基]呋喃-2(3H)-酮 (-)-异落叶松脂素-9'-O-BETA-D-吡喃葡萄糖苷 (+)-南烛木树脂酚9'-O-葡萄糖甙 4-O-[2"-O-[6-[4-hydroxypiperidin-1-yl]hexyl]-3",4"-di-O-methyl-β-D-xylopyranosyl]diphyllin 4-O-[2"-O-[8-[4-hydroxypiperidin-1-yl]octyl]-3",4"-di-O-methyl-β-D-xylopyranosyl]diphyllin phyllanthusmin B (2S,3R,4S,5S)-2-((9-(benzo[d][1,3]dioxol-5-yl)-6,7-dimethoxy-1,3-dihydronaphtho[2,3-c]furan-4-yl)oxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate (2S,3R,4S,5S)-2-((9-(benzo[d][1,3]dioxol-5-yl)-6,7-dimethoxy-3-oxo-1,3-dihydronaphtho[2,3-c]furan-4-yl)oxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate tri-O-acetylpatentiflorin A phyllanthusmin D 2")-β-D-xylopyranosyl-(1""->5")-β-D-apiofuranosyl]diphyllin">4-O-[α-L-arabinopyranosyl-(1"'->2")-β-D-xylopyranosyl-(1""->5")-β-D-apiofuranosyl]diphyllin (+)-syringaresinol 4-O-β-D-glucopyranosyl(1->6)-β-D-glucopyranoside liriodendrin 4-O-[6-O-(5-O-sinapoyl-β-D-apiofuranosyl)-β-D-glucopyranosyl]-(+)-(7S,7'S,8R,8'R)-4'-hydroxy-3,3',5,5'-tetramethoxy-7,9':7',9-diepoxylignane 4-O-[3″,4″-di-O-methyl-β-d-xylopyranosyl]diphyllin (+)-medioresinol di-O-β-D-glucopyranoside (-)-(8S,8'R)-4,4'-dihydroxy-3,3',5'-trimethoxylignan-4'-O-β-D-glucopyranoside (-)-nectandrin B-β-D-glucopyranoside (3S)-4''-O-β-D-Glucopyranosylhinokiresinol 4'-O-β-D-glucopyranosylhinokiresinol (7R,8R)-4,7,9,3′,9′-pentahydroxy-3-methoxy-8,4′-oxyneolignan-3′-O-β-D-glucopyranoside (7S,7'R,8R,8'S)-7'-butoxy-7,9'-epoxy-4,4',9-trihydroxy-3,3'-dimethoxylignane 9-O-β-D-glucopyranoside