N-aminocarbamodithioate;nickel(2+) | 53989-86-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: N-aminocarbamodithioate;nickel(2+)
• CAS: 53989-86-9；32268-94-3；198059-88-0；34873-65-9
• 化学式: C₂H₆N₄NiS₄
• 分子量: 273.05
• InChiKey: HYMAFHMYSJZJIR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.44
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  142
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  四甲基氯化铵 、 N-aminocarbamodithioate;nickel(2+) 以 sodium hydroxide 为溶剂， 生成
  参考文献：
  名称：

  二硫代咔唑酸的金属配合物

  摘要：

  摘要制备并表征了许多二硫代氨基甲酸及其3-苯基和3,3-二甲基衍生物的金属配合物。对于每个配体均获得了ML2或ML3类型的中性复合物，二硫代咔唑的复合物观察到了NS键，而在其取代类似物中观察到了SS键。讨论了这些配合物的立体化学及其红外和电子吸收光谱的变化。使二硫代咔唑酸的某些配合物与碱反应，得到阴离子物质，该阴离子物质已被分离为其四甲基铵盐。

  DOI：

  10.1016/s0020-1693(00)83630-0
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 potassium dithiocarbazate 以 乙醇 为溶剂， 以70%的产率得到N-aminocarbamodithioate;nickel(2+)
  参考文献：
  名称：

  COMPLEXES OF TRANSITION AND NONTRANSITION METALS OF DITHIOCARBAZATE ION AND THEIR BIOLOGICAL ACTIVITIES

  摘要：

  The complexation of the dithiocarbazate ion (DTCA(-)) with various metal ions, viz., Sn(II)/(IV), Bi(III), Sb(III), U(VI), Zr(IV), Th(IV), AI(III), Ni(II), Zn(II), and Cu(II) was investigated. Most of the complexes were hexa-coordinated with the exception of Cu(II), Ni(II), and Zn(II) complexes that were four-coordinated, The biological properties of the metal complexes revealed that in general the complexes of nontransition metals were more effective against microorganisms than those of transition metals. In particular, [Sb(DTCA)Cl-2. 2H(2)O] and [AI(DTCA)Cl-2. 2H(2)O] were found to have strong antimicrobial activities. A minimum inhibitory concentration of 300 mug/mL was recorded for the above two complexes against Pseudomonas aeruginosa while that against Bacillus cereus was found to be 700 mug/mL. None of the complexes were cytotoxic.

  DOI：

  10.1081/sim-100001937