5lambda4,11-Dithia-4,6,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-1(12),2,4,5,7,9-hexaene-2,8-diamine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻二唑类
• 英文名称: 5lambda4,11-Dithia-4,6,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-1(12),2,4,5,7,9-hexaene-2,8-diamine
• 英文别名: 5λ4,11-dithia-4,6,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-1(12),2,4,5,7,9-hexaene-2,8-diamine
• 化学式: C₆H₄N₆S₂
• 分子量: 224.3
• InChiKey: FBNHFYCAVOJRGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  132
• 氢给体数：
  2
• 氢受体数：
  8

文献信息

• [EN] ORGANIC SEMICONDUCTORS<br/>[FR] SEMICONDUCTEURS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2017157782A1

  公开（公告）日：2017-09-21

  The invention relates to novel compounds containing one or more benzo[1,2-d;4,5-d']bisthiazole-4,8-diyl ("BBT") units, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the compounds, mixtures and formulations as organic semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these compounds, mixtures or formulations.

  该发明涉及含有一个或多个苯并[1,2-d;4,5-d']噻二唑-4,8-二基（"BBT"）单元的新化合物，以及其制备方法和在其中使用的底物或中间体，含有它们的混合物和配方，将这些化合物，混合物和配方作为有机半导体用于有机电子（OE）器件，特别是用于有机光伏（OPV）器件和有机光探测器（OPD），以及包含这些化合物，混合物或配方的OE、OPV和OPD器件。
• [EN] NAPHTHOINDACENODITHIOPHENES AND POLYMERS<br/>[FR] NAPHTOINDACÉNODITHIOPHÈNES ET POLYMÈRES
  申请人：BASF SE

  公开号：WO2017097924A1

  公开（公告）日：2017-06-15

  Polymers comprising at least one unit of formula1 and compounds of the formula 1' wherein, in formulae 1 and 1' n is 0, 1, 2, 3 or 4 mis 0, 1, 2, 3 or 4 X is at each occurrence selected from the group consisting of O, S, Se or Te, Q is at each occurrence selected from the group consisting of C, Si or Ge R is at each occurrence selected from the group consisting of hydrogen, C1-30-alkyl, C2-30-alkenyl, C2-30-alkynyl, C5-12-cycloalkyl, C6-18-aryl, R2, R2', R* are at each occurrence independently selected from the group consisting of hydrogen, C1-30-alkyl, C2-30-alkenyl, C2-30-alkynyl,C5-12-cycloalkyl, C6-18-aryl, 5 to 20 membered hetero-aryl, OR21, OC(O)-R21, C(O)-OR21, C(O)-R21, NR21R22, NR21-C(O)R22, C(O)-NR21R22, N[C(O)R21][C(O)R22], SR21, halogen, CN, SiRSisRSitRSiu and OH, L1 and L2 are independently from each other and at each occurrence selected from the group consisting of C6-30-arylene, 5 to 30 membered heteroarylene.

  聚合物包括至少一个式1的单元和式1'的化合物，其中，在式1和1'中，n为0、1、2、3或4，X在每次出现时从O、S、Se或Te中选择，Q在每次出现时从C、Si或Ge中选择，R在每次出现时从氢、C1-30-烷基、C2-30-烯基、C2-30-炔基、C5-12-环烷基、C6-18-芳基中选择，R2、R2'、R*在每次出现时独立地从氢、C1-30-烷基、C2-30-烯基、C2-30-炔基、C5-12-环烷基、C6-18-芳基、5至20个成员的杂芳基、OR21、OC(O)-R21、C(O)-OR21、C(O)-R21、NR21R22、NR21-C(O)R22、C(O)-NR21R22、N[C(O)R21][C(O)R22]、SR21、卤素、CN、SiRSisRSitRSiu和OH中选择，L1和L2相互独立且在每次出现时从C6-30-芳基、5至30个成员的杂芳基中选择。
• [EN] 1,3-DITHIOLO[5,6-F]BENZO-2,1,3-THIADIAZOLE OR 1,3-DITHIOLO[6,7-G]QUINOXALINE BASED ORGANIC SEMICONDUCTORS<br/>[FR] SEMI-CONDUCTEURS ORGANIQUES À BASE DE 1,3-DITHIOLO [5,6-F] BENZO -2,1,3-THIADIAZOLE OU 1,3-DITHIOLO [6,7-G] QUINOXALINE
  申请人：MERCK PATENT GMBH

  公开号：WO2018041768A1

  公开（公告）日：2018-03-08

  The invention relates to novel organic semiconducting (OSC) compounds containing one or more 1,3-dithiolo[5,6-f]benzo-2,1,3-thiadiazole ("DTBTz") or 1,3-dithiolo[6,7-g]quinoxaline ("DTQ") units or derivatives thereof, to methods for their preparation and educts or intermediates used therein, to compositions and formulations containing them, to the use of the compounds and compositions as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photodetectors (OPD), organic field effect transistors (OFET) and organic light emitting diodes (OLED), and to OE devices comprising these compounds or compositions.

  该发明涉及包含一个或多个1,3-二硫代[5,6-f]苯并-2,1,3-噻二唑（"DTBTz"）或1,3-二硫代[6,7-g]喹喔啉（"DTQ"）单元或其衍生物的新型有机半导体（OSC）化合物，以及其制备方法、用于制备的底物或中间体，包含它们的组合物和配方，将这些化合物和组合物作为有机半导体在有机电子（OE）设备中的使用，特别是在有机光伏（OPV）设备、钙钛矿基太阳能电池（PSC）设备、有机光探测器（OPD）、有机场效应晶体管（OFET）和有机发光二极管（OLED）的制备中的使用，以及包含这些化合物或组合物的OE设备。
• [EN] ORGANIC SEMICONDUCTING COMPOUNDS COMPRISING A TETRAAZAPYRENE CORE<br/>[FR] COMPOSÉS ORGANIQUES SEMI-CONDUCTEURS COMPRENANT UN NOYAU DE TÉTRAAZAYRÈNE
  申请人：MERCK PATENT GMBH

  公开号：WO2018029159A1

  公开（公告）日：2018-02-15

  The present invention relates to organic semiconducting compounds of formula (I) wherein X1 is C, Si or Ge; X2 is 0, S or Se; and X3 is N or P as well as to organic electronic devices comprising such organic semiconducting compounds. (I)

  本发明涉及公式（I）中的有机半导体化合物，其中X1为C、Si或Ge；X2为0、S或Se；X3为N或P，以及包含此类有机半导体化合物的有机电子器件。 (I)
• [EN] ORGANIC SEMICONDUCTING POLYMERS<br/>[FR] POLYMÈRES SEMI-CONDUCTEURS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2020161052A1

  公开（公告）日：2020-08-13

  The invention relates to novel photo-crosslinkable organic semiconducting (OSC) polymers, to methods for their preparation and educts or intermediates used therein, to compositions and formulations containing them, to the use of the polymers and compositions as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photo-detectors (OPD), organic field effect transistors (OFET)and organic light emitting diodes (OLED), and to OE, OPV, PSC, OPD, OFET and OLED devices comprising these polymers or compositions.

  本发明涉及一种新型光交联有机半导体（OSC）聚合物，以及其制备方法中使用的原料或中间体，包含它们的组合物和配方，将这些聚合物和组合物作为有机半导体在有机电子（OE）器件中使用或用于其制备，尤其是有机光伏（OPV）器件、钙钛矿太阳能电池（PSC）器件、有机光探测器（OPD）、有机场效应晶体管（OFET）和有机发光二极管（OLED），以及包含这些聚合物或组合物的OE、OPV、PSC、OPD、OFET和OLED器件。