1-(Thiazol-2-yl)-3-(3-(triethoxysilyl)propyl)urea | 1215207-66-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-(Thiazol-2-yl)-3-(3-(triethoxysilyl)propyl)urea
• 英文别名: 1-(1,3-Thiazol-2-yl)-3-(3-triethoxysilylpropyl)urea
• CAS: 1215207-66-1
• 化学式: C₁₃H₂₅N₃O₄SSi
• 分子量: 347.511
• InChiKey: YUKPDGITGDJZCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  22
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  110
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  terbium(III) nitrate hexahydrate 、 1-(Thiazol-2-yl)-3-(3-(triethoxysilyl)propyl)urea 以 乙醇 为溶剂， 生成 [Tb((C3H2NS)NHCONH(CH2)3Si(OC2H5)3)₃NO₃^-·H₂O]²⁺
  参考文献：
  名称：

  Thiazole derivative based terbium(III) covalent silica nanosphere and its sensing property

  摘要：

  Covalent cross-linked luminescent hybrid material including terbium complex and silica was prepared through a sol-gel process. Homogenous spherical morphology (similar to 40 nm) could be achieved and this nanomaterial exhibited remarkable green emissions. It presented highly selective and rapid fluorescence quenching to Cu2+ (detection limit 3.9 mu M) compared with Na+, K+, Ca2+, Mg2+, Al3+, Zn2+, Fe2+, Co2+, Ni2+, Mn2+, Cd2+, Pd2+, Ag+, and Hg+ in CH3CN/H2O (4/1). More importantly, it was found that this sensing material can be reused more than 5 cycles. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.07.034
• 作为产物：
  描述：

  、 异氰酸丙基三乙氧基硅烷 以70%的产率得到1-(Thiazol-2-yl)-3-(3-(triethoxysilyl)propyl)urea
  参考文献：
  名称：

  Thiazole derivative based terbium(III) covalent silica nanosphere and its sensing property

  摘要：

  Covalent cross-linked luminescent hybrid material including terbium complex and silica was prepared through a sol-gel process. Homogenous spherical morphology (similar to 40 nm) could be achieved and this nanomaterial exhibited remarkable green emissions. It presented highly selective and rapid fluorescence quenching to Cu2+ (detection limit 3.9 mu M) compared with Na+, K+, Ca2+, Mg2+, Al3+, Zn2+, Fe2+, Co2+, Ni2+, Mn2+, Cd2+, Pd2+, Ag+, and Hg+ in CH3CN/H2O (4/1). More importantly, it was found that this sensing material can be reused more than 5 cycles. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.07.034

文献信息

• ORGANOSILICON COMPOUNDS, PRODUCTION PROCESSES THEREOF, PRESSURE-SENSITIVE ADHESIVE COMPOSITIONS CONTAINING THE ORGANOSILICON COMPOUNDS, SELF-ADHESIVE POLARIZERS AND LIQUID CRYSTAL DISPLAYS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20130066014A1

  公开（公告）日：2013-03-14

  Organosilicon compounds are represented by the following formula: wherein R is a hydrolyzable group, R′ is an alkyl having 1 to 4 carbon atoms, A is an alkylene having 1 to 6 carbon atoms, X is O or S, Y is —NH— or S, L 1 and L 2 are C or N, Z and M are —NH—, O or S, R 1 to R 11 are H, alkyl having 1 to 6 carbon atoms, alkoxy or fluoroalkyl, or amino, m is 1 to 3, and n is 0 to 3. R 1 and R 2 or R 2 and R 3 may bonded together. R 5 and R 6 or R 9 and R 10 may directly bond together. R 4 and R 7 or R 8 and R 11 may form a ring skeleton. Their production processes, pressure-sensitive adhesive compositions, self-adhesive polarizers and LCDs are also disclosed.

  有机硅化合物的表示式如下：其中R是一个可水解的基团，R′是具有1至4个碳原子的烷基，A是具有1至6个碳原子的烷基，X是O或S，Y是—NH—或S，L1和L2是C或N，Z和M是—NH—、O或S，R1到R11是H、具有1至6个碳原子的烷基、烷氧基或氟烷基，或氨基，m为1至3，n为0至3。R1和R2或R2和R3可以相互连接。R5和R6或R9和R10可以直接相互连接。R4和R7或R8和R11可以形成一个环骨架。还公开了它们的生产过程、压敏胶粘剂组合物、自粘性偏光片和液晶显示器。
• Thiazole derivative based terbium(III) covalent silica nanosphere and its sensing property
  作者：Zhan Zhou、Yuhui Zheng、Qianming Wang

  DOI：10.1016/j.ica.2012.07.034

  日期：2013.1

  Covalent cross-linked luminescent hybrid material including terbium complex and silica was prepared through a sol-gel process. Homogenous spherical morphology (similar to 40 nm) could be achieved and this nanomaterial exhibited remarkable green emissions. It presented highly selective and rapid fluorescence quenching to Cu2+ (detection limit 3.9 mu M) compared with Na+, K+, Ca2+, Mg2+, Al3+, Zn2+, Fe2+, Co2+, Ni2+, Mn2+, Cd2+, Pd2+, Ag+, and Hg+ in CH3CN/H2O (4/1). More importantly, it was found that this sensing material can be reused more than 5 cycles. (C) 2012 Elsevier B.V. All rights reserved.