1,1'-ethylidene-di-piperidine | 5499-00-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1,1'-ethylidene-di-piperidine
• 英文别名: 1,1'-Aethyliden-di-piperidin；1-(1-Piperidin-1-ylethyl)piperidine
• CAS: 5499-00-3
• 化学式: C₁₂H₂₄N₂
• 分子量: 196.336
• InChiKey: ZXHLQRSUVYZJGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  哌啶 、 乙醛 在 potassium carbonate 作用下， 生成 1,1'-ethylidene-di-piperidine
  参考文献：
  名称：

  Mannich; Handke; Roth, Chemische Berichte, 1936, vol. 69, p. 2122

  摘要：

  DOI：

文献信息

• Aminosilyl-Substituted Diarylethene Compounds for Anionic Polymerisation
  申请人：Trinseo Europe GmbH

  公开号：US20170204119A1

  公开（公告）日：2017-07-20

  The invention related to novel compounds useful as modifying monomers and precursors for polymerization initiators. The invention further relates to a method of making the polymerization initiators and resulting polymers. The invention also relates to polymer compositions comprising the polymer of the invention and further components such as extender oils, fillers, vulcanizing agents etc., and to corresponding vulcanized polymer compositions and articles comprising vulcanized parts made from the vulcanized polymer composition.

  这项发明涉及用作改性单体和聚合引发剂前体的新化合物。该发明还涉及一种制备聚合引发剂和所得聚合物的方法。该发明还涉及包括该发明的聚合物和扩展油、填料、硫化剂等进一步组分的聚合物组合物，以及包括由该聚合物组合物制成的硫化部件的相应硫化聚合物组合物和制品。
• [EN] SILANE SULFIDE MODIFIED ELASTOMERIC POLYMERS<br/>[FR] POLYMÈRES ÉLASTOMÈRES MODIFIÉS PAR UN SULFURE DE SILANE
  申请人：STYRON EUROPE GMBH

  公开号：WO2014040639A1

  公开（公告）日：2014-03-20

  The present invention relates to silane sulfide modifier compounds and methods of making them. The invention also relates to a silane sulfide modified macromolecular compound obtainable by reacting a living anionic elastomeric polymer and a silane sulfide modifier. The silane sulfide modified macromolecular compound may be provided in the form of a polymer composition, and the polymer composition may be vulcanized (cross-linked) by making use of and reaction with at least one vulcanization agent, resulting in a vulcanized polymer composition.

  本发明涉及硅烷硫化物改性剂化合物及其制备方法。该发明还涉及通过反应活性阴离子弹性聚合物和硅烷硫化物改性剂获得的硅烷硫化物改性的高分子化合物。硅烷硫化物改性的高分子化合物可以以聚合物组成物的形式提供，并且可以通过利用至少一种硫化剂进行交联（硫化），从而得到硫化的聚合物组成物。
• [EN] METALLATED BENZYLSILANES AND THEIR USE AS POLYMERIZATION INITIATORS<br/>[FR] BENZYLSILANES MÉTALLÉS ET LEUR UTILISATION EN TANT QU'INITIATEURS DE POLYMÉRISATION
  申请人：TRINSEO EUROPE GMBH

  公开号：WO2018150043A1

  公开（公告）日：2018-08-23

  The invention relates to novel compounds useful as polymerization initiators or precursors for polymerization initiators. The invention further relates to a method of making the polymerization initiators and resulting polymers. The invention also relates to polymer compositions comprising the polymer of the invention and further components such as extender oils, fillers, vulcanizing agents etc., and to corresponding vulcanized polymer compositions and articles comprising vulcanized parts made from the vulcanized polymer composition.

  这项发明涉及用作聚合引发剂或聚合引发剂前体的新化合物。该发明进一步涉及一种制备聚合引发剂和所得聚合物的方法。该发明还涉及包括该发明的聚合物以及其他组分如延展油、填料、硫化剂等的聚合物组合物，以及包括由该聚合物组合物制成的硫化部件的相应硫化聚合物组合物和制品。
• Use of sulfur containing initiators for anionic polymerization of monomers
  申请人：Hogan E Terrence

  公开号：US20060030657A1

  公开（公告）日：2006-02-09

  An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.

  提供了一种用于阴离子聚合单体的引发剂，以在聚合物上提供一个功能性头基团。还提供了一种具有源自含硫阴离子引发剂的功能性头基团的聚合物，以及根据使用功能性终止试剂、偶联剂或连接剂而产生的额外功能性基团。还提供了一种用于阴离子聚合单体的方法，包括使用含硫阴离子引发剂聚合单体的步骤，以在聚合物上提供一个功能性头基团。还描述了一种包含功能性聚合物和填料的弹性化合物。还提供了一种具有减少滚动阻力的轮胎，其轮胎部件含有可硫化的弹性化合物。
• Amino Silane-Modified Polymers
  申请人：Döring Christian

  公开号：US20160060368A1

  公开（公告）日：2016-03-03

  Modified macromolecular compounds obtainable by using specific amino silane polymerization initiator compounds and optionally chain end-modifying compounds are described. Polymer compositions including such modified macromolecular compounds and the use of such compositions in the preparation of vulcanized (crosslinked) elastomeric polymer compositions and articles are described.

  描述了通过使用特定氨基硅烷聚合引发剂化合物和可选的链端修饰化合物可获得的改性高分子化合物。描述了包括这种改性高分子化合物的聚合物组合物以及在制备硫化（交联）弹性聚合物组合物和制品中使用这种组合物的用途。