1,3,5-tris(chlorodimethylsilyl)benzene | 120666-38-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3,5-tris(chlorodimethylsilyl)benzene
• 英文别名: Silane, 1,3,5-benzenetriyltris[chlorodimethyl-；[3,5-bis[chloro(dimethyl)silyl]phenyl]-chloro-dimethylsilane
• CAS: 120666-38-8
• 化学式: C₁₂H₂₁Cl₃Si₃
• 分子量: 355.914
• InChiKey: LBFOVAINRVHXRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.64
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3,5-tris(chlorodimethylsilyl)benzene 在 18-冠醚-6 、 sodium 作用下， 以 甲苯 为溶剂， 以0.22%的产率得到4,4,5,5,11,11,12,12,15,15,16,16-dodecamethyl-4,5,11,12,15,16-hexasilatetracyclo[6.6.2.13,13.16,10]octadeca-1(14),2,6,8,10(18),13(17)-hexaene
  参考文献：
  名称：

  Sekiguchi, Akira; Yatabe, Tetsuo; Kabuto, Chizuko, Angewandte Chemie, 1989, vol. 101, # 6, p. 778 - 780

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-三溴苯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 43.0h， 生成 1,3,5-tris(chlorodimethylsilyl)benzene
  参考文献：
  名称：

  Siloxa-bridged-cyclophanes featuring benzene, thiophene and pyridine units

  摘要：

  通过水解氯硅烷单体，制备了两个八甲基二硅氧烷键合的[3.3]环烷（1 和 2）和一个十二甲基三硅氧烷键合的[3.3.3]笼状化合物（3）。此外，还采用这种一般方法制备了两种具有两个噻吩（14）或吡啶（17）分子的八甲基二硅氧烷键合[3.3]杂环化合物。

  DOI：

  10.1039/b211045h

文献信息

• A sandwich-shaped M₃L₂ zinc(<scp>ii</scp>) complex containing 1,3,5-tris(dimethyl(pyridin-3-yl)silyl)benzene: selective photoluminescence recognition of diiodomethane
  作者：Sangseok Lee、Haeri Lee、Ok-Sang Jung

  DOI：10.1039/c7dt01138e

  日期：——

  The selective small molecular recognition of a discrete sandwich-shaped M₃L₂ zinc(ii) complex showing strong blue photoluminescence has been investigated.

  翻译结果：

  研究了一种选择性小分子识别的离散三明治形状的M₃L₂锌（ii）配合物，该配合物表现出强烈的蓝色光致发光。

• Nanosized starlike molecules. Synthesis and optical properties of tris- and tetrakis[oligo(disilanylenebithienylene)dimethylsilyl]benzene
  作者：Akinobu Naka、Yoshiaki Matsumoto、Tatsuya Itano、Kei Hasegawa、Tomoaki Shimamura、Joji Ohshita、Atsutaka Kunai、Takae Takeuchi、Mitsuo Ishikawa

  DOI：10.1016/j.jorganchem.2008.10.053

  日期：2009.2

  The syntheses of two types of starlike molecules with the arms that extend to three and four directions have been reported. The molecules with the arms consisting of a regular alternating arrangement of a silicon-silicon bond and bithienylene unit that extend to three directions were synthesized by the reactions of 1,3,5-tris(chlorodimethylsilyl) benzene, which was chosen as a core, with the lithio[oligo(disilanylenebithienylene)] derivatives. The starlike molecules with extended arms to four directions were prepared by the reaction of 1,2,4,5-tetrakis(fluorodimethylsilyl) benzene used as a core, with lithio[oligo(disilanylenebithienylene)]s. UV-Vis absorption and fluorescence properties of these starlike molecules have been investigated in a dioxane solution. The present molecules showed absorption maxima in a range of 321-337 nm, and revealed higher fluorescence quantum yields than that of the corresponding linear polymer, poly[(tetraethyldisilanylene) bithiophene]. (C) 2008 Elsevier B.V. All rights reserved.
• Polycylopentadienyls: Synthesis of arylsilylcyclopentadienyl compounds and their η5-complexes with tungsten
  作者：Herbert Plenio

  DOI：10.1016/0022-328x(92)83456-r

  日期：1992.2

  A general route to arylsilylcyclopentadienyl compounds starting from 1,4-C6H4Br2, 2,6-C5NH3Br2 and 1,3,5-C6H3Br3 is described. The aryl bromides were treated with Mg/ClSiMe2H to give the aryldimethylsilanes 1,4-C6H4(SiMe2H)2, 2,6-C5NH3(SiMe2H)2, and 1,3,5-C6H3(SiMe2H)3 which after reaction with Cl2 or Br2 yielded the aryldimethylsilyl halides 1,4-C6H4(SiMe2Br)2, 2,6-C5NH3 (SiMe2Br)2, 1,3,5-C6H3(SiMe2X)3 (X = Br or Cl) in excellent yields. The halide can be replaced by various cyclopentadienides to give aryldimethylsilylcyclopentadienes of the general type 1,4-C6H4 (SiMe2CP)2 and 1,3,5-C6H3(SiMe2CP)3 (Cp = C5H5 (8,11), C5H3(t-C4H9)2 (9,12), C5HMe4 (10,13)). Compounds C6H5(SiMe2(C5H5)), 1,4-C6H4(SiMe2(C5H5))2 (8) and 1,3,5-C6H3(SiMe2(C5H5))3 (11) were in turn treated with NaH, (MeCN)3W(CO)3, and MeI to give the eta-5-bound complexes C6H5 (SiMe2(C5H4)W(CO)3Me) (14), 1,4-C6H4(SiMe2(C5H4)W(CO)3Me)2 (15), 1,3,5-C6H3(SiMe2(C5H4)-W(CO)3Me)3 (16), which contain up to three half-sandwich units within one molecule.