2,2,6,6-tetramethyl-1-(2-phenyl-propoxy)-piperidin-4-ol | 1110727-04-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 2,2,6,6-tetramethyl-1-(2-phenyl-propoxy)-piperidin-4-ol
• 英文别名: 2,2,6,6-Tetramethyl-1-(2-phenylpropoxy)piperidin-4-ol
• CAS: 1110727-04-2
• 化学式: C₁₈H₂₉NO₂
• 分子量: 291.434
• InChiKey: PZZUAEQLNKJDOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  32.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-苯基丁醛 、 阻聚剂701 在 双氧水 、 copper(l) chloride 作用下， 以 水 为溶剂， 反应 13.0h， 以68%的产率得到2,2,6,6-tetramethyl-1-(2-phenyl-propoxy)-piperidin-4-ol
  参考文献：
  名称：

  Synthetic Studies on N-Alkoxyamines: A Mild and Broadly Applicable Route Starting from Nitroxide Radicals and Aldehydes

  摘要：

  A broad variety of 2,2,6,6-tetramethylpiperidine-based N-alkoxyamines were prepared in a newly found reaction. By means of a copper-catalyzed fragmentation reaction of aldehyde peroxides in the presence of TEMPO or TEMPO derivatives, N-alkoxyamines were obtained in moderate to good yields.

  DOI：

  10.1021/jo802403j

文献信息

• PROCESS FOR THE PREPARATION OF BLOCK COPOLYMERS
  申请人：Polimeri Europa S.p.A.

  公开号：EP1519970B1

  公开（公告）日：2007-10-24
• Process for the preparation of block copolymers
  申请人：Po Riccardo

  公开号：US20070219329A1

  公开（公告）日：2007-09-20

  Process for the preparation of block copolymers, based on vinylaromatic monomers and monomers deriving from (meth)acrylic acid by means of radicalic polymerization which comprises polymerizing the monomers at a temperature higher than or equal to 120° C., in the presence of a radicalic initiating system comprising a compound having general Formula (I).
• US7388052B2
  申请人：——

  公开号：US7388052B2

  公开（公告）日：2008-06-17