2,2',3,3,',4,4'-hexakis[bis(trimethylsilyl)methyl]-1,1'-bicyclotetrastibane | 500721-19-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 2,2',3,3,',4,4'-hexakis[bis(trimethylsilyl)methyl]-1,1'-bicyclotetrastibane
• CAS: 500721-19-7
• 化学式: C₄₂H₁₁₄Sb₈Si₁₂
• 分子量: 1930.39
• InChiKey: XGVRTVXBHMIZFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.63
• 重原子数：
  62
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,2',3,3,',4,4'-hexakis[bis(trimethylsilyl)methyl]-1,1'-bicyclotetrastibane 以 氘代苯 为溶剂， 生成 tris[bis(trimethylsilyl)methyl]cyclotristibane
  参考文献：
  名称：

  Neutron Diffraction Crystallography of meso-R(H)Sb−Sb(H)R and Reactions of R(H)Sb−Sb(H)R and RSbH₂ (R = (Me₃Si)₂CH) Leading to Tungsten Carbonyl Complexes, Methylstibanes, and Antimony Homocycles

  摘要：

  The crystal structure of the meso form of R(H)Sb-Sb(H)R (1; R = (Me3Si)(2)CH) was studied by single-crystal neutron diffraction at 20 K. 1 or RSbH2 (2) reacts with W(CO)(5)THF (THF = tetrahydrofuran) to give meso- and d,l-(OC)(5)W[R(H)Sb-Sb(H)R]W(CO)(5) (3) or R(H)(2)SbW-(CO)(5) (4). Dehydrogenation of 3 or 4 leads to [RSb=SbR]W(CO)(5) (5) or [(OC)(5)W](2)SbR (6). 1 or 2 reacts with MeI and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to give R(Me)Sb-Sb-(Me)R (7) or R(Me)SbH (8). 2 reacts with SbCl3 and pyridine to form R4Sb8 (9). Photochemical degradation of 9 gives cyclo-R3Sb3 (10). Dehydrogenation of 1 in the presence of LiAlH4 leads to the cis,trans isomer of R4Sb4 (11), which in the presence of light forms all-trans-11 and 10. Decomposition of 1 in the presence of (BuONa)-Bu-t leads to R6Sb8 (12). The structures of meso-3, d,l-3, 4, 5, 9.2THF, and 12 were determined by X-ray diffraction. The deuterium derivatives of 1, 2, and 8 were synthesized and characterized spectroscopically.

  DOI：

  10.1021/om020754h
• 作为产物：
  描述：

  meso-(Me₃Si)2CH(H)SbSb(H)CH(SiMe₃)2 在 t-BuONa 、 18-crown-6 作用下， 以 乙醚 为溶剂， 以2.3%的产率得到2,2',3,3,',4,4'-hexakis[bis(trimethylsilyl)methyl]-1,1'-bicyclotetrastibane
  参考文献：
  名称：

  Neutron Diffraction Crystallography of meso-R(H)Sb−Sb(H)R and Reactions of R(H)Sb−Sb(H)R and RSbH₂ (R = (Me₃Si)₂CH) Leading to Tungsten Carbonyl Complexes, Methylstibanes, and Antimony Homocycles

  摘要：

  The crystal structure of the meso form of R(H)Sb-Sb(H)R (1; R = (Me3Si)(2)CH) was studied by single-crystal neutron diffraction at 20 K. 1 or RSbH2 (2) reacts with W(CO)(5)THF (THF = tetrahydrofuran) to give meso- and d,l-(OC)(5)W[R(H)Sb-Sb(H)R]W(CO)(5) (3) or R(H)(2)SbW-(CO)(5) (4). Dehydrogenation of 3 or 4 leads to [RSb=SbR]W(CO)(5) (5) or [(OC)(5)W](2)SbR (6). 1 or 2 reacts with MeI and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to give R(Me)Sb-Sb-(Me)R (7) or R(Me)SbH (8). 2 reacts with SbCl3 and pyridine to form R4Sb8 (9). Photochemical degradation of 9 gives cyclo-R3Sb3 (10). Dehydrogenation of 1 in the presence of LiAlH4 leads to the cis,trans isomer of R4Sb4 (11), which in the presence of light forms all-trans-11 and 10. Decomposition of 1 in the presence of (BuONa)-Bu-t leads to R6Sb8 (12). The structures of meso-3, d,l-3, 4, 5, 9.2THF, and 12 were determined by X-ray diffraction. The deuterium derivatives of 1, 2, and 8 were synthesized and characterized spectroscopically.

  DOI：

  10.1021/om020754h

文献信息

• Neutron Diffraction Crystallography of <i>m</i><i>eso</i>-R(H)Sb−Sb(H)R and Reactions of R(H)Sb−Sb(H)R and RSbH₂ (R = (Me₃Si)₂CH) Leading to Tungsten Carbonyl Complexes, Methylstibanes, and Antimony Homocycles
  作者：Gábor Balázs、Hans Joachim Breunig、Enno Lork、Sax Mason

  DOI：10.1021/om020754h

  日期：2003.2.1

  The crystal structure of the meso form of R(H)Sb-Sb(H)R (1; R = (Me3Si)(2)CH) was studied by single-crystal neutron diffraction at 20 K. 1 or RSbH2 (2) reacts with W(CO)(5)THF (THF = tetrahydrofuran) to give meso- and d,l-(OC)(5)W[R(H)Sb-Sb(H)R]W(CO)(5) (3) or R(H)(2)SbW-(CO)(5) (4). Dehydrogenation of 3 or 4 leads to [RSb=SbR]W(CO)(5) (5) or [(OC)(5)W](2)SbR (6). 1 or 2 reacts with MeI and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to give R(Me)Sb-Sb-(Me)R (7) or R(Me)SbH (8). 2 reacts with SbCl3 and pyridine to form R4Sb8 (9). Photochemical degradation of 9 gives cyclo-R3Sb3 (10). Dehydrogenation of 1 in the presence of LiAlH4 leads to the cis,trans isomer of R4Sb4 (11), which in the presence of light forms all-trans-11 and 10. Decomposition of 1 in the presence of (BuONa)-Bu-t leads to R6Sb8 (12). The structures of meso-3, d,l-3, 4, 5, 9.2THF, and 12 were determined by X-ray diffraction. The deuterium derivatives of 1, 2, and 8 were synthesized and characterized spectroscopically.