1,1-diethylpropylphosphine | 89634-34-4

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: 1,1-diethylpropylphosphine
• 英文别名: (3-Ethylpentan-3-yl)phosphane；3-ethylpentan-3-ylphosphane
• CAS: 89634-34-4
• 化学式: C₇H₁₇P
• 分子量: 132.186
• InChiKey: ISAQKGFPYXDZBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1-diethylpropylphosphine 在 正丁基锂 作用下， 以 乙醚 、 正戊烷 为溶剂， 反应 2.0h， 生成 1,1-diethylpropyl(isobutyryl)phosphine
  参考文献：
  名称：

  Veits; Leksunkin; Neganova, Russian Journal of General Chemistry, 2000, vol. 70, # 8, p. 1237 - 1239

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1-二乙基丙基氯化镁 在 lithium aluminium tetrahydride 、 三氯化磷 作用下， 以 乙醚 、 正戊烷 为溶剂， 生成 1,1-diethylpropylphosphine
  参考文献：
  名称：

  Veits; Leksunkin; Neganova, Russian Journal of General Chemistry, 2000, vol. 70, # 8, p. 1237 - 1239

  摘要：

  DOI：

文献信息

• Method for preparing aminoarylborane compounds or derivatives thereof
  申请人：Université de Bordeaux I

  公开号：EP2881398A1

  公开（公告）日：2015-06-10

  The present invention provides a process for the preparation of aminoarylborane compounds and derivatives thereof comprising a step of arylation by reacting an aryl chloride with an aminoborane compound in the presence of a catalytic system. Typically, the transformation comprises, converting Aryl-chloride Ar-Cl with an aminoborane such as into an aminoarylborane compound of the following formula:

  本发明提供了一种制备氨基芳基硼化合物及其衍生物的方法，包括通过在催化体系存在下，将芳基氯化物与氨基硼烷化合物反应进行芳基化的步骤。通常，该转化包括将芳基氯化物Ar-Cl与氨基硼烷化合物反应，转化为以下式的氨基芳基硼化合物：
• [EN] HOMOGENOUS PROCESS FOR THE HYDROGENATION OF CARBOXYLIC ACIDS AND DERIVATIVES THEREOF<br/>[FR] PROCEDE HOMOGENE D'HYDROGENATION D'ACIDES CARBOXYLIQUES ET DE DERIVES DE CEUX-CI
  申请人：DAVY PROCESS TECHN LTD

  公开号：WO2003093208A1

  公开（公告）日：2003-11-13

  A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.

  在存在包含钌、铑、铁、锇或钯的催化剂以及有机膦的情况下，描述了一种用于羧酸及/或其衍生物的加氢反应的均相过程，其中加氢反应在至少约1%重量的水存在下进行。还描述了一种用于再生包含钌、铑、铁、锇或钯和有机膦的催化剂的过程，其中再生在氢气和水的存在下进行。
• METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20160108071A1

  公开（公告）日：2016-04-21

  The present invention provides a method for easily and inexpensively producing a heterogeneous catalyst used to synthesize a cyclic carbonate by reacting an epoxide with carbon dioxide and having excellent catalyst activity; a catalyst obtained using said manufacturing method; and a method for synthesizing a cyclic carbonate using said catalyst. A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group by reacting a silane compound with a silica gel in the presence of xylene, the silane compound having a haloalkyl group or a haloaryl group and (b) a step of obtaining a catalyst for synthesizing a cyclic carbonate by reacting the catalyst precursor obtained in step (a) with a tertiary phosphine.

  本发明提供了一种用于通过将环氧化合物与二氧化碳反应来合成环状碳酸酯的异质催化剂的简便且廉价的生产方法；采用所述制备方法获得的催化剂；以及使用该催化剂合成环状碳酸酯的方法。用于生产一种用于合成环状碳酸酯的催化剂的方法，通过将环氧化合物与二氧化碳反应，该方法包括以下步骤(a)和(b)：(a)通过在二甲苯存在下将硅烷化合物与二氧化硅反应以获得具有卤代烷基或卤代芳基的催化剂前驱体的步骤，其中所述硅烷化合物具有卤代烷基或卤代芳基；以及(b)通过将步骤(a)中获得的催化剂前驱体与三膦反应以获得用于合成环状碳酸酯的催化剂的步骤。
• [EN] HOMOGENEOUS PROCESS FOR THE HYDROGENATION OF DICARBOXYLIC ACIDS AND/OR ANHYDRIDES THEREOF<br/>[FR] PROCEDE HOMOGENE D'HYDROGENATION D'ACIDES DICARBOXYLIQUES ET/OU D'ANHYDRIDES DE CEUX-CI
  申请人：DAVY PROCESS TECHN LTD

  公开号：WO2005051875A1

  公开（公告）日：2005-06-09

  A homogeneous process for the hydrogenation of dicarboxylic acids and/or anhydrides in the presence of a catalyst comprising: (a) ruthenium, rhodium, iron, osmium or palladium; and (b) an organic phosphine; wherein the hydrogenation is carried out in the presence of at least about 1 % by weight water and wherein the reaction is carried out at a pressure. of from about 500 psig to about 2000 psig and a temperature of from about 200 °C to about 3OO °C such that from about 1 mol to about 10 mol of hydrogen are used to strip 1 mole of product from the reactor.

  一种均相过程，用于在催化剂的存在下氢化二羧酸和/或酐，所述催化剂包括：（a）钌、铑、铁、锇或钯；和（b）有机膦；其中氢化在至少约1%重量的水存在下进行，并且反应在约500 psig至约2000 psig的压力和约200°C至约300°C的温度下进行，使得约1摩尔至约10摩尔的氢用于从反应器中剥离1摩尔的产物。
• MANUFACTURING METHOD FOR COMPOUND HAVING N,N-BIS(2-HYROXY-3-CHLOROPROPYL)AMINO GROUP
  申请人：Toray Fine Chemicals Co., Ltd.

  公开号：US20180030013A1

  公开（公告）日：2018-02-01

  A method efficiently and safely manufactures, on an industrial scale, a compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group. (1) an amine compound or a solution thereof, (2) epichlorohydrin or a solution thereof, and (3) an acidic compound or a solution thereof are continuously supplied to a flow reactor and reacted at a reaction temperature of 40 to 130° C. and a liquid space velocity of 0.2 to 10 h −1 so that a compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group is manufactured. The obtained compound having an N,N-bis(2-hydroxy-3-chloropropyl)amino group is dehydrochlorinated by reaction with an alkali so that a polyfunctional glycidylamine type epoxy compound is manufactured.

  一种高效且安全地在工业规模上制造具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物的方法。将胺化合物或其溶液，环氧氯丙烷或其溶液，以及酸性化合物或其溶液连续供给到流动反应器中，在40至130°C的反应温度和0.2至10 h−1的液体空间速度下反应，从而制造出具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物。通过与碱反应将获得的具有N,N-双(2-羟基-3-氯丙基)氨基基团的化合物脱氯化，从而制造出一种多功能环氧化胺型环氧化合物。