N,N-二(2-羟乙基)-N'-十八烷基脲 | 36837-80-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: N,N-二(2-羟乙基)-N'-十八烷基脲
• 中文别名: N,N-二(2-羟乙基)-N-十八烷基脲
• 英文名称: 1,1-Bis(2-hydroxyethyl)-3-octadecylurea
• CAS: 36837-80-6
• 化学式: C₂₃H₄₈N₂O₃
• 分子量: 400.6
• InChiKey: PWTLFNDBSYUVAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  28
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  72.8
• 氢给体数：
  3
• 氢受体数：
  3

文献信息

• A process for the production of polyurethane elastomers and an isocyanate-reactive composition to be used in this process
  申请人：MOBAY CORPORATION

  公开号：EP0173888A1

  公开（公告）日：1986-03-12

  The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings by reacting a reaction mixture containing 1) a polyisocyanate, II) an isocyanate-reactive polymer having a molecular weight of about 1800 to 12 000, III) about 5 to 50% by weight, based on the weight of component (II) of a chain extender comprising a sterically hindered aromatic diamine and IV) an internal mold release agent mixture comprising a) about 0.5 to 10% by weight, based on the weight of components (11) and (111) of a zinc carboxylate containing 8 to 24 carbon atoms per carboxylate group and b) .a compatibilizer comprising a member selected from the group consisting of nitrogen-containing, isocyanate-reactive. acyclic compounds and nitrogen-containing, isocyanate-reactive polymers in an amount sufficient to solubilize the zinc carboxylate so that when the internal mold release agent mixture is in admixture with components (11) and (111), the zinc carboxylate posseses improved resistance to precipitation, the reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of about 70 to 130.

  本发明涉及一种生产可选蜂窝状聚氨酯弹性体模塑件的工艺，其反应混合物中含有 1) 一种多异氰酸酯 分子量约为 1800 至 12 000 的异氰酸酯反应聚合物、 III) 以组分（II）重量为基准，约 5%至 50%（按重量计）的由立体受阻芳香族二胺组成的扩链剂和 IV) 内脱模剂混合物，包括 a) 以组分(11)和(111)的重量为基准，约 0.5 至 10%（以重量计）的羧酸锌， 每个羧酸基含有 8 至 24 个碳原子，以及 b) .一种相容剂，该相容剂包括从含氮、异氰酸酯反应性无环化合物和含氮、异氰酸酯反应性聚合物组成的组中选出的成员，其用量足以溶解羧酸锌，从而当内部脱模剂混合物与组分（11）和（111）混合时，羧酸锌具有更好的抗沉淀性，反应混合物通过 RIM 工艺在异氰酸酯指数约为 70 至 130 的条件下作为一次性系统进行加工。
• Rim polyurethane or polyurea compositions containing internal mold release agents
  申请人：MOBAY CORPORATION

  公开号：EP0275907A2

  公开（公告）日：1988-07-27

  The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing i) a polyisocyanate, ii) a high molecular weight polymer having at least two isocyanate-reactive groups and having a molecular weight of 400 to about 10,000, iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two isocyanate-reactive groups and iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii), of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula wherein R₁, R₂ and R₃ are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups,       R₄ corresponds to the definition of R₁, R₂ and R₃, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group -NR₂R₃ and       R₁, R₂, R₃ and R₄ may, with one or both of the amidine nitrogen, also form a heterocyclic ring. The present invention is also directed to the amidine group-containing salt (iv) and to a isocyanate-­reactive composition based on components (ii), (iii) and (iv).

  本发明涉及一种生产可选蜂窝状聚氨酯弹性体模塑件或可选蜂窝状硬质结构聚氨酯的工艺，其反应混合物中含有 i) 一种多异氰酸酯 具有至少两个异氰酸酯反应基团且分子量在 400 到 10,000 之间的高分子聚合物、 以组分（ii）重量为基准，约 5%至 50%的具有至少两个异氰酸酯反应基团的扩链剂，以及 iv) 以组分（ii）和（iii）的重量为基准，约 0.05%至 10%的盐，该盐基于羧基官能团硅氧烷和含脒基的化合物，其式为 其中 R₁、R₂ 和 R₃ 是直链或支链、饱和或不饱和烃链，具有多达 30 个碳原子，可任选被醚基、酯基、酰胺基或脒基取代，并可任选被异氰酸酯反应基团如羟基或氨基终止、 R₄ 符合 R₁、R₂ 和 R₃ 的定义，但可另外代表具有 6 至 15 个碳原子的芳香族取代基，或代表基团 -NR₂R₃ 和 R₁、R₂、R₃ 和 R₄ 还可与一个或两个脒氮形成杂环。 本发明还涉及含脒基的盐（iv）和基于组分（ii）、（iii）和（iv）的异氰酸酯反应组合物。
• Process for the production of molded products using internal mold release agents
  申请人：MOBAY CORPORATION

  公开号：EP0364846A2

  公开（公告）日：1990-04-25

  The present invention is directed to a process for producing a molded product comprising A) reacting: i) an organic polyisocyanate having an isocyanate group content of from 5 to 45% by weight, preferably from 15 to 35% by weight, and most preferably from 20 to 35% by weight, prepared by reacting: a) an organic di- and/or polyisocyanate, and b) an active hydrogen containing fatty acid ester prepared by reacting an alcohol or polyol with an aliphatic, saturated or unsaturated fatty acid, said ester being characterized in that at least one aliphatic acid which contains more than 8 carbon atoms is built into the molecule, said ester further characterized as having an acid number of from 0 to 100 and a hydroxyl number of from 0 to 150 with at least one of said numbers being greater than zero, said ester having an average molecular weight of from 500 to 5000, ii) an isocyanate reactive component comprising: a) from about 0.5 to about 10% by weight based on the weight of components ii)b) and ii)c), of a zinc carboxylate containing from 8 to 24 carbon atoms per carboxylate group, b) from about 0.5 to 100% by weight, preferably from 0.5 to 95% by weight, more preferably from 5 to 45% by weight, and most preferably from 10 to 35% by weight, based on the weight of components ii)b) and ii)c), of a compatibilizer which compatibilizes said carboxylate in component ii), and c) from 0 to about 99.5% by weight, preferably from 5 to 99.5% by weight, more preferably from 55 to 95% by weight, and most preferably from 65 to 90% by weight, based on the weight of components ii)b), and ii)c), of at least one active hydrogen containing compound other than said compatibilizer, at an isocyanate index of from about 90 to about 400 and preferably from about 95 to about 115, in a closed mold, B) allowing the components to react, and C) removing the product from the mold.

  本发明涉及一种生产模塑产品的工艺，包括 A) 反应 i) 一种有机多异氰酸酯，其异氰酸酯基含量为 5-45%（重量比），优选 15-35%（重量比），最优选 20-35%（重量比）： a) 有机二异氰酸酯和/或多异氰酸酯，和 b) 一种活性含氢脂肪酸酯，由醇或多元醇与脂肪族饱和或不饱和脂肪酸反应制备，所述酯的特征在于分子中至少含有一种含 8 个以上碳原子的脂肪族酸，所述酯的进一步特征在于酸数为 0 至 100，羟基数为 0 至 150，其中至少一个数字大于零，所述酯的平均分子量为 500 至 5000、 ii) 异氰酸酯活性组分，包括 a) 以成分 ii)b) 和 ii)c) 重量计，约 0.5 至约 10%的羧酸锌，每个羧酸基含有 8 至 24 个碳原子、 b) 以组分 ii)b) 和 ii)c) 的重量为基准，约 0.5%至 100%（按重量计），优选 0.5%至 95%（按重量计），更优选 5%至 45%（按重量计），最优选 10%至 35%（按重量计）的相容剂，该相容剂可使组分 ii) 中的所述羧酸盐相容，以及 c) 以组分 ii)b) 和 ii)c) 重量为基准，0 至约 99.5%（以重量计），优选 5 至 99.5%（以重量计），更优选 55 至 95%（以重量计），最优选 65 至 90%（以重量计）的至少一种活性含氢化合物，而不是所述相容剂、 在封闭模具中，异氰酸酯指数约为 90 至约 400，最好约为 95 至约 115、 B) 让各组分反应，以及 C) 从模具中取出产品。
• Novel internal release agents for the production of molded products
  申请人：MILES INC.

  公开号：EP0501223A2

  公开（公告）日：1992-09-02

  The present invention is directed to a novel internal mold release agent for use in a polyurethane(urea) RIM process. The release agent broadly consists of the transesterification product of a fatty acid and a lower alkyl acetoacetate.

  本发明涉及一种用于聚氨酯（脲）RIM 工艺的新型内脱模剂。脱模剂大致由脂肪酸和乙酰乙酸低级烷基酯的酯交换产物组成。
• Internal release agents, avtive hydrogen containing mixtures which contain such agents and the use thereof in a process for the production of molded products
  申请人：MILES INC.

  公开号：EP0510437A2

  公开（公告）日：1992-10-28

  The present invention is directed to novel release agents.

  本发明涉及新型脱模剂。