tris(2,3-epoxy-3-methylpropyl)isocyanurat | 26157-73-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: tris(2,3-epoxy-3-methylpropyl)isocyanurat
• 英文别名: tris(2-methyl-2,3-epoxypropyl) isocyanurate；1,3,5-Tris(2-methylglycidyl)hexahydro-1,3,5-triazine-2,4,6-trione；1,3,5-tris[(2-methyloxiran-2-yl)methyl]-1,3,5-triazinane-2,4,6-trione
• CAS: 26157-73-3
• 化学式: C₁₅H₂₁N₃O₆
• 分子量: 339.348
• InChiKey: XVKPDQWVRPRLLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  98.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  三甲代烯丙基异氰酸酯 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以30%的产率得到tris(2,3-epoxy-3-methylpropyl)isocyanurat
  参考文献：
  名称：

  Fischer; Zeidler; Budnowski, Arzneimittel-Forschung/Drug Research, 1984, vol. 34, # 5, p. 543 - 547

  摘要：

  DOI：

文献信息

• Method for producing purified epoxy compound
  申请人：NISSAN CHEMICAL INDUSTRIES LTD.

  公开号：EP0822189A2

  公开（公告）日：1998-02-04

  A 2,3-epoxypropyl derivative or a 2-methyl-2,3-epoxypropyl derivative of a compound having carboxyl groups or amido groups is produced as a purified product having an epoxide equivalent of 1.0 to 1.1 times the theoretical epoxide equivalent of the derivative, an ionic halogen content of 10 ppm or less, transparency when molten and a stability against increase in the epoxide equivalent when stored at 150°C for 24 hours, by a process comprising steps (A) reacting 1.2 to 60 mol of an epihalohydrin or a 2-methyl-epihalohydrin with 1 mol of active hydrogen atoms of the carboxyl or amido group of the compound in the presence of a catalytic amount of a tertiary amine, a quaternary ammonium base or salt, a tri-substituted phosphine or quaternary phosphonium salt, thereby forming a reaction product containing a 2-hydroxy-3-halopropyl derivative or a 2-hydroxy-2-methyl-3-halopropyl derivative, (B) dehydrohalogenating the derivative by adding to the reaction product a sufficient amount of an alkali metal hydroxide while agitating the resulting slurry containing a precipitated alkali metal halide, thereby forming a final slurry containing the 2,3-epoxypropyl derivative or the 2-methyl-2,3-epoxypropyl derivative and the alkali metal halide, (C) washing the final slurry or a liquid product formed by removing the alkali metal halide from the final slurry with an aqueous solution of, as refining agent, a sulfonic acid, a salt of a sulfonic acid, a salt of a carboxylic acid having at least 7 carbon atoms, a salt of a sulfate of an alcohol having at least 4 carbon atoms or a mixture thereof respectively having a solubility of at most 1 wt% in water at 30°C containing the refining agent in an amount effective to refine the slurry or the liquid product, thereby forming a refined liquid containing the derivative, and (D) removing by evaporation the epihalohydrin or the 2-methyl-epihalohidrin from the refined liquid, thereby forming the 2,3-epoxypropyl derivative or the 2-methyl-2,3-epoxypropyl derivative as the purified product.

  一种具有羧基或氨基的化合物的 2，3-环氧丙基衍生物或 2-甲基-2，3-环氧丙基衍生物，是通过包括以下步骤的工艺制得的纯化产品：(A)将 1.2 至 60 摩尔环卤代烃或 2-甲基环卤代烃与 1 摩尔化合物羧基或氨基的活性氢原子在催化量的叔胺、季铵碱或盐、三取代膦或季鏻盐存在下反应，从而形成含有 2-羟基-3-卤丙基衍生物或 2-羟基-2-甲基-3-卤丙基衍生物的反应产物、(B) 向反应产物中加入足量的碱金属氢氧化物，同时搅拌所生成的含有沉淀碱金属卤化物的浆液，从而脱氢卤化该衍生物，形成含有 2,3-环氧丙基衍生物或 2-甲基-2,3-环氧丙基衍生物和碱金属卤化物的最终浆液、(C) 用以下物质的水溶液洗涤最终浆液或从最终浆液中除去碱金属卤化物而形成的液态产品：磺酸、磺酸的盐、至少有 7 个碳原子的羧酸的盐，作为精制剂、具有至少 4 个碳原子的醇的硫酸盐或它们的混合物，它们在 30°C 水中的溶解度不超过 1 wt%、(D) 通过蒸发从精制液体中除去表卤海德林或 2-甲基-表卤海德林，从而形成 2,3-环氧丙基衍生物或 2-甲基-2,3-环氧丙基衍生物作为精制产品。
• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。
• RESIN COMPOSITIONS FOR POWDERY COATINGS
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1057875A1

  公开（公告）日：2000-12-06

  A resin composition for powdery coatings, which contains the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1000 to 20000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120°C, (B) a poly-β-methylglycidyl compound having at least two structures represented by the formula (1) in one molecule: and (C) a sterically-hindered amine as a heat yellowing inhibitor.

  一种用于粉末涂料的树脂组合物，它含有以下成分（A）、（B）和（C）： (A) 含羧基的树脂，其平均分子量为 1000 至 20000，酸值为 5 至 200，玻璃化温度为 30 至 120°C、 (B) 聚-β-甲基缩水甘油酯化合物，该化合物在一个分子中至少具有两个由式（1）表示的结构： 和 (C) 作为热黄变抑制剂的立体受阻胺。
• Method of making carbon nanotube patterned film or carbon nanotube composite material using a composition comprising carbon nanotubes surface-modified with polymerizable moieties
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1457821A1

  公开（公告）日：2004-09-15

  Disclosed herein are methods of making a negative pattern of carbon nanotubes or a polymerized carbon nanotube composite having interpenetrating polymer network(IPN) by modifying the surfaces of the carbon nanotubes with polymerizable functional groups such as oxirane and anhydride groups and subjecting the surface-modified carbon nanotubes either to a photolithography process or to a heatcuring process. By virtue of the present invention, desired patterns of carbon nanotubes can be easily made on the surfaces of various substrates, and polymerized carbon nanotube composites improved in hardening properties can be made without additional polymers.

  本发明公开了制作碳纳米管负图案或具有互穿聚合物网络（IPN）的聚合碳纳米管复合材料的方法，方法是用可聚合的官能团（如环氧乙烷基团和酸酐基团）修饰碳纳米管的表面，并将表面修饰的碳纳米管置于光刻工艺或热固化工艺中。通过本发明，可以很容易地在各种基底的表面上制作出所需的碳纳米管图案，并且无需额外的聚合物就可以制作出硬化性能更好的聚合碳纳米管复合材料。
• COMPOSITION FOR FORMING ANTIREFLECTION FILM FOR LITHOGRAPHY
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1560070A1

  公开（公告）日：2005-08-03

  There is provided a composition for forming anti-reflective coating for anti-reflective coating that has a good absorption of light at a wavelength utilized for manufacturing a semiconductor device, that exerts a high protection effect against light reflection, that has a high dry etching rate compared with the photoresist layer. Concretely, the composition for forming anti-reflective coating contains a triazine trione compound, oligomer compound or polymer compound having hydroxyalkyl structure as substituent on nitrogen atom.

  本发明提供了一种用于形成防反射涂层的组合物，该组合物对用于制造半导体器件的波长的光具有良好的吸收性，对光的反射具有较高的保护效果，与光刻胶层相比具有较高的干蚀刻率。具体来说，用于形成抗反射涂层的组合物含有一种三嗪三酮化合物、低聚物化合物或聚合物化合物，其氮原子上的取代基为羟烷基结构。