9,10-Ethanoanthracene-11,12-dicarboxylic acid, 9,10-dihydro-, diethyl ester | 83742-19-2

分子结构分类

有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基四氢萘木脂素

中文名称

——

中文别名

——

英文名称

9,10-Ethanoanthracene-11,12-dicarboxylic acid, 9,10-dihydro-, diethyl ester

英文别名

diethyl tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9,11,13-hexaene-15,16-dicarboxylate

9,10-Ethanoanthracene-11,12-dicarboxylic acid, 9,10-dihydro-, diethyl ester化学式

CAS

83742-19-2

化学式

C₂₂H₂₂O₄

mdl

——

分子量

350.414

InChiKey

KVAFCEQAGCSSBJ-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

3.7
重原子数：

26
可旋转键数：

6
环数：

5.0
sp3杂化的碳原子比例：

0.36
拓扑面积：

52.6
氢给体数：

0
氢受体数：

4

反应信息

作为产物：

描述：

蒽、马来酸二乙酯以 xylene 为溶剂，生成 9,10-Ethanoanthracene-11,12-dicarboxylic acid, 9,10-dihydro-, diethyl ester

参考文献：

名称：

Synthese organique sous champ microondes : premier exemple d'activation specifique en phase homogene

摘要：

The rate of several Diels-Alder reactions under conventional or microwave heating are compared at the same bulk temperature. This afford the first evidence for a specific activating effect of microwaves under homogeneous conditions.

DOI：

10.1016/s0040-4039(00)79924-2

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文献信息

Synthese organique sous champ microondes : premier exemple d'activation specifique en phase homogene

作者：J. Berlan、P. Giboreau、S. Lefeuvre、C. Marchand

DOI：10.1016/s0040-4039(00)79924-2

日期：1991.5

The rate of several Diels-Alder reactions under conventional or microwave heating are compared at the same bulk temperature. This afford the first evidence for a specific activating effect of microwaves under homogeneous conditions.

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鬼臼酸哌啶基腙氮氧自由基鬼臼酸鬼臼毒醇苦鬼臼毒醇米托肼甘尔布林珠子草次素消泡剂愈创木素异落叶松脂素异紫杉脂素9,9'-缩丙酮异紫杉脂素大侧柏酸四环[6.6.2.02,7.09,14]十六烷-2(7),3,5,9(14),10,12-己烯-15,15,16,16-四甲腈叶下珠新素五脂素A1 7,8,9,9-四去氢异落叶松树脂醇 7,14-二氢-7,14-乙桥二苯并[a,h]蒽-15,16-二羧酸二钠盐 7,14-二氢-7,14-乙桥二苯并[a,h]蒽-15,16-二甲酸 6,8-二溴-4-氧代-4H-1-苯并吡喃-3-甲醛 5a-苯基-5a,14c-二氢苯并[a]茚并[2,1-c]芴-5,10-二酮 1-苯基-1,2,3,4-四氢-萘-2,3-二羧酸 1-(3,4-二羟基苯基)-6,7-二羟基-1,2-二氢萘-2,3-二甲酸 1-(3,4-二甲氧基苯基)-1,2,3,4-四氢-6,7-二甲氧基-2,3-萘二甲醇 1-(3,4-二甲氧基-苯基)-6,7-二甲氧基-1,2,3,4-四氢-萘-2,3-二羧酸 (7S,8S,9R)-9-(3,4-二甲氧基苯基)-6,7,8,9-四氢-4-甲氧基-7,8-双(甲氧基甲基)萘并[1,2-D]-1,3-二恶茂 (7S,8R,9R)-9-(1,3-苯并二氧戊环-5-基)-7,8-二甲基-6,7,8,9-四氢苯并[g][1,3]苯并二氧戊环 (1S,2R,3S)-1-(3,4-二甲氧基苯基)-1,2,3,4-四氢-6,7-二甲氧基-2,3-二甲基-萘 (11S,12R)-9,10-乙桥-9,10-二氢蒽-11,12-二甲酸 (-)-南烛木树脂酚 (+)-异落叶松脂素 (1RS,2SR)-1,2-dihydro-7-hydroxy-1-(4-hydroxy-3,5-dimethoxyphenyl)-6,8-dimethoxynaphthalene-2,3-dicarboxylic acid dimethyl ester (+/-)-(1R,2S,3R)-12-benzyl-4-hydroxy-6,7-methylenedioxy-1-phenyl-2,3,4-trihydrobenzo[f]isoindol-13-one (+/-)-dimethoxy-epi-isopicropodophyllin N-benzyl lactam (+/-)-(1R,2R,3S)-12-benzyl-6,7-methylenedioxy-4-oxo-1-phenyl-2,3-dihydrobenzo[f]isoindol-13-one (+)-ovafolinin B (5R,6R)-methyl 7-(6-fluoro-1H-benzo[d]imidazol-2-yl)-5-(3,4,5-trimethoxyphenyl)-5,6-dihydronaphtho[2,3-d][1,3]dioxole-6-carboxylate 2,5,8-trimethoxy-4a,9,9a,10-tetrahydro-9,10-[1,2]benzenoanthracene-1,4-dione 2,11-dichloro-13b-phenylbenzo[a]indeno[1,2-c]fluorene-9,14(8bH,13bH)-dione rel-(1R,4aR,9S,9aS,10R)-4a,9,9a,10-tetrahydro-9,10-diphenylspiro[9,10-epoxyanthracene-1(4H),2'-oxiran]-4-one 1,4-diphenyl-1,2,3,4-tetrahydro-1,4-epoxido-naphthalene-2,3-dicarboxylic acid diethyl ester rel-(1R,4aS,9R,9aS,10S)-4a,9,9a,10-tetrahydro-9,10-diphenylspiro[9,10-epoxyanthracene-1(4H),2'-oxetane]-4-one endo-2,5-diphenyl-3,4-benzo-14-oxatetracyclo<7.2.2.1^2,5.0^1,6>tetradec-3-ene 1a,2,7,7a-tetrahydro-2,7-epoxy-1a-methyl-1,2,7-triphenylbenzonaphthothiophenium triflate endo-2,5-diphenyl-3,4-benzo-14-oxatetracyclo<6.3.2.1^2,5.0^1,6>tetradec-3-ene (1S,8R,9S,10S)-1,8-diphenyl-10-methyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2(7),3,5-triene-9-carboxaldegyde 13b-phenylbenzo[a]indeno[1,2-c]fluorene-9,14(8bH,13bH)-dione (1R,2R)-7-methyl-1,2,3-tris(4-methylphenyl)-1,2-dihydronaphthalene methyl 9-deoxy-9-oxo-α-apopicropodophyllate 9-n-hexylimine (15R)-13-(4-fluorophenyl)-10-hydroxy-10,11-dihydro-9H-9,10-[3,4]epipyrroloanthracene-12,14(13H,15H)-dione