N-(4-((4-(二甲基氨基)苯基)偶氮)苯基)乙酰胺 | 1591-56-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 中文名称: N-(4-((4-(二甲基氨基)苯基)偶氮)苯基)乙酰胺
• 中文别名: C.I.分散黑3,乙酰衍生物
• 英文名称: 4'-Acetamino-4-dimethylamino-azobenzol
• 英文别名: 4'-((p-(Dimethylamino)phenyl)azo)acetanilide；N-[4-[[4-(dimethylamino)phenyl]diazenyl]phenyl]acetamide
• CAS: 1591-56-6
• 化学式: C₁₆H₁₈N₄O
• 分子量: 282.345
• InChiKey: ZUZJJOZXFBPXOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  57.1
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2927000090

反应信息

• 作为反应物：
  描述：

  N-(4-((4-(二甲基氨基)苯基)偶氮)苯基)乙酰胺 在 硫酸 作用下， 生成 N,N-二甲基-4,4-偶氮二苯胺
  参考文献：
  名称：

  Jacobs; Heidelberger, Journal of Biological Chemistry, 1915, vol. 21, p. 150

  摘要：

  DOI：
• 作为产物：
  描述：

  4-硝基氯化重氮苯 在 ammonium sulfide 、 乙醇 、 水 作用下， 生成 N-(4-((4-(二甲基氨基)苯基)偶氮)苯基)乙酰胺
  参考文献：
  名称：

  Meldola, Journal of the Chemical Society, 1884, vol. 45, p. 116

  摘要：

  DOI：

文献信息

• Method Of Preparing Fused Ring Indeno Compounds
  申请人：Transitions Optical, Inc.

  公开号：US20150141662A1

  公开（公告）日：2015-05-21

  The present invention relates to methods of preparing fused ring indeno compounds that involves reacting together a dienophile and a lactone compound, in the presence of a catalyst, and a carboxylic acid anhydride. With some embodiments, the fused ring indeno compound is represented by the following Formula (I-A), the dienophile is represented by the following Formula (II-A), and the lactone compound is represented by the following Formula (III-A):

  本发明涉及一种制备融合环吲哚化合物的方法，涉及将双亲受体和内酯化合物在催化剂和羧酸酐的存在下反应在一起。在某些实施例中，融合环吲哚化合物由以下式(I-A)表示，双亲受体由以下式(II-A)表示，内酯化合物由以下式(III-A)表示：
• Photochromic Indeno-Fused Ring Pyran Compounds
  申请人：Transitions Optical, Inc.

  公开号：US20150141661A1

  公开（公告）日：2015-05-21

  The present invention relates to photochromic indeno-fused ring pyran compounds represented by the following Formula (I-A): The present invention also relates to photochromic dichroic compounds, such as represented by Formula (I-A), in which (i) Z 2 is a group N—R 13 in which R 13 is a group L, and (ii) optionally at least one R 1 independently for each n is selected from a group L, in which the group L independently in each case is a lengthening group that provides the photochromic compound with dichroic properties, in accordance with some embodiments. The present invention also relates to photochromic articles, such as photochromic ophthalmic articles, that include one or more photochromic compounds according to the present invention, such as represented by Formula (I-A).

  本发明涉及由以下式（I-A）表示的光致变色吲哚融合环吡喃化合物。本发明还涉及光致二向色化合物，例如由式（I-A）表示，其中（i）Z2是一个N—R13基团，其中R13是一个L基团，以及（ii）对于每个n，可选地至少选择一个R1，每种情况下独立选择自L基团，其中每种情况下L基团是一个提供光致化合物二向色性能的延伸基团，符合某些实施例。本发明还涉及光致物品，例如光致眼科物品，包括根据本发明的一个或多个光致化合物，例如由式（I-A）表示。
• Fused Ring Indeno Compounds For Preparation Of Photochromic Compounds
  申请人：Transitions Optical, Inc.

  公开号：US20150141663A1

  公开（公告）日：2015-05-21

  The present invention relates to intermediate compounds represented by the following Formula (I-A), The intermediate compounds of the present invention, such as represented by Formula (I-A), can be used to prepare photochromic compounds, such as photochromic fused ring indenopyran compounds, including but not limited to photochromic fused ring indeno-naphtho-pyran compounds.

  本发明涉及以下式(I-A)所表示的中间化合物。本发明的中间化合物，如式(I-A)所示，可用于制备光致变色化合物，例如光致变色融合环吲哚吡喃化合物，包括但不限于光致变色融合环吲哚萘吡喃化合物。
• Pongratz; Markgraf; Mayer-Pitsch, Chemische Berichte, 1938, vol. 71, p. 1287,1289
  作者：Pongratz、Markgraf、Mayer-Pitsch

  DOI：——

  日期：——
• METHOD OF PREPARING FUSED RING INDENO COMPOUNDS
  申请人：Transitions Optical, Inc.

  公开号：EP3071550B1

  公开（公告）日：2019-03-13