5-(4-methoxyphenyl)thianthrenium | 47193-93-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二硫类化合物
• 英文名称: 5-(4-methoxyphenyl)thianthrenium
• 英文别名: 5-(4-Methoxyphenyl)thianthren-5-ium
• CAS: 47193-93-1
• 化学式: C₁₉H₁₅OS₂
• 分子量: 323.459
• InChiKey: FUUNJHHNSDERSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-(4-methoxyphenyl)thianthrenium 、 1-triethylsiloxy-2,2-difluoro-1-phenylethene 在 fac-tris(2-phenylpyridinato-N,C2')iridium(III) 、 双(二氧化硫)-1,4-二氮杂双环[2.2.2]辛烷加合物 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 48.0h， 以62%的产率得到2,2-difluoro-2-((4-methoxyphenyl)sulfonyl)-1-phenylethan-1-one
  参考文献：
  名称：

  光氧化还原催化的二氧化硫和硫蒽盐中酮的α-磺酰化

  摘要：

  用 DABCO·(SO 2 ) 2和 thianthrenium 盐对甲硅烷基烯醇醚进行光氧化还原催化磺酰化，以中等至良好的产率提供多种 β-酮砜。该协议具有易于获得的起始材料和良好的官能团兼容性，能够将各种官能化磺酰基引入酮。此外，甲醇作为重要的工业原料之一，首次可作为甲基源，通过甲基噻蒽中间体制备α-甲基磺化酮。

  DOI：

  10.1021/acs.orglett.2c01132

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Radiation-curable silicone composition
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2239295A2

  公开（公告）日：2010-10-13

  A silicone composition comprising an epoxy-containing organopolysiloxane and a fluoroalkylfluorophosphoric acid salt as a photoacid generator is curable and safe.

  由含环氧树脂的有机聚硅氧烷和作为光酸发生剂的氟烷基氟磷酸盐组成的硅树脂组合物可固化且安全。
• MATERIAL FOR ORGANIC ELECTRONICS, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY ELEMENT USING ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATING DEVICE, AND DISPLAY DEVICE
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2485290A1

  公开（公告）日：2012-08-08

  Provided is a material for organic electronics which can produce an organic electronic element capable of lowering the driving voltage or capable of performing stable driving for a long time. The material for organic electronics contains at least an ionic compound and a compound having a charge transporting unit (hereinafter, referred to as charge transporting compound), and the ionic compound is composed of a counter cation and a counter anion, while the counter cation is any one kind or two or more kinds selected from H+, a carbocation, a nitrogen cation, an oxygen cation, and a cation having a transition metal.

  本发明提供了一种有机电子元件材料，它可以生产出能够降低驱动电压或能够长时间稳定驱动的有机电子元件。该有机电子元件材料至少包含一种离子化合物和一种具有电荷传输单元的化合物（以下简称电荷传输化合物），离子化合物由反阳离子和反阴离子组成，而反阳离子是从 H+、碳化物、氮阳离子、氧阳离子和具有过渡金属的阳离子中任选一种或两种以上。
• RESIN COMPOSITION
  申请人：Denki Kagaku Kogyo Kabushiki Kaisha

  公开号：EP2878611A1

  公开（公告）日：2015-06-03

  Provided is a resin composition comprising (A) an epoxy compound, (B) an epoxy resin, and (C) a photocationic polymerization initiator. Preferably, this resin composition has a moisture content of 1000 ppm or less and a chlorine content of 1000 ppm or less. This resin composition is an energy beam-curable resin composition having accurate coating properties, excellent adhesiveness, low moisture permeability, excellent adhesive durability, and excellent storage stability.

  本发明提供了一种树脂组合物，其中包括 (A) 环氧化合物、(B) 环氧树脂和 (C) 光致聚合引发剂。这种树脂组合物的水分含量最好不超过 1000 ppm，氯含量最好不超过 1000 ppm。这种树脂组合物是一种能量束固化树脂组合物，具有精确的涂层性能、优异的粘合性、低透湿性、优异的粘合耐久性和优异的储存稳定性。
• IONIC-COMPOUND-CONTAINING TREATMENT SOLUTION, ORGANIC ELECTRONIC ELEMENT, AND METHOD FOR MANUFACTURING ORGANIC ELECTRONIC ELEMENT
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP2966942A1

  公开（公告）日：2016-01-13

  An embodiment of the present invention relates to a treatment liquid which contains an ionic compound and a solvent, and is used for adhering the ionic compound to at least one surface selected from the group consisting of a surface on which a layer having hole transport properties is to be formed, and a surface of a layer having hole transport properties.

  本发明的一个实施方案涉及一种含有离子化合物和溶剂的处理液，该处理液用于将离子化合物附着在至少一个表面上，该表面可从以下两组中选择：一个是要形成具有孔传输特性的层的表面，另一个是具有孔传输特性的层的表面。