N-(4-cyanophenyl)-aziridino-[2,3-c]-N-phenyl succinimide | 1388625-35-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: N-(4-cyanophenyl)-aziridino-[2,3-c]-N-phenyl succinimide
• 英文别名: 4-(2,4-Dioxo-3-phenyl-3,6-diazabicyclo[3.1.0]hexan-6-yl)benzonitrile；4-(2,4-dioxo-3-phenyl-3,6-diazabicyclo[3.1.0]hexan-6-yl)benzonitrile
• CAS: 1388625-35-1
• 化学式: C₁₇H₁₁N₃O₂
• 分子量: 289.293
• InChiKey: ZBERMSBIKXLYFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  64.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  反应 1.0h， 生成 N-(4-cyanophenyl)-aziridino-[2,3-c]-N-phenyl succinimide
  参考文献：
  名称：

  Efficient Aziridine Synthesis in Metastable Crystalline Phases by Photoinduced Denitrogenation of Crystalline Triazolines

  摘要：

  The solid-state photodenitrogenation of crystalline triazolines proceeds with high efficiency to form the corresponding aziridines in high chemical yields upon selection of the proper irradiation wavelength. It was shown that the solid-to-solid reactions occur by formation of the product in metastable crystalline phases.

  DOI：

  10.1021/ol301582n

文献信息

• Efficient Aziridine Synthesis in Metastable Crystalline Phases by Photoinduced Denitrogenation of Crystalline Triazolines
  作者：Denisse de Loera、Miguel A. Garcia-Garibay

  DOI：10.1021/ol301582n

  日期：2012.8.3

  The solid-state photodenitrogenation of crystalline triazolines proceeds with high efficiency to form the corresponding aziridines in high chemical yields upon selection of the proper irradiation wavelength. It was shown that the solid-to-solid reactions occur by formation of the product in metastable crystalline phases.