2-[2-(5,6-Dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-ethylidene]-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine | 140934-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: 2-[2-(5,6-Dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-ethylidene]-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine
• 英文别名: 2-[2-(5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)ethylidene]-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine
• CAS: 140934-22-1
• 化学式: C₁₃H₁₂S₈
• 分子量: 424.766
• InChiKey: RPCJFWWFIYLBFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  在 正丁基锂 、 三乙胺 作用下， 反应 13.25h， 生成 2-[2-(5,6-Dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-ethylidene]-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine
  参考文献：
  名称：

  New vinylogous tetrathiafulvalene (TTF) π-electron donors

  摘要：

  The synthesis and solution electrochemistry of ten new ethanediylidene-2,2'-bis(1,3-dithiole) derivatives (7)-(16) is described; charge-transfer complexes have been obtained with tetracyano-p-quinodimethane (TCNQ).

  DOI：

  10.1016/s0040-4039(00)91626-5

文献信息

• New vinylogous tetrathiafulvalene (TTF) π-electron donors
  作者：Adrian J Moore、Martin R Bryce

  DOI：10.1016/s0040-4039(00)91626-5

  日期：1992.3

  The synthesis and solution electrochemistry of ten new ethanediylidene-2,2'-bis(1,3-dithiole) derivatives (7)-(16) is described; charge-transfer complexes have been obtained with tetracyano-p-quinodimethane (TCNQ).