N-氯-2,2,6,6-四甲基-4-哌啶基甲基丙烯酸酯 | 1126272-77-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 中文名称: N-氯-2,2,6,6-四甲基-4-哌啶基甲基丙烯酸酯
• 英文名称: N-chloro-2,2,6,6-tetramethyl-4-piperidinyl methacrylate
• 英文别名: N-Chloro-2,2,6,6-tetramethyl-4-piperidyl methacrylate；(1-chloro-2,2,6,6-tetramethylpiperidin-4-yl) 2-methylprop-2-enoate
• CAS: 1126272-77-2
• 化学式: C₁₃H₂₂ClNO₂
• 分子量: 259.776
• InChiKey: HEVKFRBDENHXII-UHFFFAOYSA-N

物化性质

• 溶解度：
  可溶于氯仿（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  2-甲基-2-丙烯酸-2,2,6,6-四甲基-4-哌啶基酯	4-methacryloyloxy-2,2,6,6-tetramethylpiperidine	31582-45-3	C13H23NO2	225.331

反应信息

• 作为产物：
  描述：

  2-甲基-2-丙烯酸-2,2,6,6-四甲基-4-哌啶基酯 在 sode de l'acide trichloroisocyanurique 作用下， 以 氯仿 、 水 为溶剂， 反应 1.0h， 以96.3%的产率得到N-氯-2,2,6,6-四甲基-4-哌啶基甲基丙烯酸酯
  参考文献：
  名称：

  ANTIMICROBIAL POLYMERS AND COATINGS

  摘要：

  生物杀灭化合物已被合成并测试。这些生物杀灭化合物具有广谱效力，其生物杀灭性能易于更新。这些生物杀灭化合物的示例包括N-卤胺单体和聚合物以及银磺胺聚合物。这些化合物可用于为各种材料和物品添加生物杀灭功能。

  公开号：

  US20090324536A1

文献信息

• Hindered primary chlorinated amine in a latex formulation
  申请人：Rohm and Haas Company

  公开号：EP2594133A1

  公开（公告）日：2013-05-22

  The present invention relates to a process comprising adding a sufficient amount of a halamine with a latex binder to achieve microbial prophylaxis, wherein the halamine is characterized by the following formula: wherein X1 is H, Br, or Cl; X2 is Br or Cl; and R1 is H or a C1-30 alkyl group or mixtures thereof. The present invention also relates to a composition comprising the halamine and a latex binder. The present invention provides a quick kill shelf stable preservative for latex binders and for formulations that use such binders.

  本发明涉及一种工艺，包括在乳胶粘合剂中加入足量的卤胺，以实现微生物预防，其中卤胺的特征为下式： 其中X1为H、Br或Cl；X2为Br或Cl；R1为H或C1-30烷基或其混合物。本发明还涉及一种包含卤胺和乳胶粘合剂的组合物。本发明为乳胶粘合剂和使用此类粘合剂的配方提供了一种快速杀灭的货架稳定防腐剂。
• NOVEL COPOLYMER WITH CYCLIC HALAMINE STRUCTURE
  申请人：Nippon Soda Co., Ltd.

  公开号：EP3078683A1

  公开（公告）日：2016-10-12

  The invention has an object to provide a copolymer, which enables to yield a coated film with a high transparency when formed into a coated film, and to add a regenerable antibacterial effect, as well as a resin composition containing the same. A copolymer of the invention is a copolymer including a repeating unit represented by the following formula (I) (wherein R1 represents a hydrogen atom or a methyl group; R2 represents a hydrogen atom or a saturated or unsaturated alkyl group having 1 to 18 carbon atoms; R11 to R14 each independently represent a hydrogen atom or an alkyl group, provided that at least 2 of R11 to R14 represent an alkyl group, and that R11 and R12, or R13 and R14 can bond together to form a ring; X represents -O- or -NR20-; R20 represents a hydrogen atom or an alkyl group; Y represents a halogen atom; and n represents 0 or 1), and a repeating unit having a crosslinkable functional group.

  本发明的目的是提供一种共聚物，该共聚物在形成涂膜时能产生具有高透明度的涂膜，并能增加可再生的抗菌效果，还能提供含有该共聚物的树脂组合物。本发明的共聚物是一种包括由下式（I）代表的重复单元的共聚物（其中 R1 代表氢原子或甲基；R2 代表氢原子或具有 1 至 18 个碳原子的饱和或不饱和烷基；R11至R14各自独立地代表氢原子或烷基，条件是R11至R14中至少有2个代表烷基，且R11和R12或R13和R14可键合在一起形成环；X代表-O-或-NR20-；R20代表氢原子或烷基；Y代表卤素原子；n代表0或1），以及具有可交联官能团的重复单元。
• HINDERED PRIMARY CHLORINATED AMINE IN A LATEX FORMULATION
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：US20130123386A1

  公开（公告）日：2013-05-16

  The present invention relates to a process comprising adding a sufficient amount of a halamine with a latex binder to achieve microbial prophylaxis, wherein the halamine is characterized by the following formula: wherein X 1 is H, Br, or Cl; X 2 is Br or Cl; and R 1 is H or a C 1-30 alkyl group or mixtures thereof. The present invention also relates to a composition comprising the halamine and a latex binder. The present invention provides a quick kill shelf stable preservative for latex binders and for formulations that use such binders.
• US8759416B2
  申请人：——

  公开号：US8759416B2

  公开（公告）日：2014-06-24
• [EN] ANTIMICROBIAL POLYMERS AND COATINGS<br/>[FR] POLYMÈRES ET REVÊTEMENTS ANTIMICROBIENS
  申请人：UNIV SOUTH DAKOTA

  公开号：WO2009158285A2

  公开（公告）日：2009-12-30

  Biocidal compounds have been synthesized and tested. These biocidal compounds have broad-spectrum efficacy and their biocidal properties are easily renewable. Illustrative examples of these biocidal compounds include N-halamine monomers and polymers and silver sulfadiazine polymers. These compounds can be used to add biocidal function to various materials and articles.