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    首页 分子通 按物质功能分类 化学试剂 手性化学试剂

    手性化学试剂

    手性化学试剂是指含有一个或多个不对称中心，在分子结构中至少有一个碳原子与四个不同的基团相连的有机化合物。这些不对称中心赋予了化合物旋光活性，导致它们具有左旋和右旋两种形式（即对映体）。在化学反应中，不同构型的手性试剂可以引发立体选择性的反应，从而形成单一立体异构体产物。

    手性化学试剂在药物合成、催化过程、分析化学等多个领域都有着广泛的应用。例如，在药物研发过程中，许多活性成分因其具有手性结构而可能产生不同的生物效应，因此需要通过精确控制使用的手性试剂来确保最终产品的纯度和药效。此外，在催化剂的设计中，选择合适的手性配体或辅剂也能够显著提高反应的选择性和效率。

    合成手性化学试剂的方法包括但不限于不对称合成、利用天然产物作为起始原料进行衍生化以及采用生物催化手段等。随着研究的深入和技术的发展，人们对于手性分子的认识越来越深刻，这也促进了相关领域的快速发展和进步。

    中文名称 英文名称 CAS号 化学式 结构式图片
    (1R,5S,6R)-3-氮杂双环[3.1.0]己烷-6-甲醇 ((1R,5S)-3-azabicyclo[3.1.0]hexan-6-yl)methanol 827599-22-4 C6H11NO
    (1R,5S,6R)-3-氮杂双环[3.1.0]己烷-6-甲醇
    (1R)-(-)-10-樟脑磺哑嗪 (-)-(camphoryl)sulfonyl oxaziridine 104372-31-8 C10H15NO3S
    (1R)-(-)-10-樟脑磺哑嗪
    (-)-文斯内酯 (-)-2-azabicyclo[2.2.1]hept-5-en-3-one 79200-56-9 C6H7NO
    (-)-文斯内酯
    (+)-8,8-二氯樟脑磺哑嗪 (+)-(8,8-dichlorocamphorylsulfonyl)oxaziridine 127184-05-8 C10H13Cl2NO3S
    (+)-8,8-二氯樟脑磺哑嗪
    —— (S)-1-Phenylethane-1,2-diyl bis(4-(trans-4-pentylcyclohexyl)benzoate) 165660-09-3 C44H58O4
    (S)-1-Phenylethane-1,2-diyl bis(4-(trans-4-pentylcyclohexyl)benzoate)
    —— 2102502-56-5 C8H13NO2.ClH
    —— (R)-(-)-4-[trans-4-(trans-4-propylcyclohexyl)cyclohexyl]-1-(1-methylheptyloxy)-2,6-difluorobenzene 159077-75-5 C29H46F2O
    (R)-(-)-4-[trans-4-(trans-4-propylcyclohexyl)cyclohexyl]-1-(1-methylheptyloxy)-2,6-difluorobenzene
    —— Exo-3-(Boc-amino)-8-azabicyclo[3.2.1]octane 132234-68-5 C12H22N2O2
    Exo-3-(Boc-amino)-8-azabicyclo[3.2.1]octane
    —— (S)-1,1'-spirobiindane-7,7'-diol 223137-87-9 C17H16O2
    (S)-1,1'-spirobiindane-7,7'-diol
    —— hydrobenzoin 492-70-6 C14H14O2
    hydrobenzoin
    —— [(1S,5R)-3-azabicyclo[3.1.0]hexan-6-yl]methanol 134575-13-6 C6H11NO
    [(1S,5R)-3-azabicyclo[3.1.0]hexan-6-yl]methanol
    —— (7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4a,7-methano-3lambda~6~-oxazireno[3,2-i][2,1]benzothiazole-3,3(4H)-dione 127184-05-8 C10H13Cl2NO3S
    (7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4a,7-methano-3lambda~6~-oxazireno[3,2-i][2,1]benzothiazole-3,3(4H)-dione
    —— (1S)-(+)-(Camphorylsulfonyl)oxaziridine 104322-63-6 C10H15NO3S
    (1S)-(+)-(Camphorylsulfonyl)oxaziridine
    —— Dibenzoyl-L-tartaric acid monohydrate 2743-38-6 C18H16O9
    Dibenzoyl-L-tartaric acid monohydrate
    —— (+)-camphorsulfonyloxaziridine 104372-31-8 C10H15NO3S
    (+)-camphorsulfonyloxaziridine
    —— 7,7-Dichloro-11,11-dimethyl-5-oxa-3lambda6-thia-4-azatetracyclo[6.2.1.01,6.04,6]undecane 3,3-dioxide 127184-05-8 C10H13Cl2NO3S
    7,7-Dichloro-11,11-dimethyl-5-oxa-3lambda6-thia-4-azatetracyclo[6.2.1.01,6.04,6]undecane 3,3-dioxide
    —— (1S,2S,5S)-2-(Hydroxymethyl)-5-vinylquinuclidine 207129-35-9 C10H17NO
    (1S,2S,5S)-2-(Hydroxymethyl)-5-vinylquinuclidine
    —— hexahydrocyclopenta[c]pyrrol-5(1H)-one 1257389-95-9 C7H11NO
    hexahydrocyclopenta[c]pyrrol-5(1H)-one
    —— Hydroquinine 1,4-phthalazinediyl diether 140924-50-1 C48H54N6O4
    Hydroquinine 1,4-phthalazinediyl diether
    —— (Z,E)-9.12-Octadecadienalkohol 506-43-4 C18H34O
    (Z,E)-9.12-Octadecadienalkohol
    —— 1-((1R)-((2R,4R,5S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)-4-((1R)-((2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine 140924-50-1 C48H54N6O4
    1-((1R)-((2R,4R,5S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)-4-((1R)-((2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine
    —— (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine 104372-31-8 C10H15NO3S
    (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine
    —— 1,4-Bis((1R)-((1S,2S,4S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine 140924-50-1 C48H54N6O4
    1,4-Bis((1R)-((1S,2S,4S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine
    —— (1R)-(-)-(10-camphorsulfonyl)oxaziridine 104372-31-8 C10H15NO3S
    (1R)-(-)-(10-camphorsulfonyl)oxaziridine
    —— (1S)-(+)-(10-camphorsulfonyl)oxaziridine 104322-63-6 C10H15NO3S
    (1S)-(+)-(10-camphorsulfonyl)oxaziridine
    —— (1R,2S')-α-(pyrrolidin-2-yl)benzyl alcohol 885462-68-0 C11H15NO
    (1R,2S')-α-(pyrrolidin-2-yl)benzyl alcohol
    —— (4As,8as)-9,9-dimethyltetrahydro-4h-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide 104372-31-8 C10H15NO3S
    (4As,8as)-9,9-dimethyltetrahydro-4h-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
    —— (-)-O,O′-dibenzoyl-L-tartaric acid monohydrate 62708-56-9 C18H14O8*H2O
    (-)-O,O′-dibenzoyl-L-tartaric acid monohydrate
    —— O,O'-dibenzoyl-D-tartrate 62708-56-9 C18H12O8
    O,O'-dibenzoyl-D-tartrate
    —— tert-butyl (R)-3-hydroxybutanoate 110171-06-7 C8H16O3
    tert-butyl (R)-3-hydroxybutanoate
    —— pentane-2,4-diol 72345-23-4 C5H12O2
    pentane-2,4-diol
    —— (1R,5S)-bicyclo[3.1.0]hexan-2-one 58001-78-8 C6H8O
    (1R,5S)-bicyclo[3.1.0]hexan-2-one
    —— trans-Cyclohexane-1,4-diol 6995-79-5 C6H12O2
    trans-Cyclohexane-1,4-diol
    —— dimethyl meso-tartrate 608-69-5 C6H10O6
    dimethyl meso-tartrate
    —— anhydroerythritol 4358-64-9 C4H8O3
    anhydroerythritol
    —— rac-tartaric acid dibenzoate 93656-02-1 C18H14O8
    rac-tartaric acid dibenzoate
    —— 9,12-octadecadien-1-ol 1577-52-2 C18H34O
    9,12-octadecadien-1-ol