| 208598-82-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 208598-82-7
• 化学式: C₂₃H₅₄LiN₃OSi₃Sn
• 分子量: 598.609
• InChiKey: SCDSYYPPXYVTOL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 碘甲烷 以 乙醚 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Triamidostannates(II) as nucleophiles: synthesis of allyltriamidostannanes

  摘要：

  A series of triamido stannanes of the general types HC{SiMe2NR}(3)SnCH3 [R = p-Tolyl (3), t-Butyl (4)] and MeSi{SiMe2N(R)}(3)SnR' [R = p-Tolyl and R' = CH2CH=CH2 (5), CH2CH=CHCH3 (6), CH2CH=CHC6H5 (7), CH2(CH3)C=CH2 (8); R = t-Butyl and R' = CH2CH=CH2 (9), CH2CH=CHCH3 (10)] have been synthesized by reacting the lithium triamidostannates [HC{SiMe2NR}(3)SnLi(THF)(n)] and [MeSi{SiMe2NR}(3)SnLi(THF)(n)] with the respective alkyl halides. For HC{SiMe(2)NtBu}(3)SnCH3 a single crystal X-ray structure analysis established the detailed structural arrangements in this new class of compounds. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00371-9