| 475176-58-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 475176-58-0
• 化学式: C₇₂H₁₈₀Si₁₇
• 分子量: 1523.67
• InChiKey: LVIOILWPUYJRPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.31
• 重原子数：
  89.0
• 可旋转键数：
  64.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Bis(2,3,4,5,6-pentafluorophenyl)-[2,3,5,6-tetrafluoro-4-(3-methoxyphenyl)phenyl]borane 、 以 not given 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of (Perfluoroaryl)borane-Functionalized Carbosilane Dendrimers and Their Use as Lewis Acid Catalysts for the Hydrosilation of Acetophenone

  摘要：

  Carbosilane dendrimers capped with 4, 8, and 12 perfluoroarylborane Lewis acids are prepared via a self-catalyzed silation of the aryl ether 1 with the appropriate Si-H terminated dendrimer scaffold. The dendrimers were fully characterized by spectroscopic methods and MALDI-TOF mass spectrometry and tested as catalysts for the hydrosilation of acetophenone using triethylsilane, exhibiting only slightly inferior activities in comparison to B(C6F5)(3).

  DOI：

  10.1021/om0205187