金,加合(3:1)镍 | 12256-69-8

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 中文名称: 金,加合(3:1)镍
• 英文名称: Gold--nickel (3/1)
• 英文别名: gold;nickel
• CAS: 12256-69-8
• 化学式: Au₃Ni
• 分子量: 649.59
• InChiKey: JVEQVALVZPYJOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  bis(acetylacetonate)nickel(II) 、 四氯金酸水合物 在 oleylamine 、 n-C₄H₉Li 作用下， 以 further solvent(s) 为溶剂， 生成 金,加合(3:1)镍
  参考文献：
  名称：

  Low-Temperature Solution Synthesis of the Non-Equilibrium Ordered Intermetallic Compounds Au₃Fe, Au₃Co, and Au₃Ni as Nanocrystals

  摘要：

  Alloys and intermetallic compounds of Au with the 3d transition metals Fe, Co, and Ni are nonequilibrium phases that have many useful potential applications as catalytic, magnetic, optic, and multifunctional magneto-optic materials. However, the atomically ordered Au-M (M = Fe, Co, Ni) intermetallics are particularly elusive from a synthetic standpoint. Here we report the low-temperature solution synthesis of the L12 (Cu3Au-type) intermetallic compounds Au3Fe, Au3Co, and Au3Ni using n-butyllithium as a reducing agent. Reaction pathway studies for the Au3Co system indicate that Au nucleates first, followed by Co incorporation to form the intermetallic. The nonequilibrium intermetallic nanocrystals have been characterized by powder XRD, TEM, EDS, selected area electron diffraction, and nanobeam electron diffraction, which collectively confirm the compositions and superlattice structures.

  DOI：

  10.1021/ja804858u

文献信息

• Observations on the melting of Au nanoparticle deposits and alloying with Ni via <i>in situ</i> synchrotron radiation x-ray diffraction
  作者：Tzu-Hsuan Kao、Jenn-Ming Song、In-Gann Chen、Teng-Yuan Dong、Weng-Sing Hwang、Hsin-Yi Lee

  DOI：10.1063/1.3242373

  日期：2009.9.28

  evolution of the x-ray diffraction peaks, the transient low temperature melting of Au nanoparticles and following alloying with the substrate were demonstrated via in situ synchrotron radiation x-ray diffraction. Upon heating, the broad diffraction peak of nanosized Au particles with the average diameter of 2.5 nm was suppressed at about 200 °C and soon became sharp due to melting and subsequent solidification

  通过监测 x 射线衍射峰的演变，通过原位同步辐射 x 射线衍射证明了 Au 纳米颗粒的瞬态低温熔化和随后与基材的合金化。加热后，平均直径为 2.5 nm 的纳米金颗粒的宽衍射峰在 200 °C 左右被抑制，并且由于熔化和随后的固化而很快变得尖锐。如果在 Ni 薄膜上进行测试，会出现不稳定的金属间化合物 Au3Ni 和结晶 Au，这是 Au 和 Ni 的过冷液体反应的结果。然而，它在 275 °C 及以上分解。
• Low-Temperature Solution Synthesis of the Non-Equilibrium Ordered Intermetallic Compounds Au₃Fe, Au₃Co, and Au₃Ni as Nanocrystals
  作者：Yolanda Vasquez、Zhiping Luo、Raymond E. Schaak

  DOI：10.1021/ja804858u

  日期：2008.9.10

  Alloys and intermetallic compounds of Au with the 3d transition metals Fe, Co, and Ni are nonequilibrium phases that have many useful potential applications as catalytic, magnetic, optic, and multifunctional magneto-optic materials. However, the atomically ordered Au-M (M = Fe, Co, Ni) intermetallics are particularly elusive from a synthetic standpoint. Here we report the low-temperature solution synthesis of the L12 (Cu3Au-type) intermetallic compounds Au3Fe, Au3Co, and Au3Ni using n-butyllithium as a reducing agent. Reaction pathway studies for the Au3Co system indicate that Au nucleates first, followed by Co incorporation to form the intermetallic. The nonequilibrium intermetallic nanocrystals have been characterized by powder XRD, TEM, EDS, selected area electron diffraction, and nanobeam electron diffraction, which collectively confirm the compositions and superlattice structures.