12-hydroxy-11-mesityl-1,4-dioxa-9-azadispiro[4.2.4.2]tetradec-11-en-10-one | 907187-05-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂螺癸烷衍生物
• 英文名称: 12-hydroxy-11-mesityl-1,4-dioxa-9-azadispiro[4.2.4.2]tetradec-11-en-10-one
• 英文别名: 1-Hydroxy-2-(2,4,6-trimethylphenyl)-9,12-dioxa-4-azadispiro[4.2.48.25]tetradec-1-en-3-one
• CAS: 907187-05-7
• 化学式: C₂₀H₂₅NO₄
• 分子量: 343.423
• InChiKey: BBZRUORJRGRIJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  67.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  12-hydroxy-11-mesityl-1,4-dioxa-9-azadispiro[4.2.4.2]tetradec-11-en-10-one 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 1.0h， 以94%的产率得到Potassium;3-oxo-2-(2,4,6-trimethylphenyl)-9,12-dioxa-4-azadispiro[4.2.48.25]tetradec-1-en-1-olate
  参考文献：
  名称：

  US2011/86762

  摘要：

  公开号：
• 作为产物：
  描述：

  2-hydroxyethyl 8-[(mesitylacetyl)amino]-1,4-dioxaspiro[4.5]decane-8-carboxylate 在 sodium methylate 作用下， 以 甲醇 、 N,N-二甲基乙酰胺 为溶剂， 反应 6.05h， 生成 12-hydroxy-11-mesityl-1,4-dioxa-9-azadispiro[4.2.4.2]tetradec-11-en-10-one
  参考文献：
  名称：

  PROCESS FOR PREPARING SPIROKETAL-SUBSTITUTED CYCLIC KETOENOLS

  摘要：

  本发明涉及一种新型制备螺环醚取代的环状酮烯醇的方法，该方法可用作杀虫剂、杀螨剂或除草剂。本发明还涉及用于制备螺环醚取代的环状酮烯醇的新型中间体。

  公开号：

  US20190202837A1

文献信息

• Process for preparing spiroketal-substituted cyclic ketoenols
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US11220511B2

  公开（公告）日：2022-01-11

  The invention relates to a novel process for preparing spiroketal-substituted cyclic ketoenols which can be used as insecticides, acaricides or herbicides. The present invention also relates to novel intermediates for the preparation of spiroketal-substituted cyclic ketoenols.

  本发明涉及一种制备可用作杀虫剂、杀螨剂或除草剂的螺酮醛取代的环酮醇的新工艺。本发明还涉及用于制备螺酮醛取代的环酮醇的新型中间体。
• Spiroketal-Substituted Cyclic Ketoenols
  申请人：Bretschneider Thomas

  公开号：US20080305955A1

  公开（公告）日：2008-12-11

  The invention relates to novel spiroketal-substituted cyclic ketoenols of the formula (I) in which A, B, Q 1 , Q 2 , D, G, W, X, Y, and Z are as defined above, to processes and intermediates for their preparation and to their use as pesticides and/or microbicides and/or herbicides. Moreover, the invention relates to selective herbicidal compositions comprising, firstly, spiroketal-substituted cyclic ketoenols and, secondly, a crop plant compatibility-improving compound.
• 4'4'-Dioxaspiro-Spirocyclically Substituted Tetramates
  申请人：Fischer Reiner

  公开号：US20110086762A1

  公开（公告）日：2011-04-14

  The present invention relates to novel 4′4′-dioxaspiro-spirocyclically substituted tetramates of the formula (I) in which A, B, G, m, n, W, X, Y and Z to a plurality of processes for their preparation and to their use as pesticides and/or herbicides. The invention also provides selectively herbicidal compositions comprising firstly the 4′4′-dioxaspiro-spirocyclically substituted tetramates and secondly a crop plant compatibility-improving compound. The present invention also relates to novel water-soluble concentrates of 4′4′-dioxaspiro-spirocyclically substituted tetramates and their enols, to processes for preparing these formulations and to their use as pesticides and/or herbicides. The present invention furthermore relates to increasing the activity of crop protection compositions comprising in particular 4′4′-dioxaspiro-spirocyclically substituted tetramates by adding ammonium salts or phosphonium salts and, if appropriate, penetrants, to the corresponding compositions, to processes for their preparation and to their use in crop protection as insecticides and/or acaricides and/or for preventing unwanted plant growth.
• US7897543B2
  申请人：——

  公开号：US7897543B2

  公开（公告）日：2011-03-01
• [DE] VERFAHREN ZUR HERSTELLUNG VON SPIROKETAL-SUBSTITUIERTEN CYCLISCHEN KETOENOLEN<br/>[EN] METHOD FOR PRODUCING SPIROKETAL-SUBSTITUTED CYCLIC KETOENOLS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE CÉTOÉNOLS CYCLIQUES SUBSTITUÉS PAR SPIROCÉTAL
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2018024659A1

  公开（公告）日：2018-02-08

  Die Erfindung betrifft ein neues Verfahren zur Herstellung von spiroketal-substituierten cyclischen Ketoenolen, die als Insektizide, Akarizide oder Herbizide Verwendung finden können. Ebenfalls Gegenstand der vorliegenden Erfindung sind neue Zwischenprodukte zur Herstellung von spiroketal-substituierten cyclischen Ketoenolen.