[3-(4-Prop-2-enoyloxybutoxy)-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propyl] 9-oxothioxanthene-2-carboxylate | 1231708-21-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: [3-(4-Prop-2-enoyloxybutoxy)-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propyl] 9-oxothioxanthene-2-carboxylate
• CAS: 1231708-21-6
• 化学式: C₃₃H₃₈O₁₁S
• 分子量: 642.724
• InChiKey: ZABNIROZTOFMGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  45
• 可旋转键数：
  24
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  158
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  丙烯酸乙烯基乙氧基乙酯 、 9-oxo-9H-thioxanthene-2-carboxylic acid-3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester 在 2,6-二叔丁基-4-甲基苯酚 、 三氟乙酸 作用下， 反应 2.0h， 生成 [3-(4-Prop-2-enoyloxybutoxy)-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propyl] 9-oxothioxanthene-2-carboxylate
  参考文献：
  名称：

  ACTIVE-ENERGY-RAY-POLYMERIZABLE INITIATOR, ACTIVE-ENERGY-RAY-POLYMERIZABLE COMPOSITION, ACTIVE-ENERGY-RAY-POLYMERIZABLE INK, INK STORAGE CONTAINER, IMAGE FORMING METHOD, AND IMAGE FORMING APPARATUS

  摘要：

  提供具有以下一般式（1）所代表的结构的活性能量射线可聚合引发剂。 在一般式（1）中，L1代表—C(═O)—O—（与L2侧结合）或—O—，L2代表—O(CH2)p-(与L1侧结合)，—(OC2H4)n-(与L1侧结合)，或—(OC3H6)m-(与L1侧结合)，其中p表示2到16的整数，n表示2到12的整数，m表示2或3，L3代表直接结合或—NH—，L4代表—OC2H4-(与L3侧结合)或—(OC2H4)2-(与L3侧结合)，R代表—H或—CH3。

  公开号：

  US20200270469A1

文献信息

• Polymerizable photoinitiators and radiation curable compositions
  申请人：AGFA NV

  公开号：EP2199273B1

  公开（公告）日：2018-02-21
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110224324A1

  公开（公告）日：2011-09-15

  A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.
• US8492452B2
  申请人：——

  公开号：US8492452B2

  公开（公告）日：2013-07-23
• [EN] POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS<br/>[FR] PHOTO-INITIATEURS POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES PAR RAYONNEMENT
  申请人：AGFA GRAPHICS NV

  公开号：WO2010069758A1

  公开（公告）日：2010-06-24

  A polymerizable photoinitiator represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w = 1 to (p-z) and z = O to (p-w); L represents an optionally substituted (p÷y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation. Radiation curable compositions including the polymerizable photoinitiator and methods of preparing the polymerizable photoinitiator are also disclosed.
• ACTIVE-ENERGY-RAY-POLYMERIZABLE INITIATOR, ACTIVE-ENERGY-RAY-POLYMERIZABLE COMPOSITION, ACTIVE-ENERGY-RAY-POLYMERIZABLE INK, INK STORAGE CONTAINER, IMAGE FORMING METHOD, AND IMAGE FORMING APPARATUS
  申请人：HARADA Shigeyuki

  公开号：US20200270469A1

  公开（公告）日：2020-08-27

  An active-energy-ray-polymerizable initiator having a structure represented by the following general formula (1) is provided. In general formula (1), L 1 represents —C(═O)—O— (binding to L 2 side) or —O—, L 2 represents —O(CH 2 ) p -(binding to L 1 side), —(OC 2 H 4 ) n -(binding to L 1 side), or —(OC 3 H 6 ) m -(binding to L 1 side), where p represents an integer of 2 to 16, n represents an integer of 2 to 12, and m represents 2 or 3, L 3 represents a direct binding or —NH—, L 4 represents —OC 2 H 4 -(binding to L 3 side) or —(OC 2 H 4 ) 2 -(binding to L 3 side), and R represents —H or —CH 3 .

  提供具有以下一般式（1）所代表的结构的活性能量射线可聚合引发剂。 在一般式（1）中，L1代表—C(═O)—O—（与L2侧结合）或—O—，L2代表—O(CH2)p-(与L1侧结合)，—(OC2H4)n-(与L1侧结合)，或—(OC3H6)m-(与L1侧结合)，其中p表示2到16的整数，n表示2到12的整数，m表示2或3，L3代表直接结合或—NH—，L4代表—OC2H4-(与L3侧结合)或—(OC2H4)2-(与L3侧结合)，R代表—H或—CH3。