hexylmethylphenylsilane | 21654-96-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: hexylmethylphenylsilane
• 英文别名: Hexyl-methyl-phenyl-silan；Hexyl-methyl-phenylsilane
• CAS: 21654-96-6
• 化学式: C₁₃H₂₂Si
• 分子量: 206.403
• InChiKey: YKZPZJMFVOQAQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.33
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  hexylmethylphenylchlorosilane 在 红铝 作用下， 以 正己烷 为溶剂， 生成 hexylmethylphenylsilane
  参考文献：
  名称：

  Separation of chiral silicon compounds using permethylated .alpha.-, .beta.-, and .gamma.-cyclodextrin capillary GC columns

  摘要：

  Permethylated alpha-, beta-, and gamma-cyclodextrin GC stationary phases were used to resolve racemic silane derivatives, R1R2Si*PhMe. Particularly good resolutions were obtained on the beta-CD phase for racemates containing a silanol group, R1 = OH.

  DOI：

  10.1021/ac00057a005

文献信息

• Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium
  作者：Daniel S. Levine、T. Don Tilley、Richard A. Andersen

  DOI：10.1039/c7cc06417a

  日期：——

  catalyst decomposition, and therefore higher total yields for some of the reactions with the scandium catalyst. Calculations indicate that the reactions may proceed via σ-bond metathesis of the alkyl complexes to form a metal hydride intermediates into which alkenes/alkynes insert.

  研究了由单阴离子PNP配体支撑的和钇同系配合物作为烯烃加氢和硅氢化反应以及炔烃半氢化和半硅氢化反应的催化剂。已发现钇同系物在所有情况下均具有更高的活性，但是这种更高的活性伴随着更快速的催化剂分解，因此，对于某些与the催化剂的反应，其总收率更高。计算表明该反应可以通过烷基络合物的σ-键复分解进行，以形成烯烃/炔烃插入其中的金属氢化物中间体。
• Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands
  作者：Kouji Kamata、Atsuko Suzuki、Yuta Nakai、Hiroshi Nakazawa

  DOI：10.1021/om300279t

  日期：2012.5.28

  Iron complexes formulated as Fe(terpy)X-2 (terpy = 2,2':6',2 ''-terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for hydrosilylation of olefin with hydrosilane were examined. Although Fe(terpy)X-2 did not show catalytic activity, the treatment of Fe(terpy)X-2 with NaHBEt3 caused catalytic activity. The influence of substituents in terpy on the catalytic activity was examined, and it was found that some complexes with an unsymmetrically disubstituted terpy selectively produced 1-silylalkane with quite high catalytic activity. In the reaction of 1-octene with PhSiH3, the double-hydrosilylation product Ph(1-octyl)(2)SiH was selectively obtained.
• Odabashyan,G.V. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 2258 - 2261
  作者：Odabashyan,G.V. et al.

  DOI：——

  日期：——