2,10-dibromo-pentacenequinone | 1300008-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 并五苯醌
• 英文名称: 2,10-dibromo-pentacenequinone
• 英文别名: 2,10-Br2PQ；2,10-Dibromopentacene-6,13-dione；2,10-dibromopentacene-6,13-dione
• CAS: 1300008-87-0
• 化学式: C₂₂H₁₀Br₂O₂
• 分子量: 466.128
• InChiKey: NUXDOYADVNECDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,10-dibromo-pentacenequinone 、 三异丙基硅基乙炔 在 正丁基锂 作用下， 以 乙醚 、 正己烷 、 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of regioregular pentacene-containing conjugated polymers

  摘要：

  我们报告了通过之前报道的合成路线合成和表征一类新的含共轭五苯并环戊二烯的共轭聚合物的结果。我们发现，与它们的共轭随机聚合物相比，我们的共轭五苯并环戊二烯聚合物的有序性更好，并且具有更好的双极性有机场效应晶体管性能。

  DOI：

  10.1039/c1jm10643k
• 作为产物：
  描述：

  1,2-二溴-4,5-二甲苯 在 吡啶 、 N-溴代丁二酰亚胺(NBS) 、 水 、 溴 、 magnesium 、 二甲胺 、 potassium hydroxide 、 过氧化苯甲酰 作用下， 以 四氢呋喃 、 四氯化碳 、 六甲基磷酰三胺 、 甲苯 为溶剂， 反应 85.75h， 生成 2,10-dibromo-pentacenequinone 、 2,9-dibromo-pentacenequinone
  参考文献：
  名称：

  [EN] QUANTITATIVE INTRAMOLECULAR FISSION IN OLIGOACENES, MATERIALS, AND METHODS OF USE THEREOF
  [FR] FRAGMENTATION INTRAMOLÉCULAIRE QUANTITATIVE DANS DES OLIGOACÈNES, MATÉRIAUX, ET LEURS PROCÉDÉS D'UTILISATION

  摘要：

  本发明提供可溶性、稳定的单重子裂变（SF）化合物、组合物、材料、其使用方法以及制备方法，其提供高效的分子内单重子裂变（iSF）和多重激子。SF化合物可以是多聚体、寡聚体或聚合物的聚合物，例如，该化合物可实现每吸收光子的三重态产率达到约200%。在这个系统中，SF不依赖于分子间相互作用。相反，SF是分子的固有性质，因此独立于分子间相互作用而发生。单重子裂变有潜力显着提高单结太阳能电池的光电流，并将从约33%提高到约46%或更高的肖克利-克瓦塞尔功率转换效率极限。在室温下只有在晶体固体或更高的芳香烃聚集体中观察到定量的SF产率。

  公开号：

  WO2016100754A1

文献信息

• ORGANIC SEMICONDUCTOR COMPOSITIONS
  申请人：SMARTKEM LIMITED

  公开号：US20150034878A1

  公开（公告）日：2015-02-05

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin film transistor (OTFT) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.

  本发明涉及有机共聚物和包含这些材料的有机半导体组合物，包括包含这种有机半导体组合物的层和器件。本发明还涉及制备这种有机半导体组合物和层的方法和其用途。本发明适用于印刷电子领域，特别适用于有机薄膜晶体管（OTFT）背板的半导体材料，用于显示器、集成电路、有机发光二极管（OLED）、光电探测器、有机光伏（OPV）电池、传感器、存储元件和逻辑电路的配方中。
• Organic semiconductor compositions
  申请人：SMARTKEM LIMITED

  公开号：US10833274B2

  公开（公告）日：2020-11-10

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin film transistor (OTFT backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.

  本发明涉及有机共聚物和包含这些材料的有机半导体组合物，包括包含这种有机半导体组合物的层和器件。本发明还涉及制备这种有机半导体组合物和层的方法及其用途。本发明可应用于印刷电子领域，特别是作为半导体材料用于显示器有机薄膜晶体管（OTFT）背板、集成电路、有机发光二极管（OLED）、光电探测器、有机光伏（OPV）电池、传感器、存储元件和逻辑电路的配方中。
• US9799830B2
  申请人：——

  公开号：US9799830B2

  公开（公告）日：2017-10-24
• [EN] ORGANIC SEMICONDUCTOR COMPOSITIONS<br/>[FR] COMPOSITIONS SEMI-CONDUCTRICES ORGANIQUES
  申请人：SMARTKEM LTD

  公开号：WO2013124682A1

  公开（公告）日：2013-08-29

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin filmtransistor (OFET) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.
• [EN] ORGANIC SEMICONDUCTOR COMPOSITIONS<br/>[FR] COMPOSITIONS DE SEMI-CONDUCTEURS ORGANIQUES
  申请人：SMARTKEM LTD

  公开号：WO2013124683A1

  公开（公告）日：2013-08-29

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin film transistor (OTFT backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.