POLYROTAXANE HAVING MAIN CHAIN BACKBONE ESSENTIALLY COMPOSED OF -Si-O- AND METHOD FOR PRODUCING THE SAME, AND CROSSLINKED POLYROTAXANE OBTAINED BY CROSSLINKING THE POLYROTAXANE AND METHOD FOR PRODUCING THE SAME
申请人:The University of Tokyo
公开号:EP2159250A1
公开(公告)日:2010-03-03
Disclosed are a novel polyrotaxane having a main chain backbone essentially composed of -Si-O-, and a method for producing such a novel polyrotaxane. Also disclosed are a polyrotaxane having stretchability and/or viscoelasticity, while exhibiting oxygen permeability, heat resistance, chemical resistance, environmental resistance and/or durability, and a method for producing such a polyrotaxane. Further disclosed are a crosslinked polyrotaxane obtained by crosslinking the polyrotaxane with another polymer and/or polyrotaxane through a chemical bond, and a method for producing such a crosslinked polyrotaxane. Specifically disclosed is a polyrotaxane obtained by arranging blocking groups on both ends of a pseudopolyrotaxane, wherein a linear molecule passes through the open portion of a circular molecule in a skewering manner, for preventing elimination of the circular molecule from the linear molecule. In this polyrotaxane, the linear molecule has a main chain backbone essentially composed of -Si-O-.
公开了一种主链骨架基本上由-Si-O-组成的新型聚罗他赛烷,以及生产这种新型聚罗他赛烷的方法。还公开了一种具有拉伸性和/或粘弹性,同时具有透氧性、耐热性、耐化学性、耐环境性和/或耐久性的聚罗他赛烷,以及生产这种聚罗他赛烷的方法。进一步公开的是通过化学键将聚碳酸酯与另一种聚合物和/或聚碳酸酯交联而得到的交联聚碳酸酯,以及生产这种交联聚碳酸酯的方法。具体而言,公开了一种通过在假聚二十六烷的两端排列封端基团而获得的聚二十六烷,其中线性分子以斜向方式穿过圆形分子的开口部分,以防止圆形分子从线性分子中消除。在这种聚交烷中,线性分子的主链骨架基本上由-Si-O-组成。