5-acetylamino-2-methoxy-4-(4-nitrophenylazo)-N,N-diethylaniline | 81924-79-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 5-acetylamino-2-methoxy-4-(4-nitrophenylazo)-N,N-diethylaniline
• 英文别名: N-(5-(Diethylamino)-4-methoxy-2-((4-nitrophenyl)azo)phenyl)acetamide；N-[5-(diethylamino)-4-methoxy-2-[(4-nitrophenyl)diazenyl]phenyl]acetamide
• CAS: 81924-79-0
• 化学式: C₁₉H₂₃N₅O₄
• 分子量: 385.423
• InChiKey: VHLPNAMZTUCDKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  112
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-硝基苯胺 、 3-(N,N-二乙基)氨基-4-甲氧基乙酰苯胺 在 盐酸 、 sodium nitrite 作用下， 以 水 、 丙酮 为溶剂， 反应 1.5h， 以82%的产率得到5-acetylamino-2-methoxy-4-(4-nitrophenylazo)-N,N-diethylaniline
  参考文献：
  名称：

  Synthesis of azo chromophores containing a perfluorocyclo-alkenyl moiety and their second-order optical nonlinearity

  摘要：

  1,2-Bis[4-[4-[N-ethyl-N-(2-hydroxyethyl)amino]phenylazo]phenylthio]perfluorocyclopentene, having two independent intramolecular push-pull chromophores in a molecule, showed the highest second-order nonlinear coefficient (d(33)) among the cyclobutenyl, -pentenyl, -hexenyl, and cyclopentenyl nitro derivatives in both doped poly(methyl methacrylate) (PMMA) and polycarbonate (PC). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(99)00050-0

文献信息

• Synthesis of azo chromophores containing a perfluorocyclo-alkenyl moiety and their second-order optical nonlinearity
  作者：Masaki Matsui、Michinori Tsuge、Kazumasa Funabiki、Katsuyoshi Shibata、Hiroshige Muramatsu、Kazuo Hirota、Masahiro Hosoda、Kazuo Tai、Hisayoshi Shiozaki、Misa Kim、Kazumi Nakatsu

  DOI：10.1016/s0022-1139(99)00050-0

  日期：1999.7

  1,2-Bis[4-[4-[N-ethyl-N-(2-hydroxyethyl)amino]phenylazo]phenylthio]perfluorocyclopentene, having two independent intramolecular push-pull chromophores in a molecule, showed the highest second-order nonlinear coefficient (d(33)) among the cyclobutenyl, -pentenyl, -hexenyl, and cyclopentenyl nitro derivatives in both doped poly(methyl methacrylate) (PMMA) and polycarbonate (PC). (C) 1999 Elsevier Science S.A. All rights reserved.