4-(4-(n-octyloxy)benzoyloxy)-2-methoxybenzaldehyde | 1325213-95-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(4-(n-octyloxy)benzoyloxy)-2-methoxybenzaldehyde
• 英文别名: 4-(4-n-Octyloxybenzoyloxy)-2-methoxybenzaldehyde；(4-formyl-3-methoxyphenyl) 4-octoxybenzoate
• CAS: 1325213-95-3
• 化学式: C₂₃H₂₈O₅
• 分子量: 384.472
• InChiKey: NVEFHQOBOZBNDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(4-(n-octyloxy)benzoyloxy)-2-methoxybenzaldehyde 在 4-二甲氨基吡啶 、 Jones reagent 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 生成 3-[4-(4-octyloxybenzoyloxy)benzoyloxy]-1-[4-(4-octyloxybenzoyloxy)-2-methoxybenzoyloxy]benzene
  参考文献：
  名称：

  Synthesis of banana-like 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene esters and luminescence of their terbium(III) complexes

  摘要：

  New esters of 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene with 4-(4-alkoxybenzoyloxy)-2-(or 3-)methoxybenzoic acids were synthesized. The correlation between their structure and liquid crystal properties was examined, and the luminescence characteristics of terbium(III) complexes with these esters were studied.

  DOI：

  10.1134/s1070427211060139
• 作为产物：
  描述：

  间苯二酚 在 吡啶 、 potassium hydroxide 、 三氯氧磷 作用下， 以 水 为溶剂， 生成 4-(4-(n-octyloxy)benzoyloxy)-2-methoxybenzaldehyde
  参考文献：
  名称：

  Synthesis of banana-like 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene esters and luminescence of their terbium(III) complexes

  摘要：

  New esters of 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene with 4-(4-alkoxybenzoyloxy)-2-(or 3-)methoxybenzoic acids were synthesized. The correlation between their structure and liquid crystal properties was examined, and the luminescence characteristics of terbium(III) complexes with these esters were studied.

  DOI：

  10.1134/s1070427211060139

文献信息

• Synthesis of banana-like 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene esters and luminescence of their terbium(III) complexes
  作者：N. S. Novikova、E. D. Kilimenchuk、R. V. Kondrat’eva、S. B. Meshkova、Z. M. Topilova

  DOI：10.1134/s1070427211060139

  日期：2011.6

  New esters of 1,3-dihydroxybenzene and 2,7-dihydroxynaphthalene with 4-(4-alkoxybenzoyloxy)-2-(or 3-)methoxybenzoic acids were synthesized. The correlation between their structure and liquid crystal properties was examined, and the luminescence characteristics of terbium(III) complexes with these esters were studied.