| 36838-19-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 36838-19-4
• 化学式: C₇H₂₁Si₃
• 分子量: 189.5
• InChiKey: FCVGPFNEXCXAEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.94
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1,1,2,3,3,3-heptamethyltrisilane 在 (t-BuO)2 作用下， 生成
  参考文献：
  名称：

  The trimethylsilyl substituent effect on the reactivity of silanes. Structural correlations between silyl radicals and their parent silanes

  摘要：

  Good linear correlations exist both between the bond dissociation energy of an Si-H bond and the corresponding SiH stretching frequency and between the Si-29 hyperfine splitting of a silicon-centered radical and J(Si-29-H) for the corresponding silane, when the successive substitution at the Si-H function takes place inside a family, i.e., (Me3Si)3-nSi(H)Men, n = 0-3. Explanations for these phenomena are advanced. Such structural correlations allow the characterization of (Me3Si)2Si(H)Me as a radical-based reducing agent with low hydrogen-donating abilities. Rate constants for the reaction of primary alkyl radicals with (Me3Si)2Si(H)Me have been measured over a range of temperatures by using competing unimolecular radical reactions as timing devices. The radical trapping abilities of this silane and other common radical-based reducing agents are compared.

  DOI：

  10.1021/jo00038a031

文献信息

• The trimethylsilyl substituent effect on the reactivity of silanes. Structural correlations between silyl radicals and their parent silanes
  作者：C. Chatgilialoglu、A. Guerrini、M. Lucarini

  DOI：10.1021/jo00038a031

  日期：1992.6

  Good linear correlations exist both between the bond dissociation energy of an Si-H bond and the corresponding SiH stretching frequency and between the Si-29 hyperfine splitting of a silicon-centered radical and J(Si-29-H) for the corresponding silane, when the successive substitution at the Si-H function takes place inside a family, i.e., (Me3Si)3-nSi(H)Men, n = 0-3. Explanations for these phenomena are advanced. Such structural correlations allow the characterization of (Me3Si)2Si(H)Me as a radical-based reducing agent with low hydrogen-donating abilities. Rate constants for the reaction of primary alkyl radicals with (Me3Si)2Si(H)Me have been measured over a range of temperatures by using competing unimolecular radical reactions as timing devices. The radical trapping abilities of this silane and other common radical-based reducing agents are compared.